Preparation, structure, and properties of montmorillonite/cellulose II/natural rubber nanocomposites

Roberta M. Mariano

Universidade Federal do Rio de Janeiro, Instituto de Macromoléculas Professora Eloísa Mano, Caixa Postal 68.525, 21.945-970 Rio de Janeiro, RJ

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Paulo Henrique de S. Picciani,

Paulo Henrique de S. Picciani

Universidade Federal do Rio de Janeiro, Instituto de Macromoléculas Professora Eloísa Mano, Caixa Postal 68.525, 21.945-970 Rio de Janeiro, RJ

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Regina C. R. Nunes,

Corresponding Author

Regina C. R. Nunes

[email protected]

Universidade Federal do Rio de Janeiro, Instituto de Macromoléculas Professora Eloísa Mano, Caixa Postal 68.525, 21.945-970 Rio de Janeiro, RJ

Universidade Federal do Rio de Janeiro, Instituto de Macromoléculas Professora Eloísa Mano, Caixa Postal 68.525, 21.945-970 Rio de Janeiro, RJ===Search for more papers by this author

Leila L. Y. Visconte,

Leila L. Y. Visconte

Universidade Federal do Rio de Janeiro, Instituto de Macromoléculas Professora Eloísa Mano, Caixa Postal 68.525, 21.945-970 Rio de Janeiro, RJ

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Roberta M. Mariano,

Roberta M. Mariano

Universidade Federal do Rio de Janeiro, Instituto de Macromoléculas Professora Eloísa Mano, Caixa Postal 68.525, 21.945-970 Rio de Janeiro, RJ

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Paulo Henrique de S. Picciani,

Paulo Henrique de S. Picciani

Universidade Federal do Rio de Janeiro, Instituto de Macromoléculas Professora Eloísa Mano, Caixa Postal 68.525, 21.945-970 Rio de Janeiro, RJ

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Regina C. R. Nunes,

Corresponding Author

Regina C. R. Nunes

[email protected]

Universidade Federal do Rio de Janeiro, Instituto de Macromoléculas Professora Eloísa Mano, Caixa Postal 68.525, 21.945-970 Rio de Janeiro, RJ

Universidade Federal do Rio de Janeiro, Instituto de Macromoléculas Professora Eloísa Mano, Caixa Postal 68.525, 21.945-970 Rio de Janeiro, RJ===Search for more papers by this author

Leila L. Y. Visconte,

Leila L. Y. Visconte

Universidade Federal do Rio de Janeiro, Instituto de Macromoléculas Professora Eloísa Mano, Caixa Postal 68.525, 21.945-970 Rio de Janeiro, RJ

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First published: 14 October 2010

https://doi.org/10.1002/app.33159

Citations: 23

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Abstract

In this work, sodium montmorillonite clay was added, as filler, to nanocomposites of natural rubber (NR) and cellulose II (regenerated cellulose) in amounts varying from 0 to 5 phr (per hundred resin). Natural rubber (NR)/cellulose II/montmorillonite nanocomposites were prepared by co-coagulating NR latex, montmorillonite aqueous suspension and cellulose xanthate. The clay was previously exfoliated in water, and the resulting suspension was then added to the mixture of NR latex with cellulose xanthate. Morphological, rheometric, mechanical, and dynamic mechanical properties were evaluated, and an increase in these properties was observed upon the addition of cellulose and clay nanomaterials to the rubber matrix. The results show the advantage in using cellulose as a nanopolymer as well as MMT as nanofiller. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011

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Volume120, Issue1

5 April 2011

Pages 458-465

Preparation, structure, and properties of montmorillonite/cellulose II/natural rubber nanocomposites

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Preparation, structure, and properties of montmorillonite/cellulose II/natural rubber nanocomposites

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