Gas-Phase Complexes: Possible Prereactive Gateways for Reactions of Halogens with NH₃, H₂O, and H₂S

Corresponding Author

Prof. Dr. Hans Bürger

FB 9 – Anorganische Chemie, Universität-GH Wuppertal, D-42097 Wuppertal (Germany), Fax: Int. code + (202)439-2901, e-mail: [email protected]

FB 9 – Anorganische Chemie, Universität-GH Wuppertal, D-42097 Wuppertal (Germany), Fax: Int. code + (202)439-2901, e-mail: [email protected]Search for more papers by this author

Prof. Dr. Hans Bürger,

Corresponding Author

Prof. Dr. Hans Bürger

FB 9 – Anorganische Chemie, Universität-GH Wuppertal, D-42097 Wuppertal (Germany), Fax: Int. code + (202)439-2901, e-mail: [email protected]

FB 9 – Anorganische Chemie, Universität-GH Wuppertal, D-42097 Wuppertal (Germany), Fax: Int. code + (202)439-2901, e-mail: [email protected]Search for more papers by this author

First published: April 18, 1997

https://doi.org/10.1002/anie.199707181

Citations: 14

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Molecular beams with the carrier gas argon contain prereactive complexes of halogens and interhalogens with NH₃, H₂O, and H₂S, as detected by Fourier-transform microwave spectroscopy; the structures have been elucidated. The partial structures of NH₃, H₂O, and H₂S as well as F₂, ClF (cf. picture), Cl₂, BrCl, and Br₂ are almost the same for the complexes as for the free molecules. The weak complex bonds result from electrostatic forces.

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Volume36, Issue7

April 18, 1997

Pages 718-721

Gas-Phase Complexes: Possible Prereactive Gateways for Reactions of Halogens with NH₃, H₂O, and H₂S

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Gas-Phase Complexes: Possible Prereactive Gateways for Reactions of Halogens with NH3, H2O, and H2S

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Gas-Phase Complexes: Possible Prereactive Gateways for Reactions of Halogens with NH₃, H₂O, and H₂S