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Trimethylsilylation of Hydroxyl Group with 1,1,1,3,3,3-Hexamethyldisilazane (HMDS) Catalyzed by Tribromomelamine (TBM)
Arash Ghorbani-Choghamarani,
Mohammad Ali Zolfigol,
Maryam Hajjami,
Shila Jafari,
Corresponding Author
Arash Ghorbani-Choghamarani
Department of Chemistry, Faculty of Science, Ilam University, P. O. Box 69315516, Ilam, Iran
Tel/Fax: +98-811-8257404Search for more papers by this authorMohammad Ali Zolfigol
Faculty of Chemistry, Bu-Ali Sina University, Hamadan, Iran
Search for more papers by this authorMaryam Hajjami
Faculty of Chemistry, Bu-Ali Sina University, Hamadan, Iran
Search for more papers by this authorShila Jafari
Faculty of Chemistry, Bu-Ali Sina University, Hamadan, Iran
Search for more papers by this authorArash Ghorbani-Choghamarani,
Mohammad Ali Zolfigol,
Maryam Hajjami,
Shila Jafari,
Corresponding Author
Arash Ghorbani-Choghamarani
Department of Chemistry, Faculty of Science, Ilam University, P. O. Box 69315516, Ilam, Iran
Tel/Fax: +98-811-8257404Search for more papers by this authorMohammad Ali Zolfigol
Faculty of Chemistry, Bu-Ali Sina University, Hamadan, Iran
Search for more papers by this authorMaryam Hajjami
Faculty of Chemistry, Bu-Ali Sina University, Hamadan, Iran
Search for more papers by this authorShila Jafari
Faculty of Chemistry, Bu-Ali Sina University, Hamadan, Iran
Search for more papers by this authorAbstract
Tribromomelamine (TBM) can be used as a novel catalyst for the trimethylsilylation of alcohols and phenols with 1,1,1,3,3,3-hexamethyldisilazane (HMDS). A wide variety of hydroxyl groups were selectively protected in CH2Cl2/CH3CN under mild conditions.
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