Adsorption Site Selective Occupation Strategy within a Metal–Organic Framework for Highly Efficient Sieving Acetylene from Carbon Dioxide
Lingzhi Yang
State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum (East China), Qingdao, 266580 P. R. China
Search for more papers by this authorDr. Liting Yan
Key Laboratory of Processing and Testing Technology of Glass & Functional Ceramics of Shandong Province, School of Materials Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 P. R. China
Search for more papers by this authorDr. Ying Wang
Key Laboratory of Macromolecular Science of Shaanxi Province, Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an, Shaanxi, 710062 P. R. China
Search for more papers by this authorZhi Liu
State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum (East China), Qingdao, 266580 P. R. China
Search for more papers by this authorJiangxiu He
State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum (East China), Qingdao, 266580 P. R. China
Search for more papers by this authorQiuju Fu
State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum (East China), Qingdao, 266580 P. R. China
Search for more papers by this authorDr. Dandan Liu
Institute of New Energy, China University of Petroleum (East China), Qingdao, 266580 P. R. China
Search for more papers by this authorDr. Xin Gu
Institute of New Energy, China University of Petroleum (East China), Qingdao, 266580 P. R. China
Search for more papers by this authorDr. Pengcheng Dai
Institute of New Energy, China University of Petroleum (East China), Qingdao, 266580 P. R. China
Search for more papers by this authorDr. Liangjun Li
Institute of New Energy, China University of Petroleum (East China), Qingdao, 266580 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Xuebo Zhao
State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum (East China), Qingdao, 266580 P. R. China
Key Laboratory of Processing and Testing Technology of Glass & Functional Ceramics of Shandong Province, School of Materials Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 P. R. China
Search for more papers by this authorLingzhi Yang
State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum (East China), Qingdao, 266580 P. R. China
Search for more papers by this authorDr. Liting Yan
Key Laboratory of Processing and Testing Technology of Glass & Functional Ceramics of Shandong Province, School of Materials Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 P. R. China
Search for more papers by this authorDr. Ying Wang
Key Laboratory of Macromolecular Science of Shaanxi Province, Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an, Shaanxi, 710062 P. R. China
Search for more papers by this authorZhi Liu
State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum (East China), Qingdao, 266580 P. R. China
Search for more papers by this authorJiangxiu He
State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum (East China), Qingdao, 266580 P. R. China
Search for more papers by this authorQiuju Fu
State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum (East China), Qingdao, 266580 P. R. China
Search for more papers by this authorDr. Dandan Liu
Institute of New Energy, China University of Petroleum (East China), Qingdao, 266580 P. R. China
Search for more papers by this authorDr. Xin Gu
Institute of New Energy, China University of Petroleum (East China), Qingdao, 266580 P. R. China
Search for more papers by this authorDr. Pengcheng Dai
Institute of New Energy, China University of Petroleum (East China), Qingdao, 266580 P. R. China
Search for more papers by this authorDr. Liangjun Li
Institute of New Energy, China University of Petroleum (East China), Qingdao, 266580 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Xuebo Zhao
State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum (East China), Qingdao, 266580 P. R. China
Key Laboratory of Processing and Testing Technology of Glass & Functional Ceramics of Shandong Province, School of Materials Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 P. R. China
Search for more papers by this authorAbstract
The separation of acetylene and carbon dioxide is an essential but challenging process owing to the similar molecular sizes and physical properties of the two gas molecules. Notably, these molecules usually exhibit different orientations in the pore channel. We report an adsorption site selective occupation strategy by taking advantage of differences in orientation to sieve the C2H2 from CO2 in a judiciously designed amine-functionalized metal–organic framework, termed CPL-1-NH2. In this material, the incorporation of amino groups not only occupies the adsorption sites of CO2 molecules and shields the interaction of uncoordinated oxygen atom and CO2 molecules resulting in a negligible adsorption amount and a decrease in enthalpy of adsorption but also strengthened the binding affinity toward C2H2 molecules. This material thus shows an extremely high amount of C2H2 at low pressure and a remarkably high C2H2/CO2 IAST selectivity (119) at 1 bar and 298 K.
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