Formation of a Single-Crystal Aluminum-Based MOF Nanowire with Graphene Oxide Nanoscrolls as Structure-Directing Agents
Dr. Mégane Muschi
Institut des Matériaux Poreux de Paris, UMR 8004 CNRS-ENS-ESPCI, PSL research university, Paris, France
Search for more papers by this authorAnusha Lalitha
Institut Charles Gerhardt Montpellier, Univ. Montpellier, CNRS, ENSCM, Montpellier, France
Search for more papers by this authorDr. Saad Sene
Institut des Matériaux Poreux de Paris, UMR 8004 CNRS-ENS-ESPCI, PSL research university, Paris, France
Search for more papers by this authorDr. Damien Aureau
Institut Lavoisier de Versailles, UMR CNRS 8180, Université de Versailles St Quentin en Yvelines, Université Paris Saclay, Versailles, France
Search for more papers by this authorDr. Mathieu Fregnaux
Institut Lavoisier de Versailles, UMR CNRS 8180, Université de Versailles St Quentin en Yvelines, Université Paris Saclay, Versailles, France
Search for more papers by this authorDr. Imène Esteve
Sorbonne Université, UMR CNRS 7590, MNHN, IRD, Institut de Minéralogie, de Physique des Matériaux et de Cosmochimie, IMPMC, 75005 Paris, France
Search for more papers by this authorDr. Lucie Rivier
Institut Lavoisier de Versailles, UMR CNRS 8180, Université de Versailles St Quentin en Yvelines, Université Paris Saclay, Versailles, France
Search for more papers by this authorDr. Naseem Ramsahye
Institut Charles Gerhardt Montpellier, Univ. Montpellier, CNRS, ENSCM, Montpellier, France
Search for more papers by this authorDr. Sabine Devautour-Vinot
Institut Charles Gerhardt Montpellier, Univ. Montpellier, CNRS, ENSCM, Montpellier, France
Search for more papers by this authorDr. Clémence Sicard
Institut Lavoisier de Versailles, UMR CNRS 8180, Université de Versailles St Quentin en Yvelines, Université Paris Saclay, Versailles, France
Search for more papers by this authorProf. Nicolas Menguy
Sorbonne Université, UMR CNRS 7590, MNHN, IRD, Institut de Minéralogie, de Physique des Matériaux et de Cosmochimie, IMPMC, 75005 Paris, France
Search for more papers by this authorDr. Christian Serre
Institut des Matériaux Poreux de Paris, UMR 8004 CNRS-ENS-ESPCI, PSL research university, Paris, France
Search for more papers by this authorCorresponding Author
Prof. Guillaume Maurin
Institut Charles Gerhardt Montpellier, Univ. Montpellier, CNRS, ENSCM, Montpellier, France
Search for more papers by this authorCorresponding Author
Prof. Nathalie Steunou
Institut des Matériaux Poreux de Paris, UMR 8004 CNRS-ENS-ESPCI, PSL research university, Paris, France
Institut Lavoisier de Versailles, UMR CNRS 8180, Université de Versailles St Quentin en Yvelines, Université Paris Saclay, Versailles, France
Search for more papers by this authorDr. Mégane Muschi
Institut des Matériaux Poreux de Paris, UMR 8004 CNRS-ENS-ESPCI, PSL research university, Paris, France
Search for more papers by this authorAnusha Lalitha
Institut Charles Gerhardt Montpellier, Univ. Montpellier, CNRS, ENSCM, Montpellier, France
Search for more papers by this authorDr. Saad Sene
Institut des Matériaux Poreux de Paris, UMR 8004 CNRS-ENS-ESPCI, PSL research university, Paris, France
Search for more papers by this authorDr. Damien Aureau
Institut Lavoisier de Versailles, UMR CNRS 8180, Université de Versailles St Quentin en Yvelines, Université Paris Saclay, Versailles, France
Search for more papers by this authorDr. Mathieu Fregnaux
Institut Lavoisier de Versailles, UMR CNRS 8180, Université de Versailles St Quentin en Yvelines, Université Paris Saclay, Versailles, France
Search for more papers by this authorDr. Imène Esteve
Sorbonne Université, UMR CNRS 7590, MNHN, IRD, Institut de Minéralogie, de Physique des Matériaux et de Cosmochimie, IMPMC, 75005 Paris, France
Search for more papers by this authorDr. Lucie Rivier
Institut Lavoisier de Versailles, UMR CNRS 8180, Université de Versailles St Quentin en Yvelines, Université Paris Saclay, Versailles, France
Search for more papers by this authorDr. Naseem Ramsahye
Institut Charles Gerhardt Montpellier, Univ. Montpellier, CNRS, ENSCM, Montpellier, France
Search for more papers by this authorDr. Sabine Devautour-Vinot
Institut Charles Gerhardt Montpellier, Univ. Montpellier, CNRS, ENSCM, Montpellier, France
Search for more papers by this authorDr. Clémence Sicard
Institut Lavoisier de Versailles, UMR CNRS 8180, Université de Versailles St Quentin en Yvelines, Université Paris Saclay, Versailles, France
Search for more papers by this authorProf. Nicolas Menguy
Sorbonne Université, UMR CNRS 7590, MNHN, IRD, Institut de Minéralogie, de Physique des Matériaux et de Cosmochimie, IMPMC, 75005 Paris, France
Search for more papers by this authorDr. Christian Serre
Institut des Matériaux Poreux de Paris, UMR 8004 CNRS-ENS-ESPCI, PSL research university, Paris, France
Search for more papers by this authorCorresponding Author
Prof. Guillaume Maurin
Institut Charles Gerhardt Montpellier, Univ. Montpellier, CNRS, ENSCM, Montpellier, France
Search for more papers by this authorCorresponding Author
Prof. Nathalie Steunou
Institut des Matériaux Poreux de Paris, UMR 8004 CNRS-ENS-ESPCI, PSL research university, Paris, France
Institut Lavoisier de Versailles, UMR CNRS 8180, Université de Versailles St Quentin en Yvelines, Université Paris Saclay, Versailles, France
Search for more papers by this authorIn memory of Professor François Couty
Abstract
An innovative strategy is proposed to synthesize single-crystal nanowires (NWs) of the Al3+ dicarboxylate MIL-69(Al) MOF by using graphene oxide nanoscrolls as structure-directing agents. MIL-69(Al) NWs with an average diameter of 70±20 nm and lengths up to 2 μm were found to preferentially grow along the [001] crystallographic direction. Advanced characterization methods (electron diffraction, TEM, STEM-HAADF, SEM, XPS) and molecular modeling revealed the mechanism of formation of MIL-69(Al) NWs involving size-confinement and templating effects. The formation of MIL-69(Al) seeds and the self-scroll of GO sheets followed by the anisotropic growth of MIL-69(Al) crystals are mediated by specific GO sheets/MOF interactions. This study delivers an unprecedented approach to control the design of 1D MOF nanostructures and superstructures.
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