Graphite felt modified with WO3, SnO2, and binary WO3/SnO2-mixtures as novel positive electrodes for cerium-based redox flow batteries
Corresponding Author
Mark D. Pritzker
Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada
Correspondence
Mark D. Pritzker, Department of Chemical Engineering, University of Waterloo, 200 University Avenue West, Waterloo, ON N2L 3G1, Canada.
Email: [email protected]
Search for more papers by this authorCorresponding Author
Mark D. Pritzker
Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada
Correspondence
Mark D. Pritzker, Department of Chemical Engineering, University of Waterloo, 200 University Avenue West, Waterloo, ON N2L 3G1, Canada.
Email: [email protected]
Search for more papers by this authorFunding information: Natural Sciences and Engineering Research Council of Canada (NSERC), Grant/Award Number: 170912-2013-RGPIN
Summary
Cerium-based redox flow batteries (RFBs) such as Zn-Ce and V-Ce have received attention as attractive energy storage systems due to their high open-circuit cell voltages. To date, the most successful Ce-based RFBs have relied on expensive Pt-based positive electrodes. In this study, the use of more economical polyacrylonitrile (PAN)-based graphite felt (GF) containing tungsten oxide (WO3) and/or tin oxide (SnO2) nanocatalysts is examined for its electrochemical activity for the Ce(III)/Ce(IV) redox reaction in a series of half-cell experiments. Cyclic voltammetry is carried out at room temperature in a 0.05 M Ce(III) methanesulfonate +1.0 M methanesulfonic acid (MSA) electrolyte using a custom-made three-electrode cell. Among all modified GFs, those coated with a binary WO3-SnO2 mixture have exhibited superior electrocatalytic activity toward the Ce(III)/Ce(IV) reaction compared to the ones decorated with single oxides WO3 or SnO2. Presumably, this can be ascribed to the involvement of both metal oxides (WO3 and SnO2) in promoting electrolyte accessibility and improving the hydrophilicity of GF electrodes. SEM images indicate that the combination of WO3 and SnO2 promotes a more homogeneous dispersion over the graphite fiber surface and prevents clustering of the oxide particles that is more evident in the case of the single metal oxide catalysts.
CONFLICT OF INTEREST
The authors declare no conflicts of interest.
Open Research
DATA AVAILABILITY STATEMENT
The data that support the findings of this study are available from the corresponding author upon reasonable request.
REFERENCES
- 1Noack J, Roznyatovskaya N, Herr T, Fischer P. The chemistry of redox-flow batteries. Angew Chem Int Ed. 2015; 54: 9776-9809.
- 2Alotto P, Guarnieri M, Moro F. Redox flow batteries for the storage of renewable energy: a review. Renew Sustain Energy Rev. 2013; 29: 325-335.
- 3Uddin M, Romlie MF, Abdullah MF, Abd Halim S, Abu Bakar AH, Chia Kwang T. A review on peak load shaving strategies. Renew Sustain Energy Rev. 2018; 82: 3323-3332.
- 4Leung P, Li X, de León CP, Berlouis L, John Low CT, Walsh FC. Progress in redox flow batteries, remaining challenges and their applications in energy storage. RSC Adv. 2012; 2: 10125-10156.
- 5Gencten M, Sahin Y. A critical review on progress of the electrode materials of vanadium redox flow battery. Int. J. Energy Res. 2020; 1–21: 7903-7923. doi:10.1002/er.5487
- 6Kim K, Park M, Kim Y, Kim J, Doub S, Skyllas-Kazacos M. A technology review of electrodes and reaction mechanisms in vanadium redox flow batteries. J Mater Chem A. 2015; 3: 16913-16933.
- 7Amini K, Gostick J, Pritzker M. Metal and metal oxide electrocatalysts for redox flow batteries. Adv Mater. 2020; 30:1910564.
