Volume 133, Issue 48
Article

Effects of butyl acrylate modified polypropylene on structural and thermal properties of foamed polypropylene

Lifen Su

Corresponding Author

Lifen Su

Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China

Key Laboratory of Renewable Energy, Chinese Academy of Sciences, Guangzhou, 510640 China

Correspondence to: L. Su (E-mail: [email protected]) and R. Xia (E-mail: [email protected])Search for more papers by this author
Wei Zhang

Wei Zhang

Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China

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Ru Xia

Corresponding Author

Ru Xia

Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China

Correspondence to: L. Su (E-mail: [email protected]) and R. Xia (E-mail: [email protected])Search for more papers by this author
Jibin Miao

Jibin Miao

Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China

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Bin Yang

Bin Yang

Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China

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Jiasheng Qian

Jiasheng Qian

Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China

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Fang Ruan

Fang Ruan

Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China

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Zhengzhi Zheng

Zhengzhi Zheng

Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China

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First published: 26 August 2016
Citations: 1

ABSTRACT

In this work, the melt strength of PP matrix was reinforced by crosslinking-modified PP (CM-PP) which was yielded by peroxide-initiated crosslinking of linear PP with butyl acrylate (BA). The nano-silica aerogel (nano-SiO2) worked as a nucleating agent for foaming. The effects of CM-PP with the various contents of BA on the foaming behavior and thermal property of PP were studied by measurements of density, thermal conductivity, Vicat softening temperature and SEM. The results showed that the foamed PP got the best properties when the crosslinking PP modified with the weight ratio of butyl acrylate was 10 wt %. The density of the obtained foamed PP with uniform closed cells was as low as 0.23 g/cm3, the thermal conductivity was 0.044 W/(m K), and the Vicat softening temperature was 120  °C. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 44340.

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