Towards Unimolecular Luminescent Solar Concentrators: Bodipy-Based Dendritic Energy-Transfer Cascade with Panchromatic Absorption and Monochromatized Emission†
Dr. O. Altan Bozdemir
UNAM-Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800 (Turkey)
Search for more papers by this authorSundus Erbas-Cakmak
UNAM-Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800 (Turkey)
Search for more papers by this authorO. Oner Ekiz
UNAM-Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800 (Turkey)
Search for more papers by this authorDr. Aykutlu Dana
UNAM-Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800 (Turkey)
Search for more papers by this authorCorresponding Author
Prof. Dr. Engin U. Akkaya
UNAM-Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800 (Turkey)
Department of Chemistry, Bilkent University, 06800 Ankara (Turkey)
UNAM-Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800 (Turkey)Search for more papers by this authorDr. O. Altan Bozdemir
UNAM-Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800 (Turkey)
Search for more papers by this authorSundus Erbas-Cakmak
UNAM-Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800 (Turkey)
Search for more papers by this authorO. Oner Ekiz
UNAM-Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800 (Turkey)
Search for more papers by this authorDr. Aykutlu Dana
UNAM-Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800 (Turkey)
Search for more papers by this authorCorresponding Author
Prof. Dr. Engin U. Akkaya
UNAM-Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800 (Turkey)
Department of Chemistry, Bilkent University, 06800 Ankara (Turkey)
UNAM-Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800 (Turkey)Search for more papers by this authorWe are grateful for funding by BOREN, Turkish academy of Sciences (TUBA), and State Planning Organization (DPT).
Graphical Abstract
A polymer-embedded dendritic, bodipy-based panchromatic absorber with a built-in energy gradient concentrates incident solar radiation at a terminal chromophore, resulting in a monochromatized emission directed to the sides of the polymer waveguide (see picture). This particular design minimizes self-absorption losses from the peripheral antenna units with an impressive S factor of 10 000.
Supporting Information
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