- 8Yuan X, Song C, Platt A, et al. A review of all-vanadium redox flow battery durability: degradation mechanisms and mitigation strategies. Int J Energy Res. 2019; 43: 1-40. doi:10.1002/er.4607
- 9Amini K, Pritzker MD. Electrodeposition and electrodissolution of zinc in mixed methanesulfonate-based electrolytes. Electrochim Acta. 2018; 268: 448-461.
- 10Kocyigit N, Gencten M, Sahin M, Sahin Y. A novel vanadium/cobalt redox couple in aqueous acidic solution for redox flow batteries. Int. J. Energy Res. 2020; 44: 411-424.
- 11Amini K, Pritzker MD. Improvement of zinc-cerium redox flow batteries using mixed methanesulfonate-chloride negative electrolyte. Appl Energy. 2019; 255:113894.
- 12Chakrabarti MH, Hajimolana SA, Mjalli FS, Saleem M, Mustafa I. Redox flow battery for energy storage. Arab J Sci Eng. 2013; 38: 723-739.
- 13Kear G, Shah AA, Walsh FC. Development of the all-vanadium redox flow battery for energy storage: a review of technological, financial and policy aspects. Int. J. Energy Res. 2012; 36: 1105-1120. doi:10.1002/er.1863.
- 14Flox C, Skoumal M, Rubio-Garcia J, Andreu T, Morante JR. Strategies for enhancing electrochemical activity of carbon-based electrodes for all-vanadium redox flow batteries. Appl Energy. 2013; 109: 344-351.
- 15Sánchez-Díez E, Ventosa E, Guarnieri M, et al. Redox flow batteries: status and perspective towards sustainable stationary energy storage. J Power Sources. 2021; 481:228804.
- 16Nikiforidis G, Cartwright R, Hodgson D, Hall D, Berlouis L. Factors affecting the performance of the Zn-Ce redox flow battery. Electrochim Acta. 2014; 140: 139-144.
- 17Govindan M, He K, Moon IS. Evaluation of dual electrochemical cell design for cerium-vanadium redox flow battery to use different combination of electrodes. Int J Electrochem Sci. 2013; 8: 10265-10279.
- 18Li Y, Geysens P, Zhang X, et al. Cerium-containing complexes for low-cost, non-aqueous redox flow batteries (RFBs). J Power Sources. 2020; 450:227634.
- 19Arenas LF, Ponce de León C, Walsh FC. Electrochemical redox processes involving soluble cerium species. Electrochim Acta. 2016; 205: 226-247.
- 20Mepsted GO, Moore JM. Performance and durability of bipolar plate materials. Handbook of Fuel Cells - Fundamentals, Technology and Applications. John Wiley & Sons; 2010; 1-8. doi:10.1002/9780470974001.f303027
10.1002/9780470974001.f303027 Google Scholar
- 21Sankarasubramanian S, Zhang Y, Ramani V. Methanesulfonic acid-based electrode-decoupled vanadium-cerium redox flow battery exhibits significantly improved capacity and cycle life. Sustain Energy Fuels. 2019; 3: 2417-2425.
- 22Gschneidner KA, Bünzli JCG, Pecharsky VK. Handbook on the Physics and Chemistry of Rare Earths. Vol 36; Amsterdam, Netherlands: Elsevier; 2006.
- 23Leung PK, Mohamed MR, Shah AA, Xu Q, Conde-Duran MB. A mixed acid based vanadium-cerium redox flow battery with a zero-gap serpentine architecture. J Power Sources. 2015; 274: 651-658.
- 24Leung PK, Ponce-De-León C, Recio FJ, Herrasti P, Walsh FC. Corrosion of the zinc negative electrode of zinc-cerium hybrid redox flow batteries in methanesulfonic acid batteries. J Appl Electrochem. 2014; 44: 1025-1035.
- 25Di Blasi A, Di Blasi O, Briguglio N, et al. Investigation of several graphite-based electrodes for vanadium redox flow cell. J Power Sources. 2013; 227: 15-23.
- 26Nikiforidis G, Berlouis L, Hall D, Hodgson D. A study of different carbon composite materials for the negative half-cell reaction of the zinc cerium hybrid redox flow cell. Electrochim Acta. 2013; 113: 412-423.
