Multiple Structural and Phase Transformations of MOF and Selective Hydrocarbon Gas Separation in its Amorphous, Glass Phase States
This article relates to:
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Innentitelbild: Multiple Structural and Phase Transformations of MOF and Selective Hydrocarbon Gas Separation in its Amorphous, Glass Phase States (Angew. Chem. 9/2025)
- Jian Li,
- Jia-Xin Wu,
- Tao Liu,
- Jian Yang,
- Mei-Ling Wei,
- Chuang Yang,
- Qiubing Dong,
- Zheng Yin,
- Mohamedally Kurmoo,
- Ming-Hua Zeng,
- Volume 137Issue 9Angewandte Chemie
- First Published online: February 10, 2025
Dr. Jian Li
School of Chemistry and Pharmaceutical Sciences, State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, Guangxi Normal University, Guilin, 541004 P. R. China
Search for more papers by this authorJia-Xin Wu
School of Chemistry and Pharmaceutical Sciences, State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, Guangxi Normal University, Guilin, 541004 P. R. China
Search for more papers by this authorTao Liu
College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, 541004 P. R. China
Search for more papers by this authorJian Yang
College of Chemistry and Chemical Engineering, Hubei University, Wuhan, 430062 P. R. China
Search for more papers by this authorMei-Ling Wei
School of Chemistry and Pharmaceutical Sciences, State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, Guangxi Normal University, Guilin, 541004 P. R. China
Search for more papers by this authorChuang Yang
College of Chemistry and Chemical Engineering, Hubei University, Wuhan, 430062 P. R. China
Search for more papers by this authorDr. Qiubing Dong
School of Chemistry and Materials Science, Anhui Normal University, Wuhu, 241002 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Dr. Zheng Yin
School of Chemistry and Pharmaceutical Sciences, State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, Guangxi Normal University, Guilin, 541004 P. R. China
Search for more papers by this authorProf. Dr. Mohamedally Kurmoo
School of Chemistry and Pharmaceutical Sciences, State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, Guangxi Normal University, Guilin, 541004 P. R. China
Strasbourg Institute of Chemistry, University of Strasbourg, 4 Blaise Pascal Road, Strasbourg, Sedex, 67008 France
Search for more papers by this authorCorresponding Author
Prof. Dr. Ming-Hua Zeng
School of Chemistry and Pharmaceutical Sciences, State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, Guangxi Normal University, Guilin, 541004 P. R. China
College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, 541004 P. R. China
Search for more papers by this authorDr. Jian Li
School of Chemistry and Pharmaceutical Sciences, State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, Guangxi Normal University, Guilin, 541004 P. R. China
Search for more papers by this authorJia-Xin Wu
School of Chemistry and Pharmaceutical Sciences, State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, Guangxi Normal University, Guilin, 541004 P. R. China
Search for more papers by this authorTao Liu
College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, 541004 P. R. China
Search for more papers by this authorJian Yang
College of Chemistry and Chemical Engineering, Hubei University, Wuhan, 430062 P. R. China
Search for more papers by this authorMei-Ling Wei
School of Chemistry and Pharmaceutical Sciences, State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, Guangxi Normal University, Guilin, 541004 P. R. China
Search for more papers by this authorChuang Yang
College of Chemistry and Chemical Engineering, Hubei University, Wuhan, 430062 P. R. China
Search for more papers by this authorDr. Qiubing Dong
School of Chemistry and Materials Science, Anhui Normal University, Wuhu, 241002 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Dr. Zheng Yin
School of Chemistry and Pharmaceutical Sciences, State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, Guangxi Normal University, Guilin, 541004 P. R. China
Search for more papers by this authorProf. Dr. Mohamedally Kurmoo
School of Chemistry and Pharmaceutical Sciences, State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, Guangxi Normal University, Guilin, 541004 P. R. China
Strasbourg Institute of Chemistry, University of Strasbourg, 4 Blaise Pascal Road, Strasbourg, Sedex, 67008 France
Search for more papers by this authorCorresponding Author
Prof. Dr. Ming-Hua Zeng
School of Chemistry and Pharmaceutical Sciences, State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, Guangxi Normal University, Guilin, 541004 P. R. China
College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, 541004 P. R. China
Search for more papers by this authorAbstract
The first wide-view image of multiple structural and phase transformations for MOFs, ranging from crystal state transformations to the extreme limit approaching liquid/glass phase, was presented. The process involves i) an initial crystalline transformation from square-layer framework [Co2(pybz)2(CH3COO)2] ⋅ DMF (Co2) to a 3-fold interpenetrated and ordered vacancies contained framework [Co(pybz)2(CH3OH)2] ⋅ 2CH3OH (CoM) due to in situ disassemble-reassemble, ii) thermal induced departure of a pair of cis-form coordinated methanol in CoM leads to amorphous framework a-dCoM, iii) glass transition to super-cooled liquid scl-dCoM, iv) obtaining MOF glass g-dCoM upon quenching the super-cooled liquid, and v) re-crystallization of super-cooled liquid generates 6-fold interpenetrated dia-net framework [Co(pybz)2]6n (rec-dCoM) under further heating. The access to glass from CoM, provides a new self-perturbation strategy to create MOF glasses without melting. The wider pore size distribution in amorphous/glassy MOFs than crystalline precursor achieved the first time selective hydrocarbon gas separation by breakthrough experiments, which bring efficient separation of 1 : 99 C2H2/C2H4 by either a-dCoM or g-dCoM and produce polymer grade C2H4 with purity≥99.5 % after a single adsorption process. Furthermore, the mixture of 50 : 50 C3H6/C3H8 can be separated by a-dCoM.
Conflict of Interests
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available in the supplementary material of this article.
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