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Outside Front Cover: Elucidating the Correlation Between the Redox Potential, Spin State and Crystal Structure in a Series of Ferrous Complexes With Redox-Active Ligands

Saioa Cobo

Corresponding Author

Saioa Cobo

Université Toulouse III-Paul Sabatier, Laboratoire de Chimie de Coodination, 205 Route de Narbonne, France

E-mail: [email protected]; [email protected]

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Livia Getzner

Livia Getzner

LCC: Laboratoire de Chimie de Coordination, CNRS, France

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Yasmine Remili

Yasmine Remili

LCC: Laboratoire de Chimie de Coordination, CNRS, France

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Zakaria Ziani

Zakaria Ziani

LCC: Laboratoire de Chimie de Coordination, CNRS, France

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Laure Vendier

Laure Vendier

LCC: Laboratoire de Chimie de Coordination, CNRS, France

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William Nicolazzi

William Nicolazzi

LCC: Laboratoire de Chimie de Coordination, CNRS, France

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Aurelian Rotaru

Aurelian Rotaru

University of Suceava: Universitatea Stefan cel Mare din Suceava, University of Suceava, France

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Haizhu Yu

Haizhu Yu

Anhui University, Anhui, France

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Gabor Molnar

Gabor Molnar

LCC: Laboratoire de Chimie de Coordination, CNRS, France

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Azzedine Bousseksou

Azzedine Bousseksou

LCC: Laboratoire de Chimie de Coordination, CNRS, France

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First published: 16 July 2025

Graphical Abstract

This image illustrates a Fe(II)-based Hofmann clathrate incorporating redox-active ligands, where electron transfer is highlighted. The three-dimensional framework represents the crystalline organization, while the spheres and curves depict the electronic motion within the material. This electron transfer is correlated with Marcus theory, explaining the coupled modulation of the redox potential and the spin transition temperature. Details are reported by Saioa Cobo et al. in their Research Article (e202506965).

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