- 27Walsh FC, Poncedeléon C, Berlouis L, et al. The development of Zn-Ce hybrid redox flow batteries for energy storage and their continuing challenges. ChemPlusChem. 2015; 80: 288-311.
- 28Smith R. Characterisation and Surface Modification of Graphitic Felts [PhD thesis]. University of Liverpool; 2018. doi:10.17638/03022752.
10.17638/03022752 Google Scholar
- 29He Z, Jianga Y, Menga W, et al. HF/H2O2 treated graphite felt as the positive electrode for vanadium redox flow battery. Appl Surf Sci. 2017; 423: 111-118.
- 30Shen Y, Xu H, Xu P, Wu X, Dong Y, Lu L. Electrochemical catalytic activity of tungsten trioxide- modified graphite felt toward VO2+/VO2+ redox reaction. Electrochim Acta. 2014; 132: 37-41.
- 31Xiang Y, Daoud WA. Cr2O3-modified graphite felt as a novel positive electrode for vanadium redox flow battery. Electrochim Acta. 2018; 290: 176-184.
- 32Chakrabarti MH, Brandon NP, Hajimolana SA, et al. Application of carbon materials in redox flow batteries. J Power Sources. 2014; 253: 150-166.
- 33Na Z, Wang X, Yin D, Wang L. Graphite felts modified by vertical two-dimensional WO3 nanowall arrays: high-performance electrode materials for cerium-based redox flow batteries. Nanoscale. 2018; 10: 10705-10712.
- 34Li B, Gu M, Nie Z, et al. Bismuth nanoparticle decorating graphite felt as a high-performance electrode for an all-vanadium redox flow battery. Nano Lett. 2013; 13: 1330-1335.
- 35Wang R, Li Y, Wang Y, Fang Z. Phosphorus-doped graphite felt allowing stabilized electrochemical interface and hierarchical pore structure for redox flow battery. Appl Energy. 2020; 261:114369.
- 36Na Z, Wang X, Yin D, Wang L. Tin dioxide as a high-performance catalyst towards Ce(IV)/Ce(III) redox reactions for redox flow battery applications. J Mater Chem A. 2017; 5: 5036-5043.
- 37Bayeh AW, Lin G, Chang Y, et al. Oxygen-vacancy-rich cubic CeO2 nanowires as catalysts for vanadium redox flow batteries. 2020. doi:10.1021/acssuschemeng.0c03861
10.1021/acssuschemeng.0c03861 Google Scholar
- 38Bayeh AW, Kabtamu DM, Chang YC, et al. Ta2O5-nanoparticle-modified graphite felt as a high-performance electrode for a vanadium redox flow battery. ACS Sustain Chem Eng. 2018; 6: 3019-3028.
- 39Xiang Y, Daoud WA. Binary NiCoO2-modified graphite felt as an advanced positive electrode for vanadium redox flow batteries. J Mater Chem A. 2019; 7: 5589-5600.
- 40Castañeda LF, Walsh FC, Nava JL, Ponce de León C. Graphite felt as a versatile electrode material: properties, reaction environment, performance and applications. Electrochim Acta. 2017; 258: 1115-1139.
- 41Huong Le TX, Bechelany M, Cretin M. Carbon felt based-electrodes for energy and environmental applications: a review. Carbon N. Y. 2017; 122: 564-591.
- 42Yin M, Yao Y, Fan H, Liu S. WO3-SnO2 nanosheet composites: hydrothermal synthesis and gas sensing mechanism. J Alloys Compd. 2018; 736: 322-331.
- 43Gao L, Qu F, Wu X. Hierarchical WO3@SnO2 core-shell nanowire arrays on carbon cloth: a new class of anode for high-performance lithium-ion batteries. J Mater Chem A. 2014; 2: 7367-7372.
- 44Kganyago P. WO3-SnO2 Nanostructures Supported on Carbon Nanomaterials for Electrochemical Energy Storage [thesis]. University of Johannesburg; 2017.
