Elevating Latent Fingerprint Visualization: Sebaceous Fingerprint Residues-Responsive Fluorescent Powders for Colour-Changing Visual Enhancement
Ying Fang
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, 266042 China
State Key Laboratory of Bioactive Substances and Function of Natural Medicine, Institute of Materia Medica, Peking Union Medical College and Chinese Academy of Medical Sciences, Beijing, 100050 China
Search for more papers by this authorJun-Yu Luan
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, 266042 China
Search for more papers by this authorJian-Shu Zhao
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, 266042 China
Search for more papers by this authorXiu-Rong Kao
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, 266042 China
Search for more papers by this authorHao-Rui Song
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, 266042 China
Search for more papers by this authorYi-Ning Luo
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, 266042 China
Search for more papers by this authorCorresponding Author
Kun-Peng Wang
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, 266042 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorShaojin Chen
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, 266042 China
Search for more papers by this authorCorresponding Author
Hai-Yu Hu
State Key Laboratory of Bioactive Substances and Function of Natural Medicine, Institute of Materia Medica, Peking Union Medical College and Chinese Academy of Medical Sciences, Beijing, 100050 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorCorresponding Author
Zhi-Qiang Hu
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, 266042 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorYing Fang
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, 266042 China
State Key Laboratory of Bioactive Substances and Function of Natural Medicine, Institute of Materia Medica, Peking Union Medical College and Chinese Academy of Medical Sciences, Beijing, 100050 China
Search for more papers by this authorJun-Yu Luan
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, 266042 China
Search for more papers by this authorJian-Shu Zhao
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, 266042 China
Search for more papers by this authorXiu-Rong Kao
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, 266042 China
Search for more papers by this authorHao-Rui Song
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, 266042 China
Search for more papers by this authorYi-Ning Luo
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, 266042 China
Search for more papers by this authorCorresponding Author
Kun-Peng Wang
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, 266042 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorShaojin Chen
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, 266042 China
Search for more papers by this authorCorresponding Author
Hai-Yu Hu
State Key Laboratory of Bioactive Substances and Function of Natural Medicine, Institute of Materia Medica, Peking Union Medical College and Chinese Academy of Medical Sciences, Beijing, 100050 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorCorresponding Author
Zhi-Qiang Hu
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong, 266042 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorComprehensive Summary
A new fluorescent fingerprint powder (DFF-MMT) was formulated by blending cyclic chalcone dye DFF with montmorillonite (MMT), which can develop latent fingerprints (LFPs) with exceptional resolution and contrast on various surfaces, including ordinary glass, tin foil, marble, LED screens, and materials with distinct colors and fluorescent backgrounds. The fluorescence of DFF-MMT transforms from orange to bright yellow with LFPs, allowing for a flawless visualization of fingerprints on uneven surfaces or materials with static electricity. Impressively, fingerprints developed by DFF-MMT can be stored for over 21 months and conveniently duplicated. The developed LFPs by DFF-MMT still keep high quality under the influence of aquatic condition, illumination and thermal effects. DFF-MMT also exhibits benefits, such as affordability, real-time, high-resolution, high-contrast development and no damage to DNA, making it an ideal choice for sophisticated criminal investigations.
Supporting Information
Filename | Description |
---|---|
cjoc202400305-sup-0001-supinfo.pdfPDF document, 2.8 MB |
Appendix S1: Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1(a) Winslow, C.-E. A. The Untilled Fields of Public Health. Science 1920, 51, 23–33; (b) Ifa, D. R.; Manicke, N. E.; Dill, A. L.; Cooks, R. G. Latent Fingerprint Chemical Imaging by Mass Spectrometry. Science 2008, 321, 805–805; (c) Ehlinger, E. P.; Necarez, C. R. Safe and Accessible Voting: The Role of Public Health. Am. J. Public Health 2021, 111 45–46; (d) Murphy, S. A.; Jani, D. D.; Elder, J. M. Public Health Integration into Public Safety in Post-Katrina New Orleans. Am. J. Public Health 2020, 110, 1490–1503.
- 2(a) Sledge, D.; Thomas, H. F. From Disaster Response to Community Recovery: Nongovernmental Entities, Government. Am. J. Public Health 2019, 109, 437–444; (b) Chu, H.; Yang, L.; Yu, L.; Kim, J.; Zhou, J.; Li, M.; Kim, J. S. Fluorescent Probes in Public Health and Public Safety. Coord. Chem. Rev. 2021, 449, 214208.
