Volume 19, Issue 3 pp. 206-207
Communication
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Correlation between Radical Reactivities and Copolymerization Parameters

Prof. Dr. Bernd Giese

Prof. Dr. Bernd Giese

Institut für Organische Chemie und Biochemie der Technischen Hochschule, Petersenstrasse 22, D-6100 Darmstadt (Germany)

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Dipl.-Chem. Jürgen Meixner

Corresponding Author

Dipl.-Chem. Jürgen Meixner

Institut für Organische Chemie und Biochemie der Technischen Hochschule, Petersenstrasse 22, D-6100 Darmstadt (Germany)

Institut für Organische Chemie und Biochemie der Technischen Hochschule, Petersenstrasse 22, D-6100 Darmstadt (Germany)Search for more papers by this author
First published: March 1980
Citations: 19

This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie

Dedicated to Professor Matthias Seefelder on the occasion of his 60th birthday

Graphical Abstract

Optimum conditions can now be predicted for the radical copolymerization of alkenes. It is only necessary to measure krel for addition of the cyclohexyl radical (by the “mercury method”) which is linearly related to the copolymerization parameters Qj and ej of the alkenes.

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