Li[LiCs2Cl][Ga3S6]: A Nanoporous Framework of GaS4 Tetrahedra with Excellent Nonlinear Optical Performance
Dr. Bin-Wen Liu
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155#, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorCorresponding Author
Xiao-Ming Jiang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155#, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorBing-Xuan Li
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155#, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorHui-Yi Zeng
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155#, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Guo-Cong Guo
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155#, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorDr. Bin-Wen Liu
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155#, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorCorresponding Author
Xiao-Ming Jiang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155#, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorBing-Xuan Li
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155#, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorHui-Yi Zeng
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155#, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Guo-Cong Guo
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155#, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorDedicated to Professor Jin-Shun Huang on the occasion of his 80th birthday
Graphical Abstract
The salt-inclusion chalcogenide Li[LiCs2Cl][Ga3S6] is presented, which features a 3D framework composed of [Ga3S6] nanosized tunnels. Introduction of an ionic guest to the covalent chalcogenide host produces a material with a moderate nonlinear optical (NLO) coefficient and an ultrawide band gap (Eg). These characteristics are promising for the development of infrared (IR) NLO materials.
Abstract
A large nonlinear optical (NLO) coefficient and a wide band gap are two crucial but contradictory parameters that are difficult to achieve simultaneously in a single infrared (IR) NLO compound. A salt-inclusion chalcogenide (SIC), Li[LiCs2Cl][Ga3S6] (1), was prepared that presents a nanosized tunnel framework constructed from monotype chalcogenide tetrahedra. Highly oriented covalent GaS4 tetrahedra in the host lead to a moderate second harmonic generation response (0.7 AgGaS2), and ionic guests effectively broaden the band gap to the widest value (4.18 eV) among all IR NLO chalcogenides, thereby achieving a remarkable balance between NLO efficiency and band gap.
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