Bis-Cyclooctatetraenyl Thulium(II): Highly Reducing Lanthanide Sandwich Single-Molecule Magnets
Dr. Jules Moutet
LCM, CNRS, Ecole polytechnique, Institut Polytechnique Paris, Route de Saclay, 91128 Palaiseau, cedex, France
Search for more papers by this authorJules Schleinitz
LCM, CNRS, Ecole polytechnique, Institut Polytechnique Paris, Route de Saclay, 91128 Palaiseau, cedex, France
Search for more papers by this authorLéo La Droitte
Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)–UMR 6226, 35000 Rennes, France
Search for more papers by this authorMaxime Tricoire
LCM, CNRS, Ecole polytechnique, Institut Polytechnique Paris, Route de Saclay, 91128 Palaiseau, cedex, France
Search for more papers by this authorDr. Fabrice Pointillart
Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)–UMR 6226, 35000 Rennes, France
Search for more papers by this authorDr. Frédéric Gendron
Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)–UMR 6226, 35000 Rennes, France
Search for more papers by this authorDr. Thomas Simler
LCM, CNRS, Ecole polytechnique, Institut Polytechnique Paris, Route de Saclay, 91128 Palaiseau, cedex, France
Search for more papers by this authorDr. Carine Clavaguéra
Université Paris-Saclay, CNRS, Institut de Chimie Physique, UMR 8000, 91405 Orsay cedex, France
Search for more papers by this authorDr. Boris Le Guennic
Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)–UMR 6226, 35000 Rennes, France
Search for more papers by this authorCorresponding Author
Dr. Olivier Cador
Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)–UMR 6226, 35000 Rennes, France
Search for more papers by this authorCorresponding Author
Dr. Grégory Nocton
LCM, CNRS, Ecole polytechnique, Institut Polytechnique Paris, Route de Saclay, 91128 Palaiseau, cedex, France
Search for more papers by this authorDr. Jules Moutet
LCM, CNRS, Ecole polytechnique, Institut Polytechnique Paris, Route de Saclay, 91128 Palaiseau, cedex, France
Search for more papers by this authorJules Schleinitz
LCM, CNRS, Ecole polytechnique, Institut Polytechnique Paris, Route de Saclay, 91128 Palaiseau, cedex, France
Search for more papers by this authorLéo La Droitte
Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)–UMR 6226, 35000 Rennes, France
Search for more papers by this authorMaxime Tricoire
LCM, CNRS, Ecole polytechnique, Institut Polytechnique Paris, Route de Saclay, 91128 Palaiseau, cedex, France
Search for more papers by this authorDr. Fabrice Pointillart
Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)–UMR 6226, 35000 Rennes, France
Search for more papers by this authorDr. Frédéric Gendron
Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)–UMR 6226, 35000 Rennes, France
Search for more papers by this authorDr. Thomas Simler
LCM, CNRS, Ecole polytechnique, Institut Polytechnique Paris, Route de Saclay, 91128 Palaiseau, cedex, France
Search for more papers by this authorDr. Carine Clavaguéra
Université Paris-Saclay, CNRS, Institut de Chimie Physique, UMR 8000, 91405 Orsay cedex, France
Search for more papers by this authorDr. Boris Le Guennic
Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)–UMR 6226, 35000 Rennes, France
Search for more papers by this authorCorresponding Author
Dr. Olivier Cador
Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)–UMR 6226, 35000 Rennes, France
Search for more papers by this authorCorresponding Author
Dr. Grégory Nocton
LCM, CNRS, Ecole polytechnique, Institut Polytechnique Paris, Route de Saclay, 91128 Palaiseau, cedex, France
Search for more papers by this authorIn memory of Professor R. A. Andersen
Abstract
Divalent lanthanide organometallics are well-known highly reducing compounds usually used for single electron transfer reactivity and small molecule activation. Thus, their very reactive nature prevented for many years the study of their physical properties, such as magnetic studies on a reliable basis. Herein, the access to rare organometallic sandwich compounds of TmII with the cyclooctatetraenyl (Cot) ligand impacts on the use of divalent organolanthanide compounds as an additional strategy for the design of performing Single Molecule Magnets (SMM). The first divalent thulium sandwich complex with f13 configuration behaving as a single-molecule magnet in absence of DC field is highlighted.
Conflict of interest
The authors declare no conflict of interest.
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