Azido and 2,2′-Bipyrimidine Ligands as Useful Tools in Designing Two- and Three-Dimensional Manganese(II) Networks†
Corresponding Author
Prof. G. Giovanni De Munno
Dipartimento di Chimica, Università della Calabria I-87030 Arcavacata di Rende, Cosenza (Italy) Fax: Int. code +(984)49-2044
G. Giovanni De Munno, Dipartimento di Chimica, Università della Calabria I-87030 Arcavacata di Rende, Cosenza (Italy) Fax: Int. code +(984)49-2044
Miguel Julve, Department de Química Inorgànica, Facultat de Química Dr. Moliner 50, E-46100 Burjassot, València (Spain) Fax: Int. code +(6)3864322 e-mail: [email protected]
Search for more papers by this authorCorresponding Author
Prof. Miguel Julve
Department de Química Inorgànica, Facultat de Química Dr. Moliner 50, E-46100 Burjassot, València (Spain) Fax: Int. code +(6)3864322 e-mail: [email protected]
G. Giovanni De Munno, Dipartimento di Chimica, Università della Calabria I-87030 Arcavacata di Rende, Cosenza (Italy) Fax: Int. code +(984)49-2044
Miguel Julve, Department de Química Inorgànica, Facultat de Química Dr. Moliner 50, E-46100 Burjassot, València (Spain) Fax: Int. code +(6)3864322 e-mail: [email protected]
Search for more papers by this authorDr. Guillaume Viau
Department de Química Inorgànica, Facultat de Química Dr. Moliner 50, E-46100 Burjassot, València (Spain) Fax: Int. code +(6)3864322 e-mail: [email protected]
Search for more papers by this authorDr. Francesc Lloret
Department de Química Inorgànica, Facultat de Química Dr. Moliner 50, E-46100 Burjassot, València (Spain) Fax: Int. code +(6)3864322 e-mail: [email protected]
Search for more papers by this authorProf. Juan Faus
Department de Química Inorgànica, Facultat de Química Dr. Moliner 50, E-46100 Burjassot, València (Spain) Fax: Int. code +(6)3864322 e-mail: [email protected]
Search for more papers by this authorProf. Davide Viterbo
Dipartimento di Chimica IFM, Università di Torino Via P. Giuria 7, 10125 Torino (Italy)
Search for more papers by this authorCorresponding Author
Prof. G. Giovanni De Munno
Dipartimento di Chimica, Università della Calabria I-87030 Arcavacata di Rende, Cosenza (Italy) Fax: Int. code +(984)49-2044
G. Giovanni De Munno, Dipartimento di Chimica, Università della Calabria I-87030 Arcavacata di Rende, Cosenza (Italy) Fax: Int. code +(984)49-2044
Miguel Julve, Department de Química Inorgànica, Facultat de Química Dr. Moliner 50, E-46100 Burjassot, València (Spain) Fax: Int. code +(6)3864322 e-mail: [email protected]
Search for more papers by this authorCorresponding Author
Prof. Miguel Julve
Department de Química Inorgànica, Facultat de Química Dr. Moliner 50, E-46100 Burjassot, València (Spain) Fax: Int. code +(6)3864322 e-mail: [email protected]
G. Giovanni De Munno, Dipartimento di Chimica, Università della Calabria I-87030 Arcavacata di Rende, Cosenza (Italy) Fax: Int. code +(984)49-2044
Miguel Julve, Department de Química Inorgànica, Facultat de Química Dr. Moliner 50, E-46100 Burjassot, València (Spain) Fax: Int. code +(6)3864322 e-mail: [email protected]
Search for more papers by this authorDr. Guillaume Viau
Department de Química Inorgànica, Facultat de Química Dr. Moliner 50, E-46100 Burjassot, València (Spain) Fax: Int. code +(6)3864322 e-mail: [email protected]
Search for more papers by this authorDr. Francesc Lloret
Department de Química Inorgànica, Facultat de Química Dr. Moliner 50, E-46100 Burjassot, València (Spain) Fax: Int. code +(6)3864322 e-mail: [email protected]
Search for more papers by this authorProf. Juan Faus
Department de Química Inorgànica, Facultat de Química Dr. Moliner 50, E-46100 Burjassot, València (Spain) Fax: Int. code +(6)3864322 e-mail: [email protected]
Search for more papers by this authorProf. Davide Viterbo
Dipartimento di Chimica IFM, Università di Torino Via P. Giuria 7, 10125 Torino (Italy)
Search for more papers by this authorThis work was supported by the Spanish DGICYT (Project PB94-1002), the Italian Ministero dell'Università e della Ricerca Scientifica e Technologica, and the Human Capital and Mobility Program (Network on Magnetic Molecular Materials from the EU) through Grant ERBCHRX-CT920080. G. V. thanks the Spanish Ministery of Education and Science for a postdoctoral fellowship.
Graphical Abstract
Same composition but different structures characterize the manganese complexes 1 and 2 of the formula [Mn2(bpym)(N3)4], which are obtained by the reaction of manganese(II) nitrate with 2,2′-bipyrimidine (bpym) and sodium azide in aqueous solution. Compound 1 has a honeycomb layered structure (shown on the right) and exhibits overall ferromagnetic interactions; 2 has a three-dimensional polymeric structure and shows overall antiferromagnetic interactions.
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