Molecular Architecture towards Helical Double-Stranded Polymers†
Hui-Chun Yang
Department of Chemistry, National Taiwan University, Taipei 106, Taiwan, Fax: (+886) 2-2364-4971
Institute of Polymer Science and Engineering, National Taiwan University, Taipei 106, Taiwan
Search for more papers by this authorShu-Yi Lin Dr.
Department of Chemistry, National Tsing Hua University, Hsinchu 300, Taiwan
Search for more papers by this authorHsiao-Ching Yang Dr.
Department of Chemistry, National Taiwan University, Taipei 106, Taiwan, Fax: (+886) 2-2364-4971
Search for more papers by this authorCheng-Lan Lin Dr.
Department of Chemistry, National Taiwan University, Taipei 106, Taiwan, Fax: (+886) 2-2364-4971
Institute of Chemistry, Academia Sinica, Nangang, Taipei 115, Taiwan
Search for more papers by this authorLun Tsai
Department of Chemistry, National Taiwan University, Taipei 106, Taiwan, Fax: (+886) 2-2364-4971
Search for more papers by this authorShou-Ling Huang
Department of Chemistry, National Taiwan University, Taipei 106, Taiwan, Fax: (+886) 2-2364-4971
Search for more papers by this authorI. Wen-Peter Chen
Department of Chemistry, National Tsing Hua University, Hsinchu 300, Taiwan
Search for more papers by this authorChun-hsien Chen Prof.
Department of Chemistry, National Tsing Hua University, Hsinchu 300, Taiwan
Search for more papers by this authorBih-Yaw Jin Prof.
Department of Chemistry, National Taiwan University, Taipei 106, Taiwan, Fax: (+886) 2-2364-4971
Search for more papers by this authorTien-Yau Luh Prof.
Department of Chemistry, National Taiwan University, Taipei 106, Taiwan, Fax: (+886) 2-2364-4971
Institute of Polymer Science and Engineering, National Taiwan University, Taipei 106, Taiwan
Search for more papers by this authorHui-Chun Yang
Department of Chemistry, National Taiwan University, Taipei 106, Taiwan, Fax: (+886) 2-2364-4971
Institute of Polymer Science and Engineering, National Taiwan University, Taipei 106, Taiwan
Search for more papers by this authorShu-Yi Lin Dr.
Department of Chemistry, National Tsing Hua University, Hsinchu 300, Taiwan
Search for more papers by this authorHsiao-Ching Yang Dr.
Department of Chemistry, National Taiwan University, Taipei 106, Taiwan, Fax: (+886) 2-2364-4971
Search for more papers by this authorCheng-Lan Lin Dr.
Department of Chemistry, National Taiwan University, Taipei 106, Taiwan, Fax: (+886) 2-2364-4971
Institute of Chemistry, Academia Sinica, Nangang, Taipei 115, Taiwan
Search for more papers by this authorLun Tsai
Department of Chemistry, National Taiwan University, Taipei 106, Taiwan, Fax: (+886) 2-2364-4971
Search for more papers by this authorShou-Ling Huang
Department of Chemistry, National Taiwan University, Taipei 106, Taiwan, Fax: (+886) 2-2364-4971
Search for more papers by this authorI. Wen-Peter Chen
Department of Chemistry, National Tsing Hua University, Hsinchu 300, Taiwan
Search for more papers by this authorChun-hsien Chen Prof.
Department of Chemistry, National Tsing Hua University, Hsinchu 300, Taiwan
Search for more papers by this authorBih-Yaw Jin Prof.
Department of Chemistry, National Taiwan University, Taipei 106, Taiwan, Fax: (+886) 2-2364-4971
Search for more papers by this authorTien-Yau Luh Prof.
Department of Chemistry, National Taiwan University, Taipei 106, Taiwan, Fax: (+886) 2-2364-4971
Institute of Polymer Science and Engineering, National Taiwan University, Taipei 106, Taiwan
Search for more papers by this authorThis work was funded by the National Science Council of the Republic of China.
Graphical Abstract
Close to original: A DNA-like double-stranded polymer is synthesized by ring-opening metathesis polymerization of a bisnorbornene derivative containing a rigid ferrocene spacer. The polymer forms helices (see picture), supercoils, and ladders, which are observable by scanning tunneling microscopy.
Supporting Information
Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z503406_s.pdf or from the author.
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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