Comprehensive assessment of the Calotropis procera natural dye extracts with weather effects for photovoltaic solar cell manufacturing
Adnan Alashkar
Materials Science and Engineering PhD Program, American University of Sharjah, Sharjah, United Arab Emirates
Search for more papers by this authorShamma Alasad
Mechanical Engineering Department, American University of Sharjah, Sharjah, United Arab Emirates
Search for more papers by this authorHaya Aljaghoub
Department of Industrial Engineering and Engineering Management, University of Sharjah, Sharjah, United Arab Emirates
Search for more papers by this authorMohamad Ayoub
Department of Sustainable and Renewable Energy Engineering, University of Sharjah, Sharjah, United Arab Emirates
Search for more papers by this authorTsombou Francois
Department of Applied Biology, University of Sharjah, Sharjah, United Arab Emirates
Search for more papers by this authorAli El-Keblawy
Department of Applied Biology, University of Sharjah, Sharjah, United Arab Emirates
Search for more papers by this authorDi Zhang
Department of Sustainable and Renewable Energy Engineering, University of Sharjah, Sharjah, United Arab Emirates
Center for Advanced Materials Research, University of Sharjah, Sharjah, United Arab Emirates
Search for more papers by this authorCorresponding Author
Abdul Hai Alami
Department of Sustainable and Renewable Energy Engineering, University of Sharjah, Sharjah, United Arab Emirates
Center for Advanced Materials Research, University of Sharjah, Sharjah, United Arab Emirates
Correspondence
Abdul Hai Alami, Department of Sustainable and Renewable Energy Engineering, University of Sharjah, Sharjah, United Arab Emirates.
Email: [email protected]
Search for more papers by this authorAdnan Alashkar
Materials Science and Engineering PhD Program, American University of Sharjah, Sharjah, United Arab Emirates
Search for more papers by this authorShamma Alasad
Mechanical Engineering Department, American University of Sharjah, Sharjah, United Arab Emirates
Search for more papers by this authorHaya Aljaghoub
Department of Industrial Engineering and Engineering Management, University of Sharjah, Sharjah, United Arab Emirates
Search for more papers by this authorMohamad Ayoub
Department of Sustainable and Renewable Energy Engineering, University of Sharjah, Sharjah, United Arab Emirates
Search for more papers by this authorTsombou Francois
Department of Applied Biology, University of Sharjah, Sharjah, United Arab Emirates
Search for more papers by this authorAli El-Keblawy
Department of Applied Biology, University of Sharjah, Sharjah, United Arab Emirates
Search for more papers by this authorDi Zhang
Department of Sustainable and Renewable Energy Engineering, University of Sharjah, Sharjah, United Arab Emirates
Center for Advanced Materials Research, University of Sharjah, Sharjah, United Arab Emirates
Search for more papers by this authorCorresponding Author
Abdul Hai Alami
Department of Sustainable and Renewable Energy Engineering, University of Sharjah, Sharjah, United Arab Emirates
Center for Advanced Materials Research, University of Sharjah, Sharjah, United Arab Emirates
Correspondence
Abdul Hai Alami, Department of Sustainable and Renewable Energy Engineering, University of Sharjah, Sharjah, United Arab Emirates.
Email: [email protected]
Search for more papers by this authorSummary
This work studies the Calotropis procera, a xerophytic plant of the hyper-arid hot deserts of the Gulf region, as a model to assess correlations between environmental conditions and photosynthetic efficiency. Plant structure and environmental factors are thoroughly assessed, such as leaf surface orientation, daytime, and photosynthetic photon flux density (PPFD). The latter measures effect of incident light on leaf surface on the photosynthesis efficiency of Calotropis, and consequently the performance of a solar cell. Furthermore, the linear Angstrom model is developed to correlate solar irradiance and sunlit hours with the quality of incident radiation on cell performance. It was interesting to note that leaves facing east and south directions received higher incident light and temperatures, attained lower potential quantum efficiency and operating efficiency but higher values of nonphotochemical chlorophyll fluorescence quenching. Such results indicate that the loss of excess excitation energy was insufficient to enhance the photosynthesis efficiency in these directions. The dye extracts were used to build a dye-sensitized solar cells that were compared to ones using synthetic ruthenium dye. The Calotropis photosystem demonstrated lower efficiencies (0.157% vs 1.58% from Ru cells). Nevertheless, for the Calotropis-based cells, a figure-of-merit of cell efficiency over their production cost makes them a good candidate for research and development efforts to overcome obvious drawbacks of low efficiency and stability.
