A Carbon Dioxide Bubble-Induced Vortex Triggers Co-Assembly of Nanotubes with Controlled Chirality
Corresponding Author
Dr. Ling Zhang
PCFM Lab and GDHPRC Lab, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorLaicheng Zhou
PCFM Lab and GDHPRC Lab, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorNa Xu
PCFM Lab and GDHPRC Lab, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorZhenjie Ouyang
PCFM Lab and GDHPRC Lab, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorCorresponding Author
Dr. Ling Zhang
PCFM Lab and GDHPRC Lab, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorLaicheng Zhou
PCFM Lab and GDHPRC Lab, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorNa Xu
PCFM Lab and GDHPRC Lab, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorZhenjie Ouyang
PCFM Lab and GDHