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Reactions of Per(chloro, fluoro)ethanes with Aryloxide and Alkoxide Ions — Evidence for Chlorophilic Attack on CCl Bonds^†

Corresponding Author

Prof. Xing-ya Li

Shanghai Institute of Organic Chemistry, Academia Sinica, 345 Lingling Lu, Shangha (China)

Shanghai Institute of Organic Chemistry, Academia Sinica, 345 Lingling Lu, Shangha (China)Search for more papers by this author

He-qi Pan,

He-qi Pan

Shanghai Institute of Organic Chemistry, Academia Sinica, 345 Lingling Lu, Shangha (China)

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Prof. Xi-kui Jiang,

Prof. Xi-kui Jiang

Shanghai Institute of Organic Chemistry, Academia Sinica, 345 Lingling Lu, Shangha (China)

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Zheng-yun Zhan,

Zheng-yun Zhan

Shanghai Institute of Organic Chemistry, Academia Sinica, 345 Lingling Lu, Shangha (China)

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Prof. Xing-ya Li,

Corresponding Author

Prof. Xing-ya Li

Shanghai Institute of Organic Chemistry, Academia Sinica, 345 Lingling Lu, Shangha (China)

Shanghai Institute of Organic Chemistry, Academia Sinica, 345 Lingling Lu, Shangha (China)Search for more papers by this author

He-qi Pan,

He-qi Pan

Shanghai Institute of Organic Chemistry, Academia Sinica, 345 Lingling Lu, Shangha (China)

Search for more papers by this author

Prof. Xi-kui Jiang,

Prof. Xi-kui Jiang

Shanghai Institute of Organic Chemistry, Academia Sinica, 345 Lingling Lu, Shangha (China)

Search for more papers by this author

Zheng-yun Zhan,

Zheng-yun Zhan

Shanghai Institute of Organic Chemistry, Academia Sinica, 345 Lingling Lu, Shangha (China)

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First published: October 1985

https://doi.org/10.1002/anie.198508711

Citations: 21

^†

Dedicated to Professor Rolf Huisgen on the occasion of his 65th birthday

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Abstract

The synthesis of aryl- and alkyl per(chloro, fluoro) ethyl ethers 2 is achieved by reaction of nucleophiles ROK with the substrates 1 (X, YCl, F). This is the first confirmed example for the attack of oxygen nucleophiles on the CCl bond. The ethers 2 are only obtainable with difficulty by others routes.

References

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Volume24, Issue10

October 1985

Pages 871-872

Reactions of Per(chloro, fluoro)ethanes with Aryloxide and Alkoxide Ions — Evidence for Chlorophilic Attack on CCl Bonds^†

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Reactions of Per(chloro, fluoro)ethanes with Aryloxide and Alkoxide Ions — Evidence for Chlorophilic Attack on CCl Bonds†

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Reactions of Per(chloro, fluoro)ethanes with Aryloxide and Alkoxide Ions — Evidence for Chlorophilic Attack on CCl Bonds^†