Gold(III) π-Allyl Complexes
Dr. Jessica Rodriguez
Laboratoire Hétérochimie Fondamentale et Appliquée, Université Paul Sabatier/CNRS UMR 5069, 118 Route de Narbonne, 31062 Toulouse Cedex 09, France
Search for more papers by this authorDr. György Szalóki
Laboratoire Hétérochimie Fondamentale et Appliquée, Université Paul Sabatier/CNRS UMR 5069, 118 Route de Narbonne, 31062 Toulouse Cedex 09, France
Search for more papers by this authorDr. E. Daiann Sosa Carrizo
CNRS/UNIV PAU & PAYS ADOUR, Institut des Sciences Analytiques et de Physico-Chimie pour l'Environnement et les Matériaux (IPREM UMR 5254), Hélioparc, 2 Avenue du Président Angot, 64053 Pau Cedex 09, France
Search for more papers by this authorDr. Nathalie Saffon-Merceron
Institut de Chimie de Toulouse (FR 2599), 118 Route de Narbonne, 31062 Toulouse Cedex 09, France
Search for more papers by this authorDr. Karinne Miqueu
CNRS/UNIV PAU & PAYS ADOUR, Institut des Sciences Analytiques et de Physico-Chimie pour l'Environnement et les Matériaux (IPREM UMR 5254), Hélioparc, 2 Avenue du Président Angot, 64053 Pau Cedex 09, France
Search for more papers by this authorCorresponding Author
Dr. Didier Bourissou
Laboratoire Hétérochimie Fondamentale et Appliquée, Université Paul Sabatier/CNRS UMR 5069, 118 Route de Narbonne, 31062 Toulouse Cedex 09, France
Search for more papers by this authorDr. Jessica Rodriguez
Laboratoire Hétérochimie Fondamentale et Appliquée, Université Paul Sabatier/CNRS UMR 5069, 118 Route de Narbonne, 31062 Toulouse Cedex 09, France
Search for more papers by this authorDr. György Szalóki
Laboratoire Hétérochimie Fondamentale et Appliquée, Université Paul Sabatier/CNRS UMR 5069, 118 Route de Narbonne, 31062 Toulouse Cedex 09, France
Search for more papers by this authorDr. E. Daiann Sosa Carrizo
CNRS/UNIV PAU & PAYS ADOUR, Institut des Sciences Analytiques et de Physico-Chimie pour l'Environnement et les Matériaux (IPREM UMR 5254), Hélioparc, 2 Avenue du Président Angot, 64053 Pau Cedex 09, France
Search for more papers by this authorDr. Nathalie Saffon-Merceron
Institut de Chimie de Toulouse (FR 2599), 118 Route de Narbonne, 31062 Toulouse Cedex 09, France
Search for more papers by this authorDr. Karinne Miqueu
CNRS/UNIV PAU & PAYS ADOUR, Institut des Sciences Analytiques et de Physico-Chimie pour l'Environnement et les Matériaux (IPREM UMR 5254), Hélioparc, 2 Avenue du Président Angot, 64053 Pau Cedex 09, France
Search for more papers by this authorCorresponding Author
Dr. Didier Bourissou
Laboratoire Hétérochimie Fondamentale et Appliquée, Université Paul Sabatier/CNRS UMR 5069, 118 Route de Narbonne, 31062 Toulouse Cedex 09, France
Search for more papers by this authorDedicated to Professor Antonio Laguna
Abstract
Gold(III) π-complexes have been authenticated recently with alkenes, alkynes, and arenes. The key importance of PdII π-allyl complexes in organometallic chemistry (Tsuji–Trost reaction) prompted us to explore gold(III) π-allyl complexes, which have remained elusive so far. The (P,C)AuIII(allyl) and (methallyl) complexes 3 and 3′ were readily prepared and isolated as thermally and air-stable solids. Spectroscopic and crystallographic analyses combined with detailed DFT calculations support tight quasi-symmetric η3-coordination of the allyl moiety. The π-allyl gold(III) complexes are activated towards nucleophilic additions, as substantiated with β-diketo enolates.
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