Zinc–Zinc Double Bonds: A Theoretical Study
Corresponding Author
Dr. Jorge Echeverría
Department de Química Inorgànica i Orgànica, Secció de Química Inorgànica, Institut de Química Teòrica i Computacional, Universitat de Barcelona, Martí i Franquès, 1–11, 08028 Barcelona, Spain
Search for more papers by this authorDr. Andrés Falceto
Department de Química Inorgànica i Orgànica, Secció de Química Inorgànica, Institut de Química Teòrica i Computacional, Universitat de Barcelona, Martí i Franquès, 1–11, 08028 Barcelona, Spain
Search for more papers by this authorCorresponding Author
Prof. Santiago Alvarez
Department de Química Inorgànica i Orgànica, Secció de Química Inorgànica, Institut de Química Teòrica i Computacional, Universitat de Barcelona, Martí i Franquès, 1–11, 08028 Barcelona, Spain
Search for more papers by this authorCorresponding Author
Dr. Jorge Echeverría
Department de Química Inorgànica i Orgànica, Secció de Química Inorgànica, Institut de Química Teòrica i Computacional, Universitat de Barcelona, Martí i Franquès, 1–11, 08028 Barcelona, Spain
Search for more papers by this authorDr. Andrés Falceto
Department de Química Inorgànica i Orgànica, Secció de Química Inorgànica, Institut de Química Teòrica i Computacional, Universitat de Barcelona, Martí i Franquès, 1–11, 08028 Barcelona, Spain
Search for more papers by this authorCorresponding Author
Prof. Santiago Alvarez
Department de Química Inorgànica i Orgànica, Secció de Química Inorgànica, Institut de Química Teòrica i Computacional, Universitat de Barcelona, Martí i Franquès, 1–11, 08028 Barcelona, Spain
Search for more papers by this authorAbstract
While double bonds are known for transition metals of Groups 9 and 10 as well as for boron and p-block elements of Groups 14–16, Zn sits in a small region of the periodic table with no well-characterized double bonds. A qualitative reasoning indicates that zero-valent zinc has the potential to form Zn=Zn double bonds. A computational study in search for complexes that might showcase this new bond type is presented here.
Supporting Information
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
| Filename | Description |
|---|---|
| ange201702171-sup-0001-misc_information.pdf1.5 MB | Supplementary |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1I. Resa, E. Carmona, E. Gutiérrez-Puebla, A. Monge, Science 2004, 305, 1136–1138.
- 2T. Nguyen, A. D. Sutton, M. Brynda, J. C. Fettinger, G. J. Long, P. P. Power, Science 2005, 310, 844–847.
- 3T. Li, S. Schulz, P. W. Roesky, Chem. Soc. Rev. 2012, 41, 3759–3771; E. Carmona, A. Galindo, Angew. Chem. Int. Ed. 2008, 47, 6526–6536; Angew. Chem. 2008, 120, 6626–6637.
- 4J. F. Van der Maelen, E. Gutiérrez-Puebla, A. Monge, S. García-Granda, I. Resa, E. Carmona, M. T. Fernández-Díaz, G. J. McIntyre, P. Pattison, H.-P. Weber, Acta Crystallogr. Sect. B 2007, 63, 862–868.
- 5X. He, R. A. Bartlett, M. M. Olmstead, K. Ruhland-Senge, B. E. Sturgeon, P. P. Power, Angew. Chem. Int. Ed. Engl. 1993, 32, 717–719; Angew. Chem. 1993, 105, 761–762.
- 6J. Su, X.-W. Li, R. C. Crittendon, G. H. Robinson, J. Am. Chem. Soc. 1997, 119, 5471–5472.
- 7R. J. Wright, M. Brynda, P. P. Power, Angew. Chem. Int. Ed. 2006, 45, 5953–5956; Angew. Chem. 2006, 118, 6099–6102.
- 8R. C. Fischer, P. P. Power, Chem. Rev. 2010, 110, 3877–3923.
- 9H. Braunschweig, R. D. Dewhurst, C. Horl, A. K. Phukan, F. Pinzner, S. Ullrich, Angew. Chem. Int. Ed. 2014, 53, 3241–3244; Angew. Chem. 2014, 126, 3305–3308; Y. Wang, B. Quillian, P. Wei, Y. Xie, C. S. Wannere, R. B. King, H. F. Schaeffer III, P. v. R. Schleyer, G. H. Robinson, J. Am. Chem. Soc. 2008, 130, 3298–3299.