REFERENCES
- 1Alami AH. In: AH Alami, ed. Introduction to mechanical energy storage BT - Mechanical energy storage for renewable and sustainable energy resources. Cham: Springer International Publishing; 2020: 1-12.
- 2Fathy A, Elaziz MA, Sayed ET, Olabi AG, Rezk H. Optimal parameter identification of triple-junction photovoltaic panel based on enhanced moth search algorithm. Energy. 2019; 188:116025.
- 3Alashkar A, Gadalla M. Thermo-economic analysis of an integrated solar power generation system using nanofluids. Appl Energy. 2017; 191: 469-491.
- 4Bojek P. Solar PV more efforts needed. Int Energy Agency. 2021: 128. https://www.iea.org/reports/solar-pv
- 5Alami AH, Aokal K, Zhang D, Tawalbeh M, Taieb A, Alhammadi A. Assessment of Calotropis natural dye extracts on the efficiency of dye-sensitized solar cells. Agron Res. 2018; 16(4): 1569-1579.
- 6Alami AH. Thermal storage. Mechanical energy storage for renewable and sustainable energy resources. Cham: Springer International Publishing; 2020: 27-34.
10.1007/978-3-030-33788-9_4 Google Scholar
- 7Alami AH. Linear angstrom model applied to weather data collected for the city of Sharjah. In: 2018 5th International Conference on Renewable Energy: Generation and Applications (ICREGA). 2018: 150-153.
- 8Almorox J, Arnaldo JA, Bailek N, Martí P. Adjustment of the angstrom-Prescott equation from Campbell-stokes and Kipp-Zonen sunshine measures at different timescales in Spain. Renew Energy. 2020; 154: 337-350.
- 9Alami AH, Aokal K, Zhang D, et al. Low-cost dye-sensitized solar cells with ball-milled tellurium-doped graphene as counter electrodes and a natural sensitizer dye. Int. J. Energy Res. 2019; 43(11): 5824-5833.
- 10 NREL. Best research-cell efficincies.
- 11Alami AH, Aokal K. Enhancement of spectral absorption of solar thermal collectors by bulk graphene addition via high-pressure graphite blasting. Energy Convers. Manag. 2018; 156: 757-764.
- 12Alami AH, Rajab B, Abed J, Faraj M, Hawili AA, Alawadhi H. Investigating various copper oxides-based counter electrodes for dye sensitized solar cell applications. Energy. 2019; 174: 526-533.
- 13Sharma S, Jain KK, Sharma A. Solar cells: in research and applications—a review. Mater Sci Appl. 2015; 6(12): 1145-1155.
- 14Alashkar A, Ibrahim T, Khamis M, Alami AH. Electrolytes, dyes, and perovskite materials in third generation photovoltaic cells. Encyclopedia of smart materials. Amsterdam: Elsevier; 2022: 621-634.
10.1016/B978-0-12-815732-9.00086-3 Google Scholar
- 15Chang H, Kao M-J, Chen T-L, Chen C-H, Cho K-C, Lai X-R. Characterization of natural dye extracted from wormwood and purple cabbage for dye-sensitized solar cells. Int J Photoenergy. 2013; 2013: 1-8.
- 16Sinha D, De D, Ayaz A. Photo sensitizing and electrochemical performance analysis of mixed natural dye and nanostructured ZnO based DSSC. Sādhanā. 2020; 45(1): 175.
- 17Bashar H, Bhuiyan MMH, Hossain MR, et al. Study on combination of natural red and green dyes to improve the power conversion efficiency of dye sensitized solar cells. Optik (Stuttg). 2019; 185: 620-625.
- 18Mabberley DJ. The plant-book: a portable dictionary of the vascular plants. Cambridge: Cambridge university press; 1997.
- 19Alami A, Alachkar A, Alasad S, Alawadhi M, Zhang D. Investigating Calotropis Procera natural dye extracts and PEDOT: PSS hole transport material for dye-sensitized solar cells. Agron Res. 2021; 19(2): 333-343.