- 3(a) Ansari, A. A.; Aldajani, K. M.; AlHazaa, A. N.; Albrithen, H. A. Recent Progress of Fluorescent Materials for Fingermarks Detection in Forensic Science and Anti-Counterfeiting. Coord. Chem. Rev. 2022, 462, 214523; (b) Prabakaran, E.; Pillay, K. Nanomaterials for Latent Fingerprint Detection: A Review. J. Mater. Res. Technol. 2021, 12, 1856–1885.
- 4(a) Wang, M.; Li, M.; Yu, A.; Zhu, Y.; Yang, M.; Mao, C. Fluorescent Nanomaterials for the Development of Latent Fingerprints in Forensic Sciences. Adv. Funct. Mater. 2017, 27, 1606243; (b) Song, K.; Huang, P.; Yi, C.; Ning, B.; Hu, S.; Nie, L.; Chen, X.; Nie, Z. Photoacoustic and Colorimetric Visualization of Latent Fingerprints. ACS Nano 2015, 9, 12344–12348; (c) Fan, Z.; Zhang, C.; Chen, J.; Ma, R.; Lu, Y.; Wu, J.; Fan, L. Highly Stable, Nondestructive, and Simple Visualization of Latent Blood Fingerprints Based on Covalent Bonding Between the Fluorescent Conjugated Polymer and Proteins in Blood. ACS Appl. Mater. Interfaces 2021, 13, 15621–15632.
- 5(a) Duan, L.; Zheng, Q.; Tu, T. Instantaneous High-Resolution Visual Imaging of Latent Fingerprints in Water Using Color-Tunable AIE Pincer Complexes. Adv. Mater. 2022, 34, 2202540; (b) Zhang, Y.; Zhang, L. Designed Multifunctional Ratiometric Fluorescent Probe for Directly Detecting Fluoride Ion/Dichromate and Indirectly Monitoring Urea. J. Hazard. Mater. 2021, 418, 126271; (c) Wang, Y.; Li, C.; Qu, H.; Fan, C.; Zhao, P.; Tian, R.; Zhu, M. Real-Time Fluorescence in Situ Visualization of Latent Fingerprints Exceeding Level 3 Details Based on Aggregation-Induced Emission. J. Am. Chem. Soc. 2020, 142, 7497–7505.
- 6(a) Qiu, Z.; Hao, B.; Gu, X.; Wang, Z.; Xie, N.; Lam, J. W. Y.; Hao, H.; Tang, B. Z. A General Powder Dusting Method for Latent Fingerprint Development Based on AIEgens. Sci. China Chem. 2018, 61, 966–970;
(b) Hai, J.; Li, T.; Su, J.; Liu, W.; Ju, Y.; Wang, B.; Hou, Y. Reversible Response of Luminescent Terbium(III)–Nanocellulose Hydrogels to Anions for Latent Fingerprint Detection and Encryption. Angew. Chem. Int. Ed. 2018, 57, 6789–6790;
10.1002/anie.201800119 Google Scholar(c) Machado, T. R.; Silva, J. S.; Miranda, R. R.; Zucolotto, V.; Li, M. S.; Yuso, M. V. M.; Guerrero-Gonźalez, J. J.; Rosa, I. L. V.; Algarra, M.; Longo, E. Amorphous Calcium Phosphate Nanoparticles Allow Fingerprint Detection via Self-Activated Luminescence. Chem. Eng. J. 2022, 443, 136443.
- 7(a) Barrio, J.; Barzilai, S.; Karjule, N.; Amo-Ochoa, P.; Zamora, F.; Shalom, M. Fluorescent Carbon Nitride Macrostructures Derived from Triazine-Based Cocrystals. Adv. Opt. Mater. 2021, 9, 2100683; (b) Han, X.; Zong, Q.; Han, Y.; Chen, C. Pagoda[5]arene with Large and Rigid Cavity for the Formation of 1:2 Host-Guest Complexes and Acid/Base-Responsive Crystalline Vapochromic Properties. CCS Chem. 2022, 4, 318–330; (c) Zhao, W.; Y. Wang, Y.; Wan, S.; Lu, H.; Li, M.; Chen, C. Chiral Thermally Activated Delayed Fluorescence-Active Macrocycles Displaying Efficient Circularly Polarized Electroluminescence. CCS Chem. 2022, 4, 3540–3548.
