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Formation and Structures of New Metallo- and Metallapolysulfanes, [MS_y]⁺ (y = 2−16)^†

Corresponding Author

Prof. Ian Dance

School of Chemistry, University of New South Wales, Sydney 2052 (Australia). Telefax: Int. code + (2) 662 2835 e-mail: [email protected]

School of Chemistry, University of New South Wales, Sydney 2052 (Australia). Telefax: Int. code + (2) 662 2835 e-mail: [email protected]Search for more papers by this author

Dr. Keith Fisher,

Dr. Keith Fisher

School of Chemistry, University of New South Wales, Sydney 2052 (Australia). Telefax: Int. code + (2) 662 2835 e-mail: [email protected]

Search for more papers by this author

Dr. Gary Willett,

Dr. Gary Willett

School of Chemistry, University of New South Wales, Sydney 2052 (Australia). Telefax: Int. code + (2) 662 2835 e-mail: [email protected]

Search for more papers by this author

Prof. Ian Dance,

Corresponding Author

Prof. Ian Dance

School of Chemistry, University of New South Wales, Sydney 2052 (Australia). Telefax: Int. code + (2) 662 2835 e-mail: [email protected]

School of Chemistry, University of New South Wales, Sydney 2052 (Australia). Telefax: Int. code + (2) 662 2835 e-mail: [email protected]Search for more papers by this author

Dr. Keith Fisher,

Dr. Keith Fisher

School of Chemistry, University of New South Wales, Sydney 2052 (Australia). Telefax: Int. code + (2) 662 2835 e-mail: [email protected]

Search for more papers by this author

Dr. Gary Willett,

Dr. Gary Willett

School of Chemistry, University of New South Wales, Sydney 2052 (Australia). Telefax: Int. code + (2) 662 2835 e-mail: [email protected]

Search for more papers by this author

First published: February 3, 1995

https://doi.org/10.1002/anie.199502011

Citations: 20

^†

Financial support from the Australian Research Council is gratefully acknowledged, as is the generous provision of computing resources by Australian Numerical Simulation and Modelling Services.

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Graphical Abstract

In the gas phase, sulfur and monopositive metal ions (ScZn) react to form novel metallo- and metallapolysulfanes [MS_y]⁺. The structures of these complexes were calculated by ab initio methods. The lowest energy structure of [Cu(cyclo-S₁₂)]⁺, in which the octahedrally coordinated Cu⁺ ion is located in the center of the S₁₂ cycle, is shown in the picture on the right.

Abstract

For corrigendum see DOI:10.1002/anie.199510321

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Volume34, Issue2

February 3, 1995

Pages 201-203

Formation and Structures of New Metallo- and Metallapolysulfanes, [MS_y]⁺ (y = 2−16)^†

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Formation and Structures of New Metallo- and Metallapolysulfanes, [MSy]+ (y = 2−16)†

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Formation and Structures of New Metallo- and Metallapolysulfanes, [MS_y]⁺ (y = 2−16)^†