Locally Ordered Graphitized Carbon Cathodes for High-Capacity Dual-Ion Batteries
Kai Yang
Functional Thin Films Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China
Nano Science and Technology Institute, University of Science and Technology of China, Suzhou, 215123 China
These authors contributed equally to this work.
Search for more papers by this authorDr. Qirong Liu
Functional Thin Films Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China
These authors contributed equally to this work.
Search for more papers by this authorDr. Yongping Zheng
Functional Thin Films Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China
These authors contributed equally to this work.
Search for more papers by this authorHang Yin
Functional Thin Films Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China
Search for more papers by this authorCorresponding Author
Prof. Shanqing Zhang
Center for Clean Environment and Energy School of Environment and Science, Griffith University, Brisbane, Queensland, 4222 Australia
Search for more papers by this authorCorresponding Author
Prof. Yongbing Tang
Functional Thin Films Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China
Nano Science and Technology Institute, University of Science and Technology of China, Suzhou, 215123 China
Key Laboratory of Advanced Materials Processing & Mold, Ministry of Education, Zhengzhou University, Zhengzhou, 450002 China
School of Chemical Sciences, Ministry of Education, University of Chinese Academy of Sciences, Beijing, 100049 China
Search for more papers by this authorKai Yang
Functional Thin Films Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China
Nano Science and Technology Institute, University of Science and Technology of China, Suzhou, 215123 China
These authors contributed equally to this work.
Search for more papers by this authorDr. Qirong Liu
Functional Thin Films Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China
These authors contributed equally to this work.
Search for more papers by this authorDr. Yongping Zheng
Functional Thin Films Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China
These authors contributed equally to this work.
Search for more papers by this authorHang Yin
Functional Thin Films Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China
Search for more papers by this authorCorresponding Author
Prof. Shanqing Zhang
Center for Clean Environment and Energy School of Environment and Science, Griffith University, Brisbane, Queensland, 4222 Australia
Search for more papers by this authorCorresponding Author
Prof. Yongbing Tang
Functional Thin Films Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China
Nano Science and Technology Institute, University of Science and Technology of China, Suzhou, 215123 China
Key Laboratory of Advanced Materials Processing & Mold, Ministry of Education, Zhengzhou University, Zhengzhou, 450002 China
School of Chemical Sciences, Ministry of Education, University of Chinese Academy of Sciences, Beijing, 100049 China
Search for more papers by this authorAbstract
Dual-ion batteries (DIBs) inherently suffer from limited energy density. Proposed here is a strategy to effectively tackle this issue by employing locally ordered graphitized carbon (LOGC) cathodes. Quantum mechanical modeling suggests that strong anion–anion repulsions and severe expansion at the deep-charging stage raise the anion intercalation voltage, therefore only part of the theoretical anion storage sites in graphite is accessible. The LOGC interconnected with disordered carbon is predicted to weaken the interlaminar van der Waals interactions, while disordered carbons not only interconnect the dispersed nanographite but also partially buffer severe anion–anion repulsion and offer extra capacitive anion storage sites. As a proof-of-concept, ketjen black (KB) with LOGC was used as a model cathode for a potassium-based DIB (KDIB). The KDIB delivers an unprecedentedly high specific capacity of 232 mAh g−1 at 50 mA g−1, a good rate capability of 110 mAh g−1 at 2000 mA g−1, and excellent cycling stability of 1000 cycles without obvious capacity fading.
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