Outside Front Cover: Elucidating the Correlation Between the Redox Potential, Spin State and Crystal Structure in a Series of Ferrous Complexes With Redox-Active Ligands
Graphical Abstract
This image illustrates a Fe(II)-based Hofmann clathrate incorporating redox-active ligands, where electron transfer is highlighted. The three-dimensional framework represents the crystalline organization, while the spheres and curves depict the electronic motion within the material. This electron transfer is correlated with Marcus theory, explaining the coupled modulation of the redox potential and the spin transition temperature. Details are reported by Saioa Cobo et al. in their Research Article (e202506965).