Anomalous Swelling Behavior of Graded Rubber
Corresponding Author
Quoc-Viet Do
School of Materials Science, Japan Advanced Institute of Science and Technology, Nomi, Ishikawa, Japan
Correspondence:
Quoc-Viet Do ([email protected])
Contribution: Conceptualization (lead), Data curation (lead), Formal analysis (lead), Methodology (lead), Writing - original draft (lead), Writing - review & editing (lead)
Search for more papers by this authorMasayuki Yamaguchi
School of Materials Science, Japan Advanced Institute of Science and Technology, Nomi, Ishikawa, Japan
Contribution: Conceptualization (equal), Methodology (supporting), Project administration (lead), Supervision (lead), Validation (lead), Visualization (equal), Writing - review & editing (equal)
Search for more papers by this authorVu Anh Doan
School of Materials Science and Engineering, Hanoi University of Science and Technology, Hanoi, Vietnam
Contribution: Supervision (supporting), Validation (supporting), Visualization (supporting)
Search for more papers by this authorCorresponding Author
Quoc-Viet Do
School of Materials Science, Japan Advanced Institute of Science and Technology, Nomi, Ishikawa, Japan
Correspondence:
Quoc-Viet Do ([email protected])
Contribution: Conceptualization (lead), Data curation (lead), Formal analysis (lead), Methodology (lead), Writing - original draft (lead), Writing - review & editing (lead)
Search for more papers by this authorMasayuki Yamaguchi
School of Materials Science, Japan Advanced Institute of Science and Technology, Nomi, Ishikawa, Japan
Contribution: Conceptualization (equal), Methodology (supporting), Project administration (lead), Supervision (lead), Validation (lead), Visualization (equal), Writing - review & editing (equal)
Search for more papers by this authorVu Anh Doan
School of Materials Science and Engineering, Hanoi University of Science and Technology, Hanoi, Vietnam
Contribution: Supervision (supporting), Validation (supporting), Visualization (supporting)
Search for more papers by this authorFunding: The authors received no specific funding for this work.
ABSTRACT
This study demonstrated the anomalous swelling behavior of graded rubber in toluene at 25°C. Ethylene-propylene rubber with a graded crosslink density in the thickness direction was prepared using a compression molding machine, under a temperature gradient (upper temperature: 200°C, lower temperature: 150°C). The crosslink densities of each surface of graded rubber corresponded to those of the homogeneous samples, which were 3.39 × 10−6 mol/cm3 and 3.74 × 10−7 mol/cm3 for samples crosslinked at 200°C and 150°C, respectively. The swelling behavior of graded rubber occurred in two distinct states: (1) after 20 min (short period), the rubber bent concavely toward the low-crosslink side, and (2) after 540 min (long period), it bent toward the high-crosslink side. According to Flory–Rehner's theory, the low-crosslink side is expected to be on the outer side. However, in the state (1), the high-crosslink side became the outer side. The possible mechanism can be explained by the theory of gel under constrained swelling. The unswollen region restricts in-plane expansion of the low-crosslink region, causing inhomogeneous stress that bent graded rubber toward the low-crosslink side in state (1). These findings introduce a novel method for developing soft robotic actuators and self-shaping materials.
Conflicts of Interest
The authors declare no conflicts of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
Filename | Description |
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app56782-sup-0001-Supinfo.docxWord 2007 document , 1.4 MB |
Data S1. Supporting Information. |
app56782-sup-0002-MovieS1.mp4MPEG-4 video, 4.6 MB |
Movie S1. Gripping processes of G200/150 actuator in toluene at 25°C. The video is displayed at its 10 times speed. |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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