Volume 139, Issue 16 52004

ARTICLE

Environment-tolerant conductive and superhydrophobic poly(m-phenylene isophthalamide) fabric prepared via γ-ray activation and reduced graphene oxide/nano SiO₂ modification

Taolin Li

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

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Lin Zou,

Lin Zou

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

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Kaichang Cheng,

Kaichang Cheng

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

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Xiang Liu,

Xiang Liu

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

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Honghui Shi,

Honghui Shi

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

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Qingqing Yang,

Qingqing Yang

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

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Baobao Chang,

Corresponding Author

Baobao Chang

[email protected]

orcid.org/0000-0003-0886-325X

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

Correspondence

Baobao Chang, Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou 450002, China.

Email: [email protected]

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Xianzhang Shi,

Xianzhang Shi

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

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Jialu Ma,

Jialu Ma

National Key Laboratory of Human Factors Engineering, China Astronauts Research and Training Center, Beijing, China

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Chuntai Liu,

Chuntai Liu

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

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Changyu Shen,

Changyu Shen

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

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Taolin Li,

Taolin Li

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

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Lin Zou,

Lin Zou

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

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Kaichang Cheng,

Kaichang Cheng

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

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Xiang Liu,

Xiang Liu

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

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Honghui Shi,

Honghui Shi

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

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Qingqing Yang,

Qingqing Yang

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

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Baobao Chang,

Corresponding Author

Baobao Chang

[email protected]

orcid.org/0000-0003-0886-325X

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

Correspondence

Email: [email protected]

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Xianzhang Shi,

Xianzhang Shi

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

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Jialu Ma,

Jialu Ma

National Key Laboratory of Human Factors Engineering, China Astronauts Research and Training Center, Beijing, China

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Chuntai Liu,

Chuntai Liu

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

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Changyu Shen,

Changyu Shen

Key Laboratory of Materials Processing and Mold, Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China

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First published: 06 December 2021

https://doi.org/10.1002/app.52004

Funding information: China Postdoctoral Science Foundation, Grant/Award Number: 2019M652571; National Natural Science Foundation of China, Grant/Award Number: 52003249; Natural Science Foundation of Henan, Grant/Award Number: 202300410426; Open Funding Project of National Key Laboratory of Human Factors Engineering, Grant/Award Number: SYFD061910K

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Abstract

As one of the high-performance polymer fibers, poly(m-phenylene isophthalamide) (PMIA) is widely used in the area of military and aerospace applications. Whereas, its insulation and hydrophilic nature may lead to electric charge accumulation and dust adherence. This work aims to fabricate a PMIA fabric with integrated conductive and superhydrophobic abilities via a simple method including γ-ray irradiation and dip-coating. Results show that after γ-ray irradiation, the surface roughness of PMIA was enhanced and the content of the oxygen element was increased. In the dip-coating step, the micro-pits and grooves on the surface of PMIA were covered totally by a layer of graphene oxide (GO). After reduction to reduced GO (rGO), a conductive network was built. The conductivity of the fabric was decreased to a minimum value of 0.5 Ω m. Meanwhile, the quite low volume resistivity was retained as 1H, 1H, 2H, 2H-perfluorooctyltriethoxysilane (PFTS)/hydrophobic fumed silica nanoparticles (SiO₂) was decorated on rGO. Due to the microscale aggregation constituted by nano-SiO₂, the fabric presented a superhydrophobic property and self-cleaning ability against simulated Lunar dust. Furthermore, the durability performance proves that an excellent environment-tolerant ability has been endowed to the PMIA fabric by the modification.

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The authors declare no conflicts of interest.

Supporting Information

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Volume139, Issue16

April 20, 2022

52004

Environment-tolerant conductive and superhydrophobic poly(m-phenylene isophthalamide) fabric prepared via γ-ray activation and reduced graphene oxide/nano SiO₂ modification

Abstract

CONFLICT OF INTEREST

Supporting Information

REFERENCES

References

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Environment-tolerant conductive and superhydrophobic poly(m-phenylene isophthalamide) fabric prepared via γ-ray activation and reduced graphene oxide/nano SiO2 modification

Abstract

CONFLICT OF INTEREST

Supporting Information

REFERENCES

References

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Environment-tolerant conductive and superhydrophobic poly(m-phenylene isophthalamide) fabric prepared via γ-ray activation and reduced graphene oxide/nano SiO₂ modification