- 20Phinjaturus K, Maiaugree W, Suriharn B, Pimanpaeng S, Amornkitbamrung V, Swatsitang E. Dye-sensitized solar cells based on purple corn sensitizers. Appl Surf Sci. 2016; 380: 101-107.
- 21Ammar AM, Mohamed HSH, Yousef MMK, Abdel-Hafez GM, Hassanien AS, Khalil ASG. Dye-sensitized solar cells (DSSCs) based on extracted natural dyes. J Nanomater. 2019; 2019: 1-10.
- 22Ghann W, Kang H, Sheikh T, et al. Fabrication, optimization and characterization of natural dye sensitized solar cell. Sci Rep. 2017; 7(1): 41470.
- 23Koutra E, Chondrogiannis C, Grammatikopoulos G. Variability of the photosynthetic machinery tolerance when imposed to rapidly or slowly imposed dehydration in native Mediterranean plants. Photosynthetica. 2022; 60: 88-101.
- 24Nicol L, Nawrocki WJ, Croce R. Disentangling the sites of non-photochemical quenching in vascular plants. Nat Plants. 2019; 5(11): 1177-1183.
- 25Murchie EH, Lawson T. Chlorophyll fluorescence analysis: a guide to good practice and understanding some new applications. J Exp Bot. 2013; 64(13): 3983-3998.
- 26Maxwell K, Johnson GN. Chlorophyll fluorescence - a practical guide. J Exp Bot. 2000; 51(345): 659-668.
- 27Alami AH, Aokal K, Faraj M. Investigating nickel foam as photoanode substrate for potential dye-sensitized solar cells applications. Energy. 2020; 211:118689.
- 28Alami AH, Alketbi A, Abed J, Almheiri M. Assessment of Al-cu-Fe compound for enhanced solar absorption. Int. J. Energy Res. 2016; 40(4).
- 29Alami AH, El Hajjar J, El Qadri L, Alhammadi A. Enhancement of transparent conductive electrodes for third generation photovoltaics. Energy Procedia. 2017; 119: 891-897.
- 30Alami AH, Abed J, Almheiri M, Alketbi A, Aokal C. Fe-cu metastable material as a mesoporous layer for dye-sensitized solar cells. Energy Sci. Eng. 2016; 4(2): 166-179.
- 31Alami AH, Faraj M, Aokal K, Abu Hawili A, Tawalbeh M, Zhang D. Investigating various permutations of copper iodide/FeCu tandem materials as electrodes for dye-sensitized solar cells with a natural dye. Nanomaterials. 2020; 10(4): 784.
- 32Alami AH, Rajab B, Aokal K. Assessment of silver nanowires infused with zinc oxide as a transparent electrode for dye-sensitized solar cell applications. Energy. 2017; 139: 1231-1236.
- 33Zhang D, Beer S, Li H, Gao K. Photosystems I and II in Ulva lactuca are well protected from high incident sunlight. Algal Res. 2020; 52:102094.
10.1016/j.algal.2020.102094 Google Scholar
- 34Greer DH. Leaf temperature and CO2 effects on photosynthetic CO2 assimilation and chlorophyll a fluorescence light responses during mid-ripening of Vitis vinifera cv. Shiraz grapevines grown in outdoor conditions. Funct Plant Biol. 2022; 49: 170-185.
- 35Hussain MI, Tsombou FM, El-Keblawy A. Surface canopy position determines the photosystem II photochemistry in invasive and native Prosopis congeners at Sharjah Desert, UAE. Forests. 2020; 11(7): 740.
- 36Bethmann S, Melzer M, Schwarz N, Jahns P. The zeaxanthin epoxidase is degraded along with the D1 protein during photoinhibition of photosystem II. Plant Direct. 2019; 3(11):e00185.
- 37Yeats TH, Rose JKC. The formation and function of plant cuticles. Plant Physiol. 2013; 163(1): 5-20.
- 38Elkins C, van Iersel MW. Longer photoperiods with the same daily light integral increase daily electron transport through photosystem II in lettuce. Plan Theory. 2020; 9(9): 1172.
- 39Bassi R, Dall'Osto L. Dissipation of light energy absorbed in excess: the molecular mechanisms. Annu. Rev. Plant Biol. 2021; 72(1): 47-76.
