New zeotype borophosphates with chiral tetrahedral topology: (H)0.5M1.25(H2O)1.5[BP2O8]·H2O (M = Co(II) and Mn(II))
L. Tatar Yįldįrįm
Department of Engineering Physics, Hacettepe University, Beytepe 06800, Ankara, Turkey
Search for more papers by this authorX. Bu
Department of Chemistry and and Biochemistry California State University, Long Beach 1250 Bellflower Blvd. Long Beach, CA 90840-3903, USA
Search for more papers by this authorM. Kizilyalli
Department of Chemistry Middle East Technical University, 06531, Ankara, Turkey
Search for more papers by this authorG. D. Stucky
Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, USA
Search for more papers by this authorL. Tatar Yįldįrįm
Department of Engineering Physics, Hacettepe University, Beytepe 06800, Ankara, Turkey
Search for more papers by this authorX. Bu
Department of Chemistry and and Biochemistry California State University, Long Beach 1250 Bellflower Blvd. Long Beach, CA 90840-3903, USA
Search for more papers by this authorM. Kizilyalli
Department of Chemistry Middle East Technical University, 06531, Ankara, Turkey
Search for more papers by this authorG. D. Stucky
Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, USA
Search for more papers by this authorAbstract
Two new isostructural open-framework zeotype transition metal borophosphate compounds, (H)0.5M1.25(H2O)1.5[BP2O8]·H2O (M = Co(II) and Mn(II)) were synthesized by mild hydrothermal method. The structure of compounds were characterized by single-crystal X-ray diffraction which have ordered, alternating, vertex-sharing BO4, PO4, and (MO4)OM(H2O)2 groups with hexagonal, P 61 2 2 (No 178) space group and unit cell parameters for Co a = 9.4960(6) Å, c = 15.6230(13) Å, for Mn a = 9.6547(12) Å, c = 15.791(3) Å, Z = 1 for both of them. TGA/DTA analysis, IR spectroscopy were used for characterization. Magnetic susceptibility measurements for both of the compound indicate strong antiferromagnetic interaction between metal centers. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)
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