Electrochemical Synthesis of Thienoacene Derivatives: Transition-Metal-Free Dehydrogenative C−S Coupling Promoted by a Halogen Mediator
Corresponding Author
Dr. Koichi Mitsudo
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushima-naka, Kita-ku, Okayama, 700-8530 Japan
Search for more papers by this authorRen Matsuo
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushima-naka, Kita-ku, Okayama, 700-8530 Japan
Search for more papers by this authorToki Yonezawa
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushima-naka, Kita-ku, Okayama, 700-8530 Japan
Search for more papers by this authorHaruka Inoue
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushima-naka, Kita-ku, Okayama, 700-8530 Japan
Search for more papers by this authorDr. Hiroki Mandai
Department of Medical Technology, Gifu University of Medical Science, 4-3-3 Nijigaoka, Kani, Gifu 5, 09-0293 Japan
Search for more papers by this authorCorresponding Author
Prof. Dr. Seiji Suga
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushima-naka, Kita-ku, Okayama, 700-8530 Japan
Search for more papers by this authorCorresponding Author
Dr. Koichi Mitsudo
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushima-naka, Kita-ku, Okayama, 700-8530 Japan
Search for more papers by this authorRen Matsuo
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushima-naka, Kita-ku, Okayama, 700-8530 Japan
Search for more papers by this authorToki Yonezawa
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushima-naka, Kita-ku, Okayama, 700-8530 Japan
Search for more papers by this authorHaruka Inoue
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushima-naka, Kita-ku, Okayama, 700-8530 Japan
Search for more papers by this authorDr. Hiroki Mandai
Department of Medical Technology, Gifu University of Medical Science, 4-3-3 Nijigaoka, Kani, Gifu 5, 09-0293 Japan
Search for more papers by this authorCorresponding Author
Prof. Dr. Seiji Suga
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushima-naka, Kita-ku, Okayama, 700-8530 Japan
Search for more papers by this authorAbstract
The first electrochemical dehydrogenative C−S bond formation leading to thienoacene derivatives is described. Several thienoacene derivatives were synthesized by dehydrogenative C−H/S−H coupling. The addition of nBu4NBr, which catalytically promoted the reaction as a halogen mediator, was essential.
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