An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses
Youchao Liu
State Key Laboratory of Structural Chemistry, Fujian institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorXiaomeng Liu
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Science Sciences, Beijing, 100049 P. R. China
Search for more papers by this authorShuai Liu
State Key Laboratory of Structural Chemistry, Fujian institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorQingran Ding
State Key Laboratory of Structural Chemistry, Fujian institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002 P. R. China
University of Chinese Academy of Science Sciences, Beijing, 100049 P. R. China
Search for more papers by this authorYanqiang Li
State Key Laboratory of Structural Chemistry, Fujian institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorProf. Lina Li
State Key Laboratory of Structural Chemistry, Fujian institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Sangen Zhao
State Key Laboratory of Structural Chemistry, Fujian institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorProf. Zheshuai Lin
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorProf. Junhua Luo
State Key Laboratory of Structural Chemistry, Fujian institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorProf. Maochun Hong
State Key Laboratory of Structural Chemistry, Fujian institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorYouchao Liu
State Key Laboratory of Structural Chemistry, Fujian institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorXiaomeng Liu
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Science Sciences, Beijing, 100049 P. R. China
Search for more papers by this authorShuai Liu
State Key Laboratory of Structural Chemistry, Fujian institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorQingran Ding
State Key Laboratory of Structural Chemistry, Fujian institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002 P. R. China
University of Chinese Academy of Science Sciences, Beijing, 100049 P. R. China
Search for more papers by this authorYanqiang Li
State Key Laboratory of Structural Chemistry, Fujian institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorProf. Lina Li
State Key Laboratory of Structural Chemistry, Fujian institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Sangen Zhao
State Key Laboratory of Structural Chemistry, Fujian institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorProf. Zheshuai Lin
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorProf. Junhua Luo
State Key Laboratory of Structural Chemistry, Fujian institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorProf. Maochun Hong
State Key Laboratory of Structural Chemistry, Fujian institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002 P. R. China
Search for more papers by this authorAbstract
Antimony(III) borates with a stereochemical active lone pair remained unknown, although the first antimony borate was reported more than twenty years ago. Now, the first antimony(III) borate in a closed system is successfully synthesized, namely SbB3O6. Remarkably, SbB3O6 not only exhibits an exceptional linear optical response, that is, birefringence of Δn=0.290 at the wavelength of 546 nm, which is the largest among borates, but also has a strong nonlinear optical response of 3.5 times larger than the benchmark KH2PO4, exceeding those of most borates. Theoretical calculations reveal that the coexistence of strong linear and nonlinear optical responses in SbB3O6 should be attributable to the synergistic effect of π-conjugated B−O anionic groups and Sb3+ with stereochemically active lone pair. This work provides a new class of optical bi-functional materials with potential prospects in integrated optical devices.
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