Volume 85, Issue 4 pp. 461-466
Communication

Reaction Engineering Investigations of the Partial Oxidation of o-Xylene in the Explosion Regime – Microfixed Bed versus Catalyst Coating

Thomas Lange

Corresponding Author

Thomas Lange

University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany

University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, GermanySearch for more papers by this author
Sebastian Heinrich

Sebastian Heinrich

Federal Institute for Materials Research and Testing, Unter den Eichen 87, 12205 Berlin, Germany

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Dr.-Ing. Christian Liebner

Dr.-Ing. Christian Liebner

Federal Institute for Materials Research and Testing, Unter den Eichen 87, 12205 Berlin, Germany

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Dr. Hartmut Hieronymus

Dr. Hartmut Hieronymus

Federal Institute for Materials Research and Testing, Unter den Eichen 87, 12205 Berlin, Germany

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Prof. Dr.-Ing. Elias Klemm

Prof. Dr.-Ing. Elias Klemm

University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany

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First published: 18 February 2013

Abstract

The selective gas phase oxidation of o-xylene was investigated inside of the explosion regime using a microstructured reactor. The V2O5/TiO2 catalyst was used as microfixed bed and as catalyst coating. There were no significant losses of the selectivity to phthalic anhydride with feed compositions up to 7 vol % o-xylene observable. Above 7 vol % the selectivity decreased due to total oxidation, especially for the microfixed bed, which was probably caused by a hotspot.

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