Volume 136, Issue 31 e202406597

Forschungsartikel

Dynamic Covalent Bonds Regulate Zinc Plating/Stripping Behaviors for High-Performance Zinc Ion Batteries

Yafei Guo

Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081 China

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Prof. Chong Luo,

Corresponding Author

Prof. Chong Luo

[email protected]

Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081 China

Advanced Technology Research Institute, Beijing Institute of Technology, Jinan, Shandong 250300 China

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Mingfang Yang,

Mingfang Yang

Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081 China

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Huirong Wang,

Huirong Wang

Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081 China

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Wenwen Ma,

Wenwen Ma

Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081 China

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Kaikai Hu,

Kaikai Hu

Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081 China

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Prof. Li Li,

Prof. Li Li

Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081 China

Advanced Technology Research Institute, Beijing Institute of Technology, Jinan, Shandong 250300 China

Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing, 100081 China

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Prof. Feng Wu,

Prof. Feng Wu

Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081 China

Advanced Technology Research Institute, Beijing Institute of Technology, Jinan, Shandong 250300 China

Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing, 100081 China

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Prof. Renjie Chen,

Corresponding Author

Prof. Renjie Chen

[email protected]

orcid.org/0000-0002-7001-2926

Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081 China

Advanced Technology Research Institute, Beijing Institute of Technology, Jinan, Shandong 250300 China

Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing, 100081 China

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Yafei Guo,

Yafei Guo

Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081 China

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Prof. Chong Luo,

Corresponding Author

Prof. Chong Luo

[email protected]

Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081 China

Advanced Technology Research Institute, Beijing Institute of Technology, Jinan, Shandong 250300 China

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Mingfang Yang,

Mingfang Yang

Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081 China

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Huirong Wang,

Huirong Wang

Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081 China

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Wenwen Ma,

Wenwen Ma

Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081 China

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Kaikai Hu,

Kaikai Hu

Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081 China

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Prof. Li Li,

Prof. Li Li

Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081 China

Advanced Technology Research Institute, Beijing Institute of Technology, Jinan, Shandong 250300 China

Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing, 100081 China

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Prof. Feng Wu,

Prof. Feng Wu

Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081 China

Advanced Technology Research Institute, Beijing Institute of Technology, Jinan, Shandong 250300 China

Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing, 100081 China

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Prof. Renjie Chen,

Corresponding Author

Prof. Renjie Chen

[email protected]

orcid.org/0000-0002-7001-2926

Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081 China

Advanced Technology Research Institute, Beijing Institute of Technology, Jinan, Shandong 250300 China

Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing, 100081 China

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First published: 17 May 2024

https://doi.org/10.1002/ange.202406597

Citations: 2

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Abstract

Artificial interfaces provide a comprehensive approach to controlling zinc dendrite and surface corrosion in zinc-based aqueous batteries (ZABs). However, due to consistent volume changes during zinc plating/stripping, traditional interfacial layers cannot consistently adapt to the dendrite surface, resulting in uncontrolled dendrite growth and hydrogen evolution. Herein, dynamic covalent bonds exhibit the Janus effect towards zinc deposition at different current densities, presenting a holistic strategy for stabilizing zinc anode. The PBSC intelligent artificial interface consisting of dynamic B−O covalent bonds is developed on zinc anode to mitigate hydrogen evolution and restrict dendrite expansion. Owing to the reversible dynamic bonds, PBSC exhibits shape self-adaptive characteristics at low current rates, which rearranges the network to accommodate volume changes during zinc plating/stripping, resisting hydrogen evolution. Moreover, the rapid association of B−O dynamic bonds enhances mechanical strength at dendrite tips, presenting a shear-thickening effect and suppressing further dendrite growth at high current rates. Therefore, the assembled symmetrical battery with PBSC maintains a stable cycle of 4500 hours without significant performance degradation and the PBSC@Zn||V₂O₅ pouch cell demonstrates a specific capacity exceeding 170 mAh g⁻¹. Overall, the intelligent interface with dynamic covalent bonds provides innovative approaches for zinc anode interfacial engineering and enhances cycling performance.

Conflict of interests

The authors declare no conflict of interest.

Open Research

Data Availability Statement

The data that support the findings of this study are available from the corresponding author upon reasonable request.

Supporting Information

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Dynamic Covalent Bonds Regulate Zinc Plating/Stripping Behaviors for High-Performance Zinc Ion Batteries

Abstract

Conflict of interests

Open Research

Data Availability Statement

Supporting Information

References

Citing Literature

References

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Dynamic Covalent Bonds Regulate Zinc Plating/Stripping Behaviors for High-Performance Zinc Ion Batteries

Abstract

Conflict of interests

Open Research

Data Availability Statement

Supporting Information

References

Citing Literature

References

Related

Information