Polymerization Mechanism of MMA in the Presence of 1,1-Diphenylethylene
Minjian Zhao
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Search for more papers by this authorDong Chen
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Search for more papers by this authorCorresponding Author
Yan Shi
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China.Search for more papers by this authorWantai Yang
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Search for more papers by this authorZhifeng Fu
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Search for more papers by this authorMinjian Zhao
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Search for more papers by this authorDong Chen
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Search for more papers by this authorCorresponding Author
Yan Shi
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China.Search for more papers by this authorWantai Yang
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Search for more papers by this authorZhifeng Fu
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Search for more papers by this authorAbstract
A suitable controlled polymerization mechanism of methyl methacrylate (MMA) in the presence of 1,1-diphenylethylene (DPE) is presented. The PMMAs with different molecular weight are prepared and the structures of the polymers are characterized by NMR spectroscopy and ESI-Q-TOF-MS. The good agreements between the theoretical and the experimental m/z values of PMMA samples acquired by ESI-Q-TOF-MS provide positive evidence to confirm that only one DPE unit is incorporated into the PMMA macromolecule chains. TEMPO is used as a radical scavenger to capture the active free radicals generated by the scission of the DPE-containing PMMA polymer. The molecular weight of the DPE-containing PMMA decreases dramatically after the reaction with TEMPO; meanwhile, the DPE molecule is split from the DPE-containing PMMA.
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