Enhanced Activity of Enzyme Immobilized on Hydrophobic ZIF-8 Modified by Ni2+ Ions
Corresponding Author
Xiao-Gang Yang
College of Chemistry and Chemical Engineering, Luoyang Normal University, Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang, 471934 P. R. China
Search for more papers by this authorJi-Rui Zhang
College of Chemistry and Chemical Engineering, Luoyang Normal University, Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang, 471934 P. R. China
Search for more papers by this authorXu-Ke Tian
College of Chemistry and Chemical Engineering, Luoyang Normal University, Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang, 471934 P. R. China
Search for more papers by this authorJian-Hua Qin
College of Chemistry and Chemical Engineering, Luoyang Normal University, Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang, 471934 P. R. China
Search for more papers by this authorXin-Ya Zhang
College of Chemistry and Chemical Engineering, Luoyang Normal University, Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang, 471934 P. R. China
Search for more papers by this authorCorresponding Author
Lu-Fang Ma
College of Chemistry and Chemical Engineering, Luoyang Normal University, Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang, 471934 P. R. China
Search for more papers by this authorCorresponding Author
Xiao-Gang Yang
College of Chemistry and Chemical Engineering, Luoyang Normal University, Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang, 471934 P. R. China
Search for more papers by this authorJi-Rui Zhang
College of Chemistry and Chemical Engineering, Luoyang Normal University, Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang, 471934 P. R. China
Search for more papers by this authorXu-Ke Tian
College of Chemistry and Chemical Engineering, Luoyang Normal University, Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang, 471934 P. R. China
Search for more papers by this authorJian-Hua Qin
College of Chemistry and Chemical Engineering, Luoyang Normal University, Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang, 471934 P. R. China
Search for more papers by this authorXin-Ya Zhang
College of Chemistry and Chemical Engineering, Luoyang Normal University, Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang, 471934 P. R. China
Search for more papers by this authorCorresponding Author
Lu-Fang Ma
College of Chemistry and Chemical Engineering, Luoyang Normal University, Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang, 471934 P. R. China
Search for more papers by this authorAbstract
The development of efficient enzyme immobilization to promote their recyclability and activity is highly desirable. Zeolitic imidazolate framework-8 (ZIF-8) has been proved to be an effective platform for enzyme immobilization due to its easy preparation and biocompatibility. However, the intrinsic hydrophobic characteristic hinders its further development in this filed. Herein, a facile synthesis approach was developed to immobilize pepsin (PEP) on the ZIF-8 carrier by using Ni2+ ions as anchor (ZIF-8@PEP-Ni). By contrast, the direct coating of PEP on the surface of ZIF-8 (ZIF-8@PEP) generated significant conformational changes. Electrochemical oxygen evolution reaction (OER) was employed to study the catalytic activity of immobilized PEP. The ZIF-8@PEP-Ni composite attains remarkable OER performance with an ultralow overpotential of only 127 mV at 10 mA cm−2, which is much lower than the 690 and 919 mV overpotential values of ZIF-8@PEP and PEP, respectively.
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
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