Cooperative Ni(Co)-Ru-P Sites Activate Dehydrogenation for Hydrazine Oxidation Assisting Self-powered H2 Production
Yanmin Hu
Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035 China
Center of Advanced Nanocatalysis (CAN), Department of Applied Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026 China
These authors contributed equally to this work.
Search for more papers by this authorTingting Chao
Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035 China
Center of Advanced Nanocatalysis (CAN), Department of Applied Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026 China
These authors contributed equally to this work.
Search for more papers by this authorYapeng Li
Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035 China
These authors contributed equally to this work.
Search for more papers by this authorPeigen Liu
Center of Advanced Nanocatalysis (CAN), Department of Applied Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026 China
These authors contributed equally to this work.
Search for more papers by this authorTonghui Zhao
Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035 China
Search for more papers by this authorGe Yu
Center of Advanced Nanocatalysis (CAN), Department of Applied Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026 China
Search for more papers by this authorCai Chen
Center of Advanced Nanocatalysis (CAN), Department of Applied Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026 China
Search for more papers by this authorXiao Liang
Department of Chemistry, Tsinghua University, Beijing, China
Search for more papers by this authorHuile Jin
Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035 China
Search for more papers by this authorCorresponding Author
Shuwen Niu
Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035 China
Center of Advanced Nanocatalysis (CAN), Department of Applied Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026 China
Search for more papers by this authorCorresponding Author
Wei Chen
Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035 China
Search for more papers by this authorCorresponding Author
Dingsheng Wang
Department of Chemistry, Tsinghua University, Beijing, China
Search for more papers by this authorYadong Li
Department of Chemistry, Tsinghua University, Beijing, China
Search for more papers by this authorYanmin Hu
Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035 China
Center of Advanced Nanocatalysis (CAN), Department of Applied Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026 China
These authors contributed equally to this work.
Search for more papers by this authorTingting Chao
Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035 China
Center of Advanced Nanocatalysis (CAN), Department of Applied Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026 China
These authors contributed equally to this work.
Search for more papers by this authorYapeng Li
Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035 China
These authors contributed equally to this work.
Search for more papers by this authorPeigen Liu
Center of Advanced Nanocatalysis (CAN), Department of Applied Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026 China
These authors contributed equally to this work.
Search for more papers by this authorTonghui Zhao
Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035 China
Search for more papers by this authorGe Yu
Center of Advanced Nanocatalysis (CAN), Department of Applied Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026 China
Search for more papers by this authorCai Chen
Center of Advanced Nanocatalysis (CAN), Department of Applied Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026 China
Search for more papers by this authorXiao Liang
Department of Chemistry, Tsinghua University, Beijing, China
Search for more papers by this authorHuile Jin
Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035 China
Search for more papers by this authorCorresponding Author
Shuwen Niu
Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035 China
Center of Advanced Nanocatalysis (CAN), Department of Applied Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026 China
Search for more papers by this authorCorresponding Author
Wei Chen
Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035 China
Search for more papers by this authorCorresponding Author
Dingsheng Wang
Department of Chemistry, Tsinghua University, Beijing, China
Search for more papers by this authorYadong Li
Department of Chemistry, Tsinghua University, Beijing, China
Search for more papers by this authorAbstract
Water electrolysis for H2 production is restricted by the sluggish oxygen evolution reaction (OER). Using the thermodynamically more favorable hydrazine oxidation reaction (HzOR) to replace OER has attracted ever-growing attention. Herein, we report a twisted NiCoP nanowire array immobilized with Ru single atoms (Ru1−NiCoP) as superior bifunctional electrocatalyst toward both HzOR and hydrogen evolution reaction (HER), realizing an ultralow working potential of −60 mV and overpotential of 32 mV for a current density of 10 mA cm−2, respectively. Inspiringly, two-electrode electrolyzer based on overall hydrazine splitting (OHzS) demonstrates outstanding activity with a record-high current density of 522 mA cm−2 at cell voltage of 0.3 V. DFT calculations elucidate the cooperative Ni(Co)−Ru−P sites in Ru1−NiCoP optimize H* adsorption, and enhance adsorption of *N2H2 to significantly lower the energy barrier for hydrazine dehydrogenation. Moreover, a self-powered H2 production system utilizing OHzS device driven by direct hydrazine fuel cell (DHzFC) achieve a satisfactory rate of 24.0 mol h−1 m−2.
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
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