Diols Activation by Cu/Borinic Acids Synergistic Catalysis in Atroposelective Ring-Opening of Cyclic Diaryliodoniums
Dr. Kun Zhao
Hefei National Laboratory for Physical Sciences at the Microscale, and Department of Chemistry, Center for Excellence in Molecular Synthesis, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui, 230026 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorShan Yang
Hefei National Laboratory for Physical Sciences at the Microscale, and Department of Chemistry, Center for Excellence in Molecular Synthesis, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui, 230026 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorQi Gong
Hefei National Laboratory for Physical Sciences at the Microscale, and Department of Chemistry, Center for Excellence in Molecular Synthesis, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui, 230026 P. R. China
Search for more papers by this authorLonghui Duan
Hefei National Laboratory for Physical Sciences at the Microscale, and Department of Chemistry, Center for Excellence in Molecular Synthesis, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui, 230026 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Zhenhua Gu
Hefei National Laboratory for Physical Sciences at the Microscale, and Department of Chemistry, Center for Excellence in Molecular Synthesis, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui, 230026 P. R. China
Ocean College, Minjiang University, Fuzhou, Fujian, 350108 P. R. China
Search for more papers by this authorDr. Kun Zhao
Hefei National Laboratory for Physical Sciences at the Microscale, and Department of Chemistry, Center for Excellence in Molecular Synthesis, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui, 230026 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorShan Yang
Hefei National Laboratory for Physical Sciences at the Microscale, and Department of Chemistry, Center for Excellence in Molecular Synthesis, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui, 230026 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorQi Gong
Hefei National Laboratory for Physical Sciences at the Microscale, and Department of Chemistry, Center for Excellence in Molecular Synthesis, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui, 230026 P. R. China
Search for more papers by this authorLonghui Duan
Hefei National Laboratory for Physical Sciences at the Microscale, and Department of Chemistry, Center for Excellence in Molecular Synthesis, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui, 230026 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Zhenhua Gu
Hefei National Laboratory for Physical Sciences at the Microscale, and Department of Chemistry, Center for Excellence in Molecular Synthesis, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui, 230026 P. R. China
Ocean College, Minjiang University, Fuzhou, Fujian, 350108 P. R. China
Search for more papers by this authorAbstract
A Cu-catalyzed enantioselective ring-opening alkoxygenation reaction of cyclic diaryliodonium salts and diols in the presence of borinic acids was reported. Tuning structure of borinic acids with six or five-membered ring skeleton could selectively activate 1,2-diols or 1,4-diols. A catalytic cycle through a key ion pair model that accounts for the observed enantioselectivity was proposed.
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