- 45Liu S, Ouyang J, Ren J. Mechanism of calcination modification of phosphogypsum and its effect on the hydration properties of phosphogypsum-based supersulfated cement. Construct Build Mater. 2020; 243:118226.
- 46Zhang Y, Li L, Su H, Huang W, Dong X. Binary metal oxide: advanced energy storage materials in supercapacitors. J Mater Chem A. 2015; 3: 43-59.
- 47Zhu L, Zeng W, Li Y. A novel cactus-like WO3-SnO2 nanocomposite and its acetone gas sensing properties. Mater Lett. 2018; 231: 5-7.
- 48Rashad MM, Ibrahim IA, Osama I, Shalan AE. Distinction between SnO2 nanoparticles synthesized using co-precipitation and solvothermal methods for the photovoltaic efficiency of dye-sensitized solar cells. Bull Mater Sci. 2014; 37: 903-909.
- 49Nadarajan R, Abu Bakar WW, Ali R. Effect of calcination temperature on metal oxides and their photocatalytic activity. Adv Mater Res. 2015; 1107: 73-78.
10.4028/www.scientific.net/AMR.1107.73 Google Scholar
- 50Sandin S, Cheritat A, Bäckström J, Cornell A. Deposition efficiency in the preparation of ozone-producing nickel and antimony doped tin oxide anodes. 2017; 7: 51-64.
- 51Na Z, Sun X, Wang L. Surface-functionalized graphite felts: enhanced performance in cerium-based redox flow batteries. Carbon N Y. 2018; 138: 363-368.
- 52Zhou H, Shen Y, Xi J, Qiu X, Chen L. ZrO2-nanoparticle-modified graphite felt: bifunctional effects on vanadium flow batteries. ACS Appl Mater Interfaces. 2016; 8: 15369-15378.
- 53Mehboob S, Ali G, Shin HJ, et al. Enhancing the performance of all-vanadium redox flow batteries by decorating carbon felt electrodes with SnO2 nanoparticles. Appl Energy. 2018; 229: 910-921.
- 54Zhang H, Chen N, Sun C, Luo X. Investigations on physicochemical properties and electrochemical performance of graphite felt and carbon felt for iron-chromium redox flow battery. Int. J. Energy Res. 2020; 44: 3839-3853. doi:10.1002/er.5179
- 55Szuber J, Czempik G, Larciprete R, Koziej D, Adamowicz B. XPS study of the L-CVD deposited SnO2 thin films exposed to oxygen and hydrogen. Thin Solid Films. 2001; 391: 198-203.
- 56Kwoka M, Ottaviano L, Passacantando M, Santucci S, Czempik G, Szuber J. XPS study of the surface chemistry of L-CVD SnO2 thin films after oxidation. Thin Solid Films. 2005; 490: 36-42.
- 57Charton P, Gengembre L, Armand P. TeO2-WO3 glasses: infrared, XPS and XANES structural characterizations. J Solid State Chem. 2002; 168: 175-183.
- 58Kloprogge JT, Wood BJ. Handbook of Mineral Spectroscopy: X-ray Photoelectron Spectra; 1. Amsterdam, Netherlands: Elsevier; 2020. doi:10.1016/c2015-0-01704-x
- 59Kabtamu DM, Chen JY, Chang YC, Wang CH. Water-activated graphite felt as a high-performance electrode for vanadium redox flow batteries. J Power Sources. 2017; 341: 270-279.
- 60Wagner CD, Riggs WM, Davis LE, Moulder JF, Muilenberg GE. Handbook of X-ray Electron Spectroscopy. Vol 192. Eden Prairie, MN: Perkin-Elmer Corporation; 1992.
- 61Yu Y, Tan Y, Zhang H, et al. Hybrid Sn–Co binary oxide nanosheets grown on carbon paper as the supercapacitor electrode materials. J Alloys Compd. 2020; 814:152199.
- 62Wei L, Li J, Tang X. NOx storage at low temperature over MnOx-SnO2 binary metal oxide prepared through different hydrothermal process. Catal Lett. 2009; 127: 107-112.