Sulfate Binding with a Tripodal Tris(4-pyridylurea) Receptor
Rui Zhang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shannxi 710069, China
Search for more papers by this authorYanlei Zhang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shannxi 710069, China
Search for more papers by this authorJiamin Wang
State Key Laboratory for Oxo Synthesis & Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, Gansu 730000, China
Search for more papers by this authorLiguo Ji
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shannxi 710069, China
Search for more papers by this authorXiaojuan Huang
State Key Laboratory for Oxo Synthesis & Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, Gansu 730000, China
Search for more papers by this authorCorresponding Author
Biao Wu
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shannxi 710069, China
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shannxi 710069, ChinaSearch for more papers by this authorRui Zhang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shannxi 710069, China
Search for more papers by this authorYanlei Zhang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shannxi 710069, China
Search for more papers by this authorJiamin Wang
State Key Laboratory for Oxo Synthesis & Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, Gansu 730000, China
Search for more papers by this authorLiguo Ji
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shannxi 710069, China
Search for more papers by this authorXiaojuan Huang
State Key Laboratory for Oxo Synthesis & Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, Gansu 730000, China
Search for more papers by this authorCorresponding Author
Biao Wu
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shannxi 710069, China
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shannxi 710069, ChinaSearch for more papers by this authorAbstract
The tris(2-aminoethyl)amine (tren)-based tris(4-pyridylurea) receptor L has been synthesized and its anion binding properties were studied. The ligand forms a 2:1 (host/guest) complex with MgSO4, [SO42−⊂L2], in which a sulfate ion is encapsulated by six urea groups from the two ligands through multiple hydrogen bonds. The metal ions do not coordinate to the pyridyl groups but exist as the hydrate [Mg(H2O)6]2+ and interact with the [SO4⊂L2] capsules in the outer coordination sphere to form a three dimensional extended structure. The anion binding behavior of ligand L in solution was studied.
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