- 10A. Hübner, M. Bolte, H.-W. Lerner, M. Wagner, Angew. Chem. Int. Ed. 2014, 53, 10408–10411; Angew. Chem. 2014, 126, 10576–10579.
- 11T. Chu, L. Belding, P. K. Poddutoori, A. van der Est, T. Dudding, I. Korobkov, G. I. Nikonov, Dalton Trans. 2016, 45, 13440–13448.
- 12T. Cadenbach, C. Gemel, R. A. Fischer, Angew. Chem. Int. Ed. 2008, 47, 9146–9149; Angew. Chem. 2008, 120, 9286–9289.
- 13B. Cordero, V. Gómez, A. E. Platero-Prats, M. Revés, J. Echeverría, E. Cremades, F. Barragán, S. Alvarez, Dalton Trans. 2008, 2832–2838.
- 14J. Hicks, E. J. Underhill, C. E. Kefalidis, L. Maron, C. Jones, Angew. Chem. Int. Ed. 2015, 54, 10000–10004; Angew. Chem. 2015, 127, 10138–10142.
- 15M. A. Czajkowski, J. Koperski, Spectrochim. Acta Part A 1999, 55, 2221–2229.
- 16L. Jiang, Y.-L. Teng, Q. Xu, J. Phys. Chem. A 2006, 110, 7092–7096.
- 17L. Jin, L.-j. Fu, Y.-h. Ding, Phys. Chem. Chem. Phys. 2010, 12, 10956–10962.
- 18P. Pyykkö, M. Atsumi, Chem. Eur. J. 2009, 15, 12770–12779.
- 19P. Pyykkö, M. Atsumi, Chem. Eur. J. 2009, 15, 186–197.
- 20J. Nuss, U. Wedig, A. Kirfel, M. Jansen, Z. Anorg. Allg. Chem. 2010, 636, 309–313.
- 21A. Rit, A. Zanardi, T. P. Spaniol, L. Maron, J. Okuda, Angew. Chem. Int. Ed. 2014, 53, 13273–13277; Angew. Chem. 2014, 126, 13489–13493.
- 22D. del Río, I. Resa, A. Rodríguez, L. Sánchez, R. Köppe, A. J. Downs, C. Y. Tang, E. Carmona, J. Phys. Chem. A 2008, 112, 10516–10525.
- 23J. W. Kress, J. Phys. Chem. A 2005, 109, 7757–7763.
- 24T. A. Albright, J. K. Burdett, M.-H. Whangbo, Orbital Interactions in Chemistry, Wiley, Hoboken, 2013.
- 25R. F. W. Bader, Atoms in Molecules, Clarendon Press, Oxford, 1994.
- 26K. B. Wiberg, R. F. W. Bader, C. D. H. Lau, J. Am. Chem. Soc. 1987, 109, 985–1001.
- 27M. Tafipolsky, W. Scherer, K. Öfele, G. Artus, B. Pedersen, W. A. Herrmann, G. S. McGrady, J. Am. Chem. Soc. 2002, 124, 5865–5880.
- 28F. P. Arnold, Organometallics 1999, 18, 4800–4809.
- 29R. Hoffmann, Angew. Chem. Int. Ed. Engl. 1982, 21, 711–724; Angew. Chem. 1982, 94, 725–739.
- 30M. J. Frisch et al., Gaussian 09, Gaussian, Inc., Wallingford, CT, 2010.
- 31A. D. McLean, G. S. Chandler, J. Chem. Phys. 1980, 72, 5639; R. Krishnan, J. S. Binkley, R. Seeger, J. A. Pople, J. Chem. Phys. 1980, 72, 650.
- 32T. A. Keith, AIMAll (v. 17.01.25), TK Gristmill Software, Overland Park KS, USA, 2017.
- 33C. R. Groom, I. J. Bruno, M. P. Lightfoot, S. C. Ward, Acta Crystallogr. Sect. B 2016, 72, 171–179.
Citing Literature
This is the
German version
of Angewandte Chemie.
Note for articles published since 1962:
Do not cite this version alone.
Take me to the International Edition version with citable page numbers, DOI, and citation export.
We apologize for the inconvenience.