- 8(a) Chen, Y.; Li, A.; Li, X.; Tu, L.; Xie, Y.; Xu, S.; Li, Z. Multi-Stimuli-Responsive Amphiphilic Pyridinium Salt and Its Application in the Visualization of Level 3 Details in Latent Fingerprints. Adv. Mater. 2023, 35, 2211917;
(b) Wang, J.; Wei, T.; Li, X.; Zhang, B.; Wang, J.; Huang, C.; Yuan, Q. Near-Infrared-Light-Mediated Imaging of Latent Fingerprints based on Molecular Recognition. Angew. Chem. Int. Ed. 2014, 126, 1642–1646.
10.1002/ange.201308843 Google Scholar
- 9(a) Yu, B.; Liu, S.; Xie, W.; Pan, P.; Zhou, P.; Zou, Y.; Yue, Q.; Deng, Y. Versatile Core–Shell Magnetic Fluorescent Mesoporous Microspheres for Multilevel Latent Fingerprints Magneto-Optic Information Recognition. InfoMat 2022, 4, e12289; (b) Lyu, J.; Gao, Y.; Zhang, Z.; Greiser, U.; Tai, H.; Wang, W. Can Flory-Stockmayer Theory Be Applied to Predict Conventional Free Radical Polymerization of Multivinyl Monomers: A Study via Monte Carlo Simulations. Sci. China Chem. 2018, 61, 319–327.
- 10(a) Jung, H.; Cho, K.; Ryu, S.; Takagi, Y.; Roche, P. A.; Neuman, K. C. Biocompatible Fluorescent Nanodiamonds as Multifunctional Optical Probes for Latent Fingerprint Detection. ACS Appl. Mater. Interfaces 2020, 12, 6641–6650; (b) Duan, Y.; Tian, H.; Li, H.; Wang, K.; Chen, S.; Guo, D.; Hu, Z. A Host-Dye Complex for Sensitive Fluorescence Detection and Clearing of Spermine in Cells. Sens. Actuators, B 2023, 386, 133757.
- 11(a) Lei, Z.; Ling, X.; Mei, Q.; Fu, S.; Zhang, J.; Zhang, Y. An Excitation Navigating Energy Migration of Lanthanide Ions in Upconversion Nanoparticles. Adv. Mater. 2020, 32, 1906225;
(b) Xu, L.; Li, Y.; Wu, S.; Liu, X.; Su, B. Imaging Latent Fingerprints by Electrochemiluminescence. Angew. Chem. Int. Ed. 2012, 51, 8068–8072;
(c) Liang, K.; Carbonell, C.; Styles, M. J.; Ricco, R.; Cui, J.; Richardson, J. J.; Maspoch, D.; Caruso, F.; Falcaro, P. Biomimetic Replication of Microscopic Metal–Organic Framework Patterns Using Printed Protein Patterns. Adv. Mater. 2015, 45, 7293–7298.
10.1002/adma.201503167 Google Scholar
- 12(a) Zhang, Z.; Zhao, X.; Zhang, X.; Hou, X.; Ma, X.; Tang, S.; Zhang, Y.; Xu, G.; Liu, Q.; Long, S. In-Sensor Reservoir Computing System for Latent Fingerprint Recognition with Deep Ultraviolet Photo-Synapses and Memristor Array. Nat. Commun. 2022, 13, 6590; (b) Cheng, X.; Wang, Z.; Tang, B.; Zhang, H.; Qin, A.; Sun, J. Z.; Tang, B. Z. Diversified Photo/Electronic Functions Based on a Simple Chalcone Skeleton: Effects of Substitution Pattern and Molecular Packing. Adv. Funct. Mater. 2018, 28, 1706506; (c) Yang, S.; Wang, C.; Chen, S. A Release-Induced Response for the Rapid Recognition of Latent Fingerprints and Formation of Inkjet-Printed Patterns. Angew. Chem. Int. Ed. 2011, 50, 3706–3709; (d) Li, J.; Jiao, Z.; Zhang, P.; Wan, X.; Song, C.; Guo, Z.; Huang, X.; Tang, B. Z. Development of AIEgen–Montmorillonite Nanocomposite Powders for Computer-Assisted Visualization of Latent Fingermarks. Mater. Chem. Front. 2020, 4, 2131–2136.
