Synthesis of Polycarboxylate Rhodium(II) Metal–Organic Polyhedra (MOPs) and their use as Building Blocks for Highly Connected Metal–Organic Frameworks (MOFs)
Dr. Thais Grancha
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, 08193 Barcelona, Spain
Search for more papers by this authorCorresponding Author
Dr. Arnau Carné-Sánchez
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, 08193 Barcelona, Spain
Search for more papers by this authorDr. Farnoosh Zarekarizi
Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box: 14115-4838, Tehran, Islamic Republic of Iran
Search for more papers by this authorLaura Hernández-López
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, 08193 Barcelona, Spain
Search for more papers by this authorDr. Jorge Albalad
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, 08193 Barcelona, Spain
Search for more papers by this authorAkim Khobotov
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, 08193 Barcelona, Spain
Search for more papers by this authorDr. Vincent Guillerm
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, 08193 Barcelona, Spain
Search for more papers by this authorDr. Ali Morsali
Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box: 14115-4838, Tehran, Islamic Republic of Iran
Search for more papers by this authorDr. Judith Juanhuix
ALBA Synchrotron, 08290 Cerdanyola del Vallès, Barcelona, Spain
Search for more papers by this authorDr. Felipe Gándara
Department of New Architectures in Materials Chemistry, Materials Science Institute of Madrid—CSIC, Sor Juana Inés de la Cruz 3, 28049 Madrid, Spain
Search for more papers by this authorDr. Inhar Imaz
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, 08193 Barcelona, Spain
Search for more papers by this authorCorresponding Author
Prof. Dr. Daniel Maspoch
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, 08193 Barcelona, Spain
ICREA, Pg. Lluís Companys 23, 08010 Barcelona, Spain
Search for more papers by this authorDr. Thais Grancha
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, 08193 Barcelona, Spain
Search for more papers by this authorCorresponding Author
Dr. Arnau Carné-Sánchez
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, 08193 Barcelona, Spain
Search for more papers by this authorDr. Farnoosh Zarekarizi
Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box: 14115-4838, Tehran, Islamic Republic of Iran
Search for more papers by this authorLaura Hernández-López
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, 08193 Barcelona, Spain
Search for more papers by this authorDr. Jorge Albalad
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, 08193 Barcelona, Spain
Search for more papers by this authorAkim Khobotov
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, 08193 Barcelona, Spain
Search for more papers by this authorDr. Vincent Guillerm
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, 08193 Barcelona, Spain
Search for more papers by this authorDr. Ali Morsali
Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box: 14115-4838, Tehran, Islamic Republic of Iran
Search for more papers by this authorDr. Judith Juanhuix
ALBA Synchrotron, 08290 Cerdanyola del Vallès, Barcelona, Spain
Search for more papers by this authorDr. Felipe Gándara
Department of New Architectures in Materials Chemistry, Materials Science Institute of Madrid—CSIC, Sor Juana Inés de la Cruz 3, 28049 Madrid, Spain
Search for more papers by this authorDr. Inhar Imaz
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, 08193 Barcelona, Spain
Search for more papers by this authorCorresponding Author
Prof. Dr. Daniel Maspoch
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, 08193 Barcelona, Spain
ICREA, Pg. Lluís Companys 23, 08010 Barcelona, Spain
Search for more papers by this authorAbstract
Use of preformed metal-organic polyhedra (MOPs) as supermolecular building blocks (SBBs) for the synthesis of metal-organic frameworks (MOFs) remains underexplored due to lack of robust functionalized MOPs. Herein we report the use of polycarboxylate cuboctahedral RhII-MOPs for constructing highly-connected MOFs. Cuboctahedral MOPs were functionalized with carboxylic acid groups on their 12 vertices or 24 edges through coordinative or covalent post-synthetic routes, respectively. We then used each isolated polycarboxylate RhII-MOP as 12-c cuboctahedral or 24-c rhombicuboctahedral SBBs that, upon linkage with metallic secondary building units (SBUs), afford bimetallic highly-connected MOFs. The assembly of a pre-synthesized 12-c SBB with a 4-c paddle-wheel SBU, and a 24-c SBB with a 3-c triangular CuII SBU gave rise to bimetallic MOFs having ftw (4,12)-c or rht (3,24)-c topologies, respectively.
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