Research Article

Determination of Pitzer Parameters for 1-1 Nitrate and 1-2 Sulfate Solutions from Freezing Point Data

Corresponding Author

Mehdi Hasan

[email protected]

Department of Chemical Technology, Lappeenranta University of Technology, Lappeenranta, Finland.

Department of Chemical Technology, Lappeenranta University of Technology, Lappeenranta, Finland.===Search for more papers by this author

Marjatta Louhi-Kultanen,

Marjatta Louhi-Kultanen

Department of Chemical Technology, Lappeenranta University of Technology, Lappeenranta, Finland.

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Mehdi Hasan,

Corresponding Author

Mehdi Hasan

[email protected]

Department of Chemical Technology, Lappeenranta University of Technology, Lappeenranta, Finland.

Department of Chemical Technology, Lappeenranta University of Technology, Lappeenranta, Finland.===Search for more papers by this author

Marjatta Louhi-Kultanen,

Marjatta Louhi-Kultanen

Department of Chemical Technology, Lappeenranta University of Technology, Lappeenranta, Finland.

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First published: 24 July 2014

https://doi.org/10.1002/ceat.201400202

Citations: 5

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Abstract

Freezing point depression (FDP) modeling was performed for selected aqueous nitrate and sulfate salt solutions to evaluate Pitzer ion interaction parameter values at 273.15 K. 1-1 and 1-2 electrolyte solutions of NaNO₃, KNO₃, NH₄NO₃, Na₂SO₄, K₂SO₄, and (NH₄)₂SO₄ were studied. New Pitzer parameter values of β⁰, β¹, and C^ϕ were obtained for the studied electrolyte solutions. FDP modeling was also used to determine temperature derivatives of interaction parameters for the Pitzer model for selected salt solutions. Osmotic and activity coefficients using the new parameter values are also presented.

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Volume37, Issue8

Special Issue:Industrial Crystallization

August, 2014

Pages 1340-1346

Determination of Pitzer Parameters for 1-1 Nitrate and 1-2 Sulfate Solutions from Freezing Point Data

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Determination of Pitzer Parameters for 1-1 Nitrate and 1-2 Sulfate Solutions from Freezing Point Data

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