- 13(a) Zhuang, C.; Zhang, W.; Sheng, C.; Zhang, W.; Xing, C.; Miao, Z. Chalcone: A Privileged Structure in Medicinal Chemistry. Chem. Rev. 2017, 117, 7762–7810; (b) Ren, T.; Xu, W.; Zhang, Q.; Zhang, X.; Wen, S.; Yi, H.; Yuan, L.; Zhang, X. Enhancing the Anti-Solvatochromic Two-Photon Fluorescence for Cirrhosis Imaging by Forming a Hydrogen-Bond Network. Angew. Chem. Int. Ed. 2018, 57, 7473–7477.
- 14CCDC-2206553 (G) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data.request/cif.
- 15(a) Hao, Q.; Ren, X.; Chen, Y.; Zhao, C.; Xu, J.; Wang, D.; Liu, H. A Sweat-Responsive Covalent Organic Framework Film for Material-Based Liveness Detection and Sweat Pore Analysis. Nat. Commun. 2023, 14, 578; (b) Zhang, Y.; Han, L.; Li, B.; Xu, Y. Improved Stability of All-InorGanic Perovskite Nanocrystals in Hierarchical ZSM-5 Zeolites for Multimodal Applications. Chem. Eng. J. 2022, 437, 135290; (c) Bi, X.; Shi, Y.; Peng, T.; Yue, S.; Wang, F.; Zheng, L.; Cao, Q. Multi-Stimuli Responsive and Multicolor Adjustable Pure Organic Room Temperature Fluorescence-Phosphorescent Dual-Emission Materials. Adv. Funct. Mater. 2021, 31, 2101312.
- 16(a) Fan, Z.; Chen, X.; Kong, R.; Lu, Y.; Ma, R.; Wu, J.; Fan, L. Strongly Fluorescent Conjugated Polymer Nanoparticles in Aqueous Colloidal Solution for Universal, Efficient and Effective Development of Sebaceous and Blood Fingerprints. J. Colloid. Interface Sci. 2023, 642, 658–668; (b) Fang, Y.; Wang, J.; Yu, H.; Zhang, Q.; Chen, S.; Wang, K.; Hu, Z. A Sequential Dual-Key-Dual-Lock Fluorescent Probe for Detection of SO2 and H2O2 in Cells and Mice. Sens. Actuators, B 2022, 371, 132514.
- 17(a) Wang, M.; Song, R.; Yang, D.; Lv, J. Asymmetric Binary Acid Catalysis: Switchable Enantioselectivity in Enantioselective Conjugate Hydride Reduction. Org. Lett. 2023, 25, 373–377; (b) Fang, Y.; Chen, R.; Qin, H.; Wang, J.; Zhang, Q.; Chen, S.; Wen, Y.; Wang, K.; Hu, Z. A Chromene Based Fluorescence Probe: Accurate Detection of Peroxynitrite in Mitochondria, Not Elsewhere. Sens. Actuators, B 2021, 334, 129603.
- 18(a) Tan, J.; Xu, L.; Li, T.; Su, B.; Wu, J. Image-Contrast Technology Based on the Electrochemiluminescence of Porous Silicon and Its Application in Fingerprint Visualization. Angew. Chem. Int. Ed. 2014, 126, 9980–9984;
10.1002/ange.201404948 Google Scholar(b) Wolfbeis, O. S. Nanoparticle-Enhanced Fluorescence Imaging of Latent Fingerprints Reveals Drug Abuse. Angew. Chem. Int. Ed. 2009, 48, 2268–2269; (c) Shi, G.; Yu, Z.; Wang, Y.; Zhang, Q.; Chen, S.; Xu, L.; Wang, K.; Hu, Z. Imidazobenzothiadiazole: A New Multifunction Dyes for Mechanochromic Luminescence, Acid Responsing and Mitochondrial Staining. Dyes Pigm. 2022, 205, 110531.
- 19 Gao, M.; Su, H.; Li, S.; Lin, Y.; Ling, X.; Qin, A.; Tang, B. Z. An Easily Accessible Aggregation-Induced Emission Probe for Lipid Droplet- Specific Imaging and Movement Tracking. Chem. Commun. 2017, 53, 921–924.