Communication
An Air-Stable Oxyallyl Radical Cation†
Dr. David Martin,
Dr. Curtis E. Moore,
Arnold L. Rheingold,
Prof. Guy Bertrand,
Dr. David Martin
UCSD-CNRS Joint Research Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, CA 92093-0343 (USA) http://bertrandgroup.ucsd.edu
Search for more papers by this authorDr. Curtis E. Moore
UCSD Crystallography Facility, Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, CA 92093-0343 (USA)
Search for more papers by this authorArnold L. Rheingold
Search for more papers by this authorCorresponding Author
Prof. Guy Bertrand
UCSD-CNRS Joint Research Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, CA 92093-0343 (USA) http://bertrandgroup.ucsd.edu
UCSD-CNRS Joint Research Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, CA 92093-0343 (USA) http://bertrandgroup.ucsd.eduSearch for more papers by this authorDr. David Martin,
Dr. Curtis E. Moore,
Arnold L. Rheingold,
Prof. Guy Bertrand,
Dr. David Martin
UCSD-CNRS Joint Research Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, CA 92093-0343 (USA) http://bertrandgroup.ucsd.edu
Search for more papers by this authorDr. Curtis E. Moore
UCSD Crystallography Facility, Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, CA 92093-0343 (USA)
Search for more papers by this authorArnold L. Rheingold
Search for more papers by this authorCorresponding Author
Prof. Guy Bertrand
UCSD-CNRS Joint Research Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, CA 92093-0343 (USA) http://bertrandgroup.ucsd.edu
UCSD-CNRS Joint Research Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, CA 92093-0343 (USA) http://bertrandgroup.ucsd.eduSearch for more papers by this author†
D.M. and G.B. acknowledge financial support from the NSF (CHE-1112133 and CHE-1316956), and Maria Angelella and Michael Tauber for assistance with ESR experiments. D.M. acknowledges the Extreme Science and Engineering Discovery Environment (XSEDE), which is supported by NSF (OCI-1053575).
Graphical Abstract
Easy does it! Simply take two carbenes, add carbon monoxide, then HCl, and open the flask to air, and an oxyallyl radical cation is formed.
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