Carbon-Doped BN Nanosheets for the Oxidative Dehydrogenation of Ethylbenzene
Fangsong Guo
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 3, 50002 China
Search for more papers by this authorDr. Pengju Yang
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 3, 50002 China
Search for more papers by this authorZhiming Pan
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 3, 50002 China
Search for more papers by this authorXu-Ning Cao
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 3, 50002 China
Search for more papers by this authorCorresponding Author
Prof. Zailai Xie
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 3, 50002 China
Search for more papers by this authorCorresponding Author
Prof. Xinchen Wang
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 3, 50002 China
Search for more papers by this authorFangsong Guo
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 3, 50002 China
Search for more papers by this authorDr. Pengju Yang
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 3, 50002 China
Search for more papers by this authorZhiming Pan
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 3, 50002 China
Search for more papers by this authorXu-Ning Cao
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 3, 50002 China
Search for more papers by this authorCorresponding Author
Prof. Zailai Xie
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 3, 50002 China
Search for more papers by this authorCorresponding Author
Prof. Xinchen Wang
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 3, 50002 China
Search for more papers by this authorAbstract
Carbon-based catalysts have demonstrated great potential for the aerobic oxidative dehydrogenation reaction (ODH). However, its widespread application is retarded by the unavoidable deactivation owing to the appearance of coking or combustion under ODH conditions. The synthesis and characterization of porous structure of BCN nanosheets as well as their application as a novel catalyst for ODH is reported. Such BCN nanosheets consist of hybridized, randomly distributed domains of h-BN and C phases, where C, B, and N were confirmed to covalent bond in the graphene-like layers. Our studies reveal that BCN exhibits both high activity and selectivity in oxidative dehydrogenation of ethylbenzene to styrene, as well as excellent oxidation resistance. The discovery of such a simple chemical process to synthesize highly active BCN allows the possibility of carbocatalysis to be explored.
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