Multiple Interaction Forces Construct Two-Dimensional Self-assembly Kagome Lattices on Au(111)
Yong Zhang
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093 China
These authors made equal contribution.
Search for more papers by this authorCorresponding Author
Jianchen Lu
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093 China
These authors made equal contribution.
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorWuyi Gao
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093 China
These authors made equal contribution.
Search for more papers by this authorYi Zhang
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093 China
These authors made equal contribution.
Search for more papers by this authorNianqiang Li
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093 China
Search for more papers by this authorShicheng Li
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093 China
Search for more papers by this authorGefei Niu
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093 China
Search for more papers by this authorBoyu Fu
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093 China
Search for more papers by this authorCorresponding Author
Lei Gao
Faculty of Science, Kunming University of Science and Technology, Kunming, Yunnan, 650500 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorCorresponding Author
Jinming Cai
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093 China
Southwest United Graduate School, Kunming, Yunnan, 650093 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorYong Zhang
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093 China
These authors made equal contribution.
Search for more papers by this authorCorresponding Author
Jianchen Lu
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093 China
These authors made equal contribution.
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorWuyi Gao
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093 China
These authors made equal contribution.
Search for more papers by this authorYi Zhang
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093 China
These authors made equal contribution.
Search for more papers by this authorNianqiang Li
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093 China
Search for more papers by this authorShicheng Li
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093 China
Search for more papers by this authorGefei Niu
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093 China
Search for more papers by this authorBoyu Fu
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093 China
Search for more papers by this authorCorresponding Author
Lei Gao
Faculty of Science, Kunming University of Science and Technology, Kunming, Yunnan, 650500 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorCorresponding Author
Jinming Cai
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093 China
Southwest United Graduate School, Kunming, Yunnan, 650093 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorComprehensive Summary
Kagome lattices have garnered significant attention due to their promising applications in catalysis, electronics, and magnetics. Although many efforts have been paid to the design and synthesis of Kagome lattices, there is a limited focus on constructing this lattice by multiple interaction forces. In this work, we employ 2,7-dibromo-carbazole as precursors to successfully fabricate the two-dimensional self-assembly Kagome lattices stabled by multiple interaction forces on Au(111) substrate. Using low-temperature scanning tunneling microscopy, non-contact atomic force microscopy and density functional theory calculation, we visualize and identify the four interaction forces within Kagome lattices: Au—N coordination bonds, Au—H hydrogen bonds, Br—Br halogen bonds, and Br—H hydrogen bonds, respectively. This study provides a basic understanding for designing and constructing more complex Kagome lattices.
Supporting Information
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References
- 1 Bian, K.; Gerber, C.; Heinrich, A. Scanning Probe Microscopy. Nat. Rev. Methods Primers 2021, 1, 36.
- 2 Sweetman, A.; Champness, N.; Saywell, A. On-Surface Chemical Reactions Characterised by Ultra-High Resolution Scanning Probe Microscopy. Chem. Soc. Rev. 2020, 49, 4189–4202.
- 3 Zhong, Q.; Li, X.; Zhang, H. Noncontact Atomic Force Microscopy: Bond Imaging and Beyond. Surf. Sci. Rep. 2020, 75, 100509.
- 4 Dong, L.; Gao, Z.; Lin, N. Self-Assembly of Metal–Organic Coordination Structures on Surfaces. Prog. Surf. Sci. 2016, 91, 101–135.
- 5 Clair, S.; De Oteyza, D. Controlling a Chemical Coupling Reaction on a Surface: Tools and Strategies for on-Surface Synthesis. Chem. Rev. 2019, 119, 4717–4776.
- 6 Zhang, Y.; Lu, J.; Zhang, Y. On-Surface Synthesis of Au–C4 and Au–O4 Alternately Arranged Organometallic Coordination Networks via Selective Aromatic C–H Bond Activation. J. Chem. Phys. 2023, 159, 184701.
- 7 Hu, J.; Liang, Z.; Shen, K. Identifying the Convergent Reaction Path from Predesigned Assembled Structures: Dissymmetrical Dehalogenation of Br2Py on Ag (111). Nano Res. 2021, 14, 4704–4713.
- 8 Liu, L.; Timmer, A.; Kolodzeiski, E. Conformational Evolution Following the Sequential Molecular Dehydrogenation of Pmdi on a Cu (111) Surface. Nanoscale Adv. 2021, 3, 6373–6378.
- 9 Yang, B.; Cao, N.; Ju, H. Intermediate States Directed Chiral Transfer on a Silver Surface. J. Am. Chem. Soc. 2018, 141, 168–174.
