Electron Acceptors Based on an All-Carbon Donor–Acceptor Copolymer†
Jessica L. Jellison
Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, IL (USA) http://www.kyleplunkett.com
Search for more papers by this authorChe-Hsiung Lee
Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, IL (USA) http://www.kyleplunkett.com
Search for more papers by this authorXinju Zhu
Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, IL (USA) http://www.kyleplunkett.com
Search for more papers by this authorJordan D. Wood
Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, IL (USA) http://www.kyleplunkett.com
Search for more papers by this authorCorresponding Author
Prof. Kyle N. Plunkett
Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, IL (USA) http://www.kyleplunkett.com
Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, IL (USA) http://www.kyleplunkett.comSearch for more papers by this authorJessica L. Jellison
Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, IL (USA) http://www.kyleplunkett.com
Search for more papers by this authorChe-Hsiung Lee
Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, IL (USA) http://www.kyleplunkett.com
Search for more papers by this authorXinju Zhu
Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, IL (USA) http://www.kyleplunkett.com
Search for more papers by this authorJordan D. Wood
Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, IL (USA) http://www.kyleplunkett.com
Search for more papers by this authorCorresponding Author
Prof. Kyle N. Plunkett
Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, IL (USA) http://www.kyleplunkett.com
Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, IL (USA) http://www.kyleplunkett.comSearch for more papers by this authorThis work was supported by startup funds and a seed grant provided by Southern Illinois University.
Graphical Abstract
The Sonogashira cross-coupling polymerization of a dibrominated cyclopenta[hi]aceanthrylene and a diethynylfluorene derivative produced a donor–acceptor copolymer composed solely of cyclopenta-fused polycyclic aromatic hydrocarbons. The resulting polymer displays low band gaps (<1.5 eV), dual absorption bands, and electron-accepting behavior as demonstrated through fluorescence quenching of poly(3-hexylthiophene).
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