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Novel CO Bond Formation via [3+2] Cycloaddition of Diphenylketene to a Dioxo Metal Moiety^†

Corresponding Author

Prof. Dr. Wolfgang A. Herrmann

Anorganisch-chemisches Institut der Technischen Universität München, Lichtenbergstrasse 4, D-8046 Garching (FRG)

Anorganisch-chemisches Institut der Technischen Universität München Lichtenbergstrasse 4, D-8046 Garching (FRG)Search for more papers by this author

Ulrich Küsthardt,

Ulrich Küsthardt

Anorganisch-chemisches Institut der Technischen Universität München, Lichtenbergstrasse 4, D-8046 Garching (FRG)

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Prof. Dr. Manfred L. Ziegler,

Prof. Dr. Manfred L. Ziegler

Anorganisch-chemisches Institut der Universität, Im Neuenheimer Feld 270, D-6900 Heidelberg 1 (FRG)

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Thomas Zahn,

Thomas Zahn

Anorganisch-chemisches Institut der Universität, Im Neuenheimer Feld 270, D-6900 Heidelberg 1 (FRG)

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Prof. Dr. Wolfgang A. Herrmann,

Corresponding Author

Prof. Dr. Wolfgang A. Herrmann

Anorganisch-chemisches Institut der Technischen Universität München, Lichtenbergstrasse 4, D-8046 Garching (FRG)

Anorganisch-chemisches Institut der Technischen Universität München Lichtenbergstrasse 4, D-8046 Garching (FRG)Search for more papers by this author

Ulrich Küsthardt,

Ulrich Küsthardt

Anorganisch-chemisches Institut der Technischen Universität München, Lichtenbergstrasse 4, D-8046 Garching (FRG)

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Prof. Dr. Manfred L. Ziegler,

Prof. Dr. Manfred L. Ziegler

Anorganisch-chemisches Institut der Universität, Im Neuenheimer Feld 270, D-6900 Heidelberg 1 (FRG)

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Thomas Zahn,

Thomas Zahn

Anorganisch-chemisches Institut der Universität, Im Neuenheimer Feld 270, D-6900 Heidelberg 1 (FRG)

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First published: October 1985

https://doi.org/10.1002/anie.198508601

Citations: 23

^†

Multiple Bonds between Main-Group Elements and Transition Metals, Part 20. This work was supported by the Fonds der Chemischen Industrie, the Deutsche Forschungsgemeinschaft, the Hermann-Schlosser Stiftung of Degussa AG (fellowship to U. K.), and the Bundesministerium für Forschung und Technologie.—Part 19: M. Herberhold, B. Schmidkonz, U. Thewalt, A. Razavi, W. A. Herrmann, C. Hecht, Z. Naturforsch. B, in press.

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The ReO₃ group is retained during the [3+2] cycloaddition of diphenylketene to the trioxorhenium(VII) compound 1; the metallacycle 2 precipitates in the form of violet crystals. The reaction could be of use for the oxidation of CC multiple bond systems (R = C₆H₅).

References

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Volume24, Issue10

October 1985

Pages 860-861

Novel CO Bond Formation via [3+2] Cycloaddition of Diphenylketene to a Dioxo Metal Moiety^†

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Novel CO Bond Formation via [3+2] Cycloaddition of Diphenylketene to a Dioxo Metal Moiety†

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Novel CO Bond Formation via [3+2] Cycloaddition of Diphenylketene to a Dioxo Metal Moiety^†