Effects of butyl acrylate modified polypropylene on structural and thermal properties of foamed polypropylene
Corresponding Author
Lifen Su
Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China
Key Laboratory of Renewable Energy, Chinese Academy of Sciences, Guangzhou, 510640 China
Correspondence to: L. Su (E-mail: [email protected]) and R. Xia (E-mail: [email protected])Search for more papers by this authorWei Zhang
Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China
Search for more papers by this authorCorresponding Author
Ru Xia
Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China
Correspondence to: L. Su (E-mail: [email protected]) and R. Xia (E-mail: [email protected])Search for more papers by this authorJibin Miao
Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China
Search for more papers by this authorBin Yang
Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China
Search for more papers by this authorJiasheng Qian
Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China
Search for more papers by this authorFang Ruan
Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China
Search for more papers by this authorZhengzhi Zheng
Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China
Search for more papers by this authorCorresponding Author
Lifen Su
Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China
Key Laboratory of Renewable Energy, Chinese Academy of Sciences, Guangzhou, 510640 China
Correspondence to: L. Su (E-mail: [email protected]) and R. Xia (E-mail: [email protected])Search for more papers by this authorWei Zhang
Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China
Search for more papers by this authorCorresponding Author
Ru Xia
Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China
Correspondence to: L. Su (E-mail: [email protected]) and R. Xia (E-mail: [email protected])Search for more papers by this authorJibin Miao
Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China
Search for more papers by this authorBin Yang
Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China
Search for more papers by this authorJiasheng Qian
Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China
Search for more papers by this authorFang Ruan
Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China
Search for more papers by this authorZhengzhi Zheng
Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601 China
Search for more papers by this authorABSTRACT
In this work, the melt strength of PP matrix was reinforced by crosslinking-modified PP (CM-PP) which was yielded by peroxide-initiated crosslinking of linear PP with butyl acrylate (BA). The nano-silica aerogel (nano-SiO2) worked as a nucleating agent for foaming. The effects of CM-PP with the various contents of BA on the foaming behavior and thermal property of PP were studied by measurements of density, thermal conductivity, Vicat softening temperature and SEM. The results showed that the foamed PP got the best properties when the crosslinking PP modified with the weight ratio of butyl acrylate was 10 wt %. The density of the obtained foamed PP with uniform closed cells was as low as 0.23 g/cm3, the thermal conductivity was 0.044 W/(m K), and the Vicat softening temperature was 120 °C. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 44340.
REFERENCES
- 1 Ester, L. G.; Rob, V. H.; Paula, M. Appl. Polym. 2015, 33, 132.
- 2 Yang, J.; Li, P. J. Reinf. Plast. Compos. 2014, 7, 34.
- 3 Liu, Z. F.; Li, Y. N. Eng. Plast. Appl. 2015, 3, 43.
- 4 Bao, J. B.; Weng, G. S.; Zhao, L.; Liu, Z. F.; Chen, Z. R. J. Cell. Plast. 2014, 50, 4.
- 5 Zhai, W. T.; Wang, H. Y.; Yu, J. Polym. Eng. Sci. 2008, 7, 48.
- 6 Bai, G.; Guo, C. G.; Li, L. P. Constr. Build. Mater. 2014, 50, 148.
- 7 Gen, C. Z.; Ja, K. B. J. Anal. Appl. Pyrolysis 2012, 12, 96.
- 8 Parent, J. S.; Bodsworth, A. Polymer 2009, 1, 50.
- 9 Passaglia, E.; Coiai, S. Prog. Polym. Sci. 2009, 9, 34.
- 10 Li, Y.; Yao, Z.; Chen, Z. H.; Qiu, S. L.; Zeng, C. C; Gao, K. Polymer 2015, 70, 207.
- 11 Liu, H.; Chuai, C. Z. J. Appl. Polym. Sci. 2011, 2, 122.
- 12 Feng, J. M.; Wang, W. K. Polym. Plast. Technol. Eng. 2011, 10, 50.
- 13 Sun, Y.; Ueda, Y. J. Supercrit. Fluids 2015, 2, 103.
- 14 Liu, T.; Zhou, S. Y.; Lei, Y. J. Ind. Eng. Chem. Res. 2014, 51, 53.
- 15 Shen, C. J.; Lu, G.; Yu, T. X. Int. J. Impact Eng. 2014, 74, 92.
- 16 Guo, P.; Xu, Y. H.; Lu, M. F.; Zhang, S. J. Ind. Chem. Res. 2015, 1, 54.
- 17 Zhang, Y.; Tiwary, P.; Parent, J. S.; Kontopoulou, M.; Park, C. B. Polymer 2013, 54, 4814.
- 18 Su, L. F.; Miao, L.; Tanemura, S. Sci. Technol. Adv. Mater. 2012, 13, 035003.
- 19
Su, L. F.;
Zhang, W.;
Xia, R. Adv. Mater. Res. 2015, 1090, 50.
10.4028/www.scientific.net/AMR.1090.50 Google Scholar
- 20 Wang, H. Y.; Hu, X. T. Prog. Chem. 2007, 6, 19.
- 21 Spitael, P.; Macosko, C. W. Polym. Eng. Sci. 2004, 11, 44.
- 22 Bao, J. B.; Junior, A. N.; Weng, G. S.; Wang, J. J. Supercrit. Fluids 2016, 111, 63.
- 23 Babu, R. R.; Singha, N. K.; Naskar, K. Exp. Polym. Lett. 2010, 4, 4.
- 24 Lee, S. J.; Zhu, L.; Maia, J. Polymer 2015, 70, 173.
- 25 Li, Y.; Yao, Z.; Chen, Z.; Cao, K.; Qiu, S.; Zhu, F. Chem. Eng. Sci. 2011, 16, 66.
- 26 Auhl, D.; Stange, J.; Münstedt, H.; Krause, B. Macromolecules 2012, 11, 51.
- 27 Kumar, P.; Topin, F. Int. J. Heat Mass Transfer 2016, 92, 539.
Citing Literature
December 20, 2016