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Te₆, [Te₈Cl₁₈]²⁻, and [TeCl₃]⁻: New Tellurium and Chlorotellurato Ligands in the Re₆ Solid-State Cluster Compounds Re₆Te₁₆Cl₁₈ and Re₆Te₁₆Cl₆^†^‡

Yuri V. Mironov

Department of Chemistry, Northwestern University, Evanston, IL 60208-3113 (USA), Fax: Int. code +(847)491-2976, e-mail: [email protected]

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Michael A. Pell,

Michael A. Pell

Department of Chemistry, Northwestern University, Evanston, IL 60208-3113 (USA), Fax: Int. code +(847)491-2976, e-mail: [email protected]

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Prof. James A. Ibers,

Corresponding Author

Prof. James A. Ibers

Department of Chemistry, Northwestern University, Evanston, IL 60208-3113 (USA), Fax: Int. code +(847)491-2976, e-mail: [email protected]

Department of Chemistry, Northwestern University, Evanston, IL 60208-3113 (USA), Fax: Int. code +(847)491-2976, e-mail: [email protected]Search for more papers by this author

Yuri V. Mironov,

Yuri V. Mironov

Department of Chemistry, Northwestern University, Evanston, IL 60208-3113 (USA), Fax: Int. code +(847)491-2976, e-mail: [email protected]

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Michael A. Pell,

Michael A. Pell

Department of Chemistry, Northwestern University, Evanston, IL 60208-3113 (USA), Fax: Int. code +(847)491-2976, e-mail: [email protected]

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Prof. James A. Ibers,

Corresponding Author

Prof. James A. Ibers

Department of Chemistry, Northwestern University, Evanston, IL 60208-3113 (USA), Fax: Int. code +(847)491-2976, e-mail: [email protected]

Department of Chemistry, Northwestern University, Evanston, IL 60208-3113 (USA), Fax: Int. code +(847)491-2976, e-mail: [email protected]Search for more papers by this author

First published: December 1996

https://doi.org/10.1002/anie.199628541

Citations: 40

^†

This research was sponsored by the U. S. National Science Foundation, Grant DMR91-14934.

^‡

Dedicated to Professor Richard H. Holm

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Graphical Abstract

Re₆ octahedra inside Te₈ cubes is a common feature of both title compounds. The picture on the right shows a section of the structure of Re₆Te₁₆Cl₁₈, in which the Re₆ octahedron and the binding of the cluster to the [Te₈Cl₁₈]²⁻ ligand are apparent. Different binding to ligands results in a three-dimensional structure for Re₆Te₁₆Cl₁₈, and a two-dimensional structure for Re₆Te₁₆Cl₆.

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Volume35, Issue23-24

December 1996

Pages 2854-2856

Te₆, [Te₈Cl₁₈]²⁻, and [TeCl₃]⁻: New Tellurium and Chlorotellurato Ligands in the Re₆ Solid-State Cluster Compounds Re₆Te₁₆Cl₁₈ and Re₆Te₁₆Cl₆^†^‡

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Te₆, [Te₈Cl₁₈]²⁻, and [TeCl₃]⁻: New Tellurium and Chlorotellurato Ligands in the Re₆ Solid-State Cluster Compounds Re₆Te₁₆Cl₁₈ and Re₆Te₁₆Cl₆^†^‡