- 10 Zhang, Z.; Gao, Y.; Yi, Z. Separation of Halogen Atoms by Sodium from Dehalogenative Reactions on a Au (111) Surface. ACS Nano 2024, 18, 9082–9091.
- 11 Gao, Y.; Zhang, Z.; Yi, Z. Visualizing the Hierarchical Evolution of Aryl–Metal Bonding in Organometallic Nanostructures on Ag (111). J. Phys. Chem. Lett. 2023, 14, 10819–10824.
- 12 Ruan, Z.; Li, B.; Lu, J. Real-Space Imaging of a Phenyl Group Migration Reaction on Metal Surfaces. Nat. Commun. 2023, 14, 970.
- 13 Zhang, Y.; Lu, J.; Zhou, H. Highly Regioselective Cyclodehydrogenation of Diphenylporphyrin on Metal Surfaces. ACS Nano 2023, 17, 13575–13583.
- 14 Zuzak, R.; Quiroga, S.; Engelund, M. Sequential on-Surface Cyclodehydrogenation in a Nonplanar Nanographene. J. Phys. Chem. Lett. 2023, 14, 10442–10449.
- 15 Wang, T.; Berdonces-Layunta, A.; Friedrich, N. Aza-Triangulene: On-Surface Synthesis and Electronic and Magnetic Properties. J. Am. Chem. Soc. 2022, 144, 4522–4529.
- 16 Zhong, Q.; Hu, Y.; Niu, K. Benzo-Fused Periacenes or Double Helicenes? Different Cyclodehydrogenation Pathways on Surface and in Solution. J. Am. Chem. Soc. 2019, 141, 7399–7406.
- 17 Cai, J.; Ruffieux, P.; Jaafar, R.; Bieri, M. Atomically Precise Bottom-up Fabrication of Graphene Nanoribbons. Nature 2010, 466, 470–473.
- 18 Zhang, Y.; Lu, J.; Li, Y. On-Surface Synthesis of a Nitrogen-Doped Graphene Nanoribbon with Multiple Substitutional Sites. Angew. Chem. Int. Ed. 2022, 61, e202204736.
- 19 Xu, J.; Xing, S.; Hu, J. Stepwise On-Surface Synthesis of Nitrogen- Doped Porous Carbon Nanoribbons. Commun. Chem. 2024, 7, 40.
- 20 Fan, Q.; Yan, L.; Tripp, M. Biphenylene Network: A Nonbenzenoid Carbon Allotrope. Science 2021, 372, 852–856.
- 21 Ma, K.; Zhang, T.; Qin, Y. Desilylative Coupling Involving C (Sp2)–Si Bond Cleavage on Metal Surfaces. J. Am. Chem. Soc. 2022, 144, 8789–8796.
- 22 Zhang, Y.; Lu, J.; Li, B. On-Surface Synthesis and Characterization of Nitrogen-Doped Covalent-Organic Frameworks on Ag (111) Substrate. J. Chem. Phys. 2022, 157, 031103.
- 23 Liu, C.; Yu, Y.; Zhang, W. Room-Temperature Synthesis of Covalent Organic Frameworks with a Boronic Ester Linkage at the Liquid/Solid Interface. Chem.-Eur. J. 2016, 22, 18412–18418.
- 24 Steiner, C.; Gebhardt, J.; Ammon, M. Hierarchical on-Surface Synthesis and Electronic Structure of Carbonyl-Functionalized One-and Two-Dimensional Covalent Nanoarchitectures. Nat. Commun. 2017, 8, 14765.
- 25 Galeotti, G.; De Marchi, F.; Hamzehpoor, E. Synthesis of Mesoscale Ordered Two-Dimensional Π-Conjugated Polymers with Semiconducting Properties. Nat. Mater. 2020, 19, 874–880.
- 26 Shang, J.; Wang, Y.; Chen, M. Assembling Molecular Sierpiński Triangle Fractals. Nat. Chem. 2015, 7, 389–393.
- 27 Feng, L.; Wang, T.; Tao, Z. Supramolecular Tessellations at Surfaces by Vertex Design. ACS Nano 2019, 13, 10603–10611.
- 28 Zhang, Y.; Paszkiewicz, M.; Du, P. Complex Supramolecular Interfacial Tessellation through Convergent Multi-Step Reaction of a Dissymmetric Simple Organic Precursor. Nat. Chem. 2018, 10, 296–304.
- 29 Liu, J.; Chen, Q.; Cai, K. Stepwise on-Surface Dissymmetric Reaction to Construct Binodal Organometallic Network. Nat. Commun. 2019, 10, 2545.
