Volume 43, Issue 25 p. 3205

Cover Picture: Expanding and Shrinking Porous Modulation Based on Pillared-Layer Coordination Polymers Showing Selective Guest Adsorption (Angew. Chem. Int. Ed. 25/2004)

Tapas Kumar Maji Dr.

Tapas Kumar Maji Dr.

Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishigyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732

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Kazuhiro Uemura

Kazuhiro Uemura

Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishigyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732

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Ho-Chol Chang Dr.

Ho-Chol Chang Dr.

Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishigyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732

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Ryotaro Matsuda

Ryotaro Matsuda

Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishigyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732

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Susumu Kitagawa Prof. Dr.

Susumu Kitagawa Prof. Dr.

Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishigyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732

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First published: 16 June 2004

Abstract

To expand or shrink are properties of the new pillared-layer porous coordination polymers shown in the cover picture. These features show that coordination polymers are much softer than generally believed. The adsorption selectivity exhibited by these new zeolite-like materials arises from a simple change in the organic-pillar module, and may find applications in molecular separation techniques. For more information see the Communication by S. Kitagawa et al. on page 3269 ff.

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