Assembly and Stepwise Oxidation of Interpenetrated Coordination Cages Based on Phenothiazine†
Marina Frank
Institute for Inorganic Chemistry, Georg-August University Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) http://www.clever-lab.de
Search for more papers by this authorJakob Hey
Institute for Inorganic Chemistry, Georg-August University Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) http://www.clever-lab.de
Search for more papers by this authorIlker Balcioglu
Institute for Inorganic Chemistry, Georg-August University Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) http://www.clever-lab.de
Search for more papers by this authorDr. Yu-Sheng Chen
Center for Advanced Radiation Source (ChemMatCARS), The University of Chicago c/o APS/ANL (USA)
Search for more papers by this authorProf. Dr. Dietmar Stalke
Institute for Inorganic Chemistry, Georg-August University Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) http://www.clever-lab.de
Search for more papers by this authorProf. Dr. Tomoyoshi Suenobu
Department of Material and Life Science, Graduate School of Engineering, Osaka University, ALCA, Japan Science and Technology Agency (JST), Suita, Osaka 565-0871 (Japan)
Search for more papers by this authorProf. Dr. Shunichi Fukuzumi
Department of Material and Life Science, Graduate School of Engineering, Osaka University, ALCA, Japan Science and Technology Agency (JST), Suita, Osaka 565-0871 (Japan)
Department of Bioinspired Science, Ewha Womans University, Seoul 120-750 (Korea)
Search for more papers by this authorDr. Holm Frauendorf
Institute for Organic and Biomolecular Chemistry, Georg-August University Göttingen, Tammannstrasse 2, 37077 Göttingen (Germany)
Search for more papers by this authorCorresponding Author
Prof. Dr. Guido H. Clever
Institute for Inorganic Chemistry, Georg-August University Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) http://www.clever-lab.de
Institute for Inorganic Chemistry, Georg-August University Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) http://www.clever-lab.de===Search for more papers by this authorMarina Frank
Institute for Inorganic Chemistry, Georg-August University Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) http://www.clever-lab.de
Search for more papers by this authorJakob Hey
Institute for Inorganic Chemistry, Georg-August University Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) http://www.clever-lab.de
Search for more papers by this authorIlker Balcioglu
Institute for Inorganic Chemistry, Georg-August University Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) http://www.clever-lab.de
Search for more papers by this authorDr. Yu-Sheng Chen
Center for Advanced Radiation Source (ChemMatCARS), The University of Chicago c/o APS/ANL (USA)
Search for more papers by this authorProf. Dr. Dietmar Stalke
Institute for Inorganic Chemistry, Georg-August University Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) http://www.clever-lab.de
Search for more papers by this authorProf. Dr. Tomoyoshi Suenobu
Department of Material and Life Science, Graduate School of Engineering, Osaka University, ALCA, Japan Science and Technology Agency (JST), Suita, Osaka 565-0871 (Japan)
Search for more papers by this authorProf. Dr. Shunichi Fukuzumi
Department of Material and Life Science, Graduate School of Engineering, Osaka University, ALCA, Japan Science and Technology Agency (JST), Suita, Osaka 565-0871 (Japan)
Department of Bioinspired Science, Ewha Womans University, Seoul 120-750 (Korea)
Search for more papers by this authorDr. Holm Frauendorf
Institute for Organic and Biomolecular Chemistry, Georg-August University Göttingen, Tammannstrasse 2, 37077 Göttingen (Germany)
Search for more papers by this authorCorresponding Author
Prof. Dr. Guido H. Clever
Institute for Inorganic Chemistry, Georg-August University Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) http://www.clever-lab.de
Institute for Inorganic Chemistry, Georg-August University Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) http://www.clever-lab.de===Search for more papers by this authorM.F. thanks the Evonik Foundation and J.H. the CaSuS program of Lower Saxony for PhD fellowships. We thank the DFG (CL 489/2-1), the FCI, and the HeKKSaGOn consortium for support, and Dr. M. John for NMR measurements. ChemMatCARS and the Advanced Photon Source are supported by the NSF Department of Energy (NSF/CHE-0822838, DE-AC02-06CH11357).
Graphical Abstract
A breath of fresh air is sufficient for the eightfold S-monooxygenation of an interpenetrated double cage based on eight phenothiazine ligands and four square-planar-coordinated PdII cations. Besides these two cages, which were both characterized by X-ray crystallography, an eightfold S-dioxygenated double-cage was obtained under harsher oxidation conditions.
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