- 30 Pan, M.; Zhang, X.; Zhou, Y. Growth of Mesoscale Ordered Two-Dimensional Hydrogen-Bond Organic Framework with the Observation of Flat Band. Phys. Rev. Lett. 2023, 130, 036203.
- 31 Pan, W.-C.; Mützel, C.; Haldar, S. Diboraperylene Diborinic Acid Self-Assembly on Ag (111)− Kagome Flat Band Localized States Imaged by Scanning Tunneling Microscopy and Spectroscopy. Angew. Chem. Int. Ed. 2024, e202400313.
- 32
Pawlak, R.; Liu, X.; Ninova, S. On-Surface Synthesis of Nitrogen- Doped Kagome Graphene, Angew. Chem. Int. Ed. 2021, 133, 8451–8456.
10.1002/ange.202016469 Google Scholar
- 33 Mo, Y.-P.; Liu, X.; Wang, D. Concentration-Directed Polymorphic Surface Covalent Organic Frameworks: Rhombus, Parallelogram, and Kagome. ACS Nano 2017, 11, 11694–11700.
- 34
Moulton, B.; Lu, J.; Hajndl, R. Crystal Engineering of a Nanoscale Kagomé Lattice. Agnew. Chem. Int. Ed. 2002, 114, 2945–2948.
10.1002/1521-3757(20020802)114:15<2945::AID-ANGE2945>3.0.CO;2-4 Google Scholar
- 35 Teyssandier, J.; Mali, K.; De Feyter, S. Halogen Bonding in Two-Dimensional Crystal Engineering. ChemistryOpen 2020, 9, 225–241.
- 36 Shi, Z.; Lin, N. Porphyrin-Based Two-Dimensional Coordination Kagome Lattice Self-Assembled on a Au (111) Surface. J. Am. Chem. Soc. 2009, 131, 5376–5377.
- 37 Xiong, J.; Qin, T.; Hu, L. On-Surface Synthesis of Novel Kagome Lattices Coordinated Via Four-Fold N–Ag Bonding. J. Phys. Chem. Lett. 2023, 14, 9787–9792.
- 38 Wang, T.; Fan, Q.; Feng, L. Chiral Kagome Lattices from on-Surface Synthesized Molecules. ChemPhysChem 2017, 18, 3329–3333.
- 39 Wang, J.; Zheng, Y.; Nie, X. Constructing and Transferring Two-Dimensional Tessellation Kagome Lattices via Chemical Reactions on Cu(111) Surface. J. Phys. Chem. Lett. 2021, 12, 8151–8156.
- 40 Wang, D.; Wang, Z.; Liu, W. Real-Space Investigation of the Multiple Halogen Bonds by Ultrahigh-Resolution Scanning Probe Microscopy. Small 2022, 18, 2202368.
- 41 Kang, F.; Sun, L.; Gao, W. On-Surface Synthesis of a Carbon Nanoribbon Composed of 4–5–6–8-Membered Rings. ACS Nano 2023, 17, 8717–8722.
- 42 Lawrence, J.; Sosso, G.; Đorđević, L. Combining High-Resolution Scanning Tunnelling Microscopy and First-Principles Simulations to Identify Halogen Bonding. Nat. Commun. 2020, 11, 2103.
- 43 Song, L.; Yang, B.; Fan, X. Intra-and Inter-Self-Assembly of Identical Supramolecules on Silver Surfaces. J. Phys. Chem. Lett. 2022, 13, 8902–8907.
- 44 Xiong, W.; Lu, J.; Geng, J. Atomic-scale construction and characterization of quantum dots array and poly-fluorene chains via 2,7-dibromofluorene on Au(111). Appl. Surf. Sci. 2023, 609, 155315.
- 45 Piquero-Zulaica, J.; Lobo-Checa, J.; Lobo-Checa, A. Precise engineering of quantum dot array coupling through their barrier widths. Nat. Commun. 2017, 8, 787.
- 46 Horcas, I.; Fernández, R.; Gomez-Rodriguez, J. Wsxm: A Software for Scanning Probe Microscopy and a Tool for Nanotechnology. Rev. Sci. Instrum. 2007, 78, 013705.
- 47 Kresse, G.; Furthmüller, J. Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comp. Mater. Sci. 1996, 6, 15–50.
- 48 Humphrey, W.; Dalke, A.; Schulten, K. VMD: visual molecular dynamics. J. Mol. Graph. 1996, 14, 33.
- 49 Lu, T.; Chen, F. Multiwfn: A multifunctional wavefunction analyzer. J. Comp. Chem. 2012, 33, 580–592.