Nickel/Nickel(II) Oxide Nanoparticles Anchored onto Cobalt(IV) Diselenide Nanobelts for the Electrochemical Production of Hydrogen†
Yun-Fei Xu
Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, University of Science and Technology of China, Hefei 230026 (P. R. China) http://staff.ustc.edu.cn/∼yulab
These authors contributed equally to this work.
Search for more papers by this authorDr. Min-Rui Gao
Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, University of Science and Technology of China, Hefei 230026 (P. R. China) http://staff.ustc.edu.cn/∼yulab
These authors contributed equally to this work.
Search for more papers by this authorYa-Rong Zheng
Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, University of Science and Technology of China, Hefei 230026 (P. R. China) http://staff.ustc.edu.cn/∼yulab
Search for more papers by this authorDr. Jun Jiang
Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, University of Science and Technology of China, Hefei 230026 (P. R. China) http://staff.ustc.edu.cn/∼yulab
Search for more papers by this authorCorresponding Author
Prof. Dr. Shu-Hong Yu
Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, University of Science and Technology of China, Hefei 230026 (P. R. China) http://staff.ustc.edu.cn/∼yulab
Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, University of Science and Technology of China, Hefei 230026 (P. R. China) http://staff.ustc.edu.cn/∼yulabSearch for more papers by this authorYun-Fei Xu
Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, University of Science and Technology of China, Hefei 230026 (P. R. China) http://staff.ustc.edu.cn/∼yulab
These authors contributed equally to this work.
Search for more papers by this authorDr. Min-Rui Gao
Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, University of Science and Technology of China, Hefei 230026 (P. R. China) http://staff.ustc.edu.cn/∼yulab
These authors contributed equally to this work.
Search for more papers by this authorYa-Rong Zheng
Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, University of Science and Technology of China, Hefei 230026 (P. R. China) http://staff.ustc.edu.cn/∼yulab
Search for more papers by this authorDr. Jun Jiang
Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, University of Science and Technology of China, Hefei 230026 (P. R. China) http://staff.ustc.edu.cn/∼yulab
Search for more papers by this authorCorresponding Author
Prof. Dr. Shu-Hong Yu
Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, University of Science and Technology of China, Hefei 230026 (P. R. China) http://staff.ustc.edu.cn/∼yulab
Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, University of Science and Technology of China, Hefei 230026 (P. R. China) http://staff.ustc.edu.cn/∼yulabSearch for more papers by this authorS. H. Yu acknowledges the funding support from the National Basic Research Program of China (grant number 2010CB934700), the National Natural Science Foundation of China (grant numbers 91022032, 91227103, and 21061160492), the Ministry of Science and Technology of China (grant number 2012BAD32B05-4), the Chinese Academy of Sciences (grant number KJZD-EW-M01-1), and the Principal Investigator Award by the National Synchrotron Radiation Laboratory at the University of Science and Technology of China.
Graphical Abstract
Not noble but effective: A novel Ni/NiO/CoSe2 hybrid material has been synthesized as an efficient catalyst for the hydrogen evolution reaction (HER; see picture). This new catalyst has a cathodic onset potential at −0.03 V, a Tafel slope of 39 mV per decade, and represents currently the best Pt-free electrocatalyst for the HER in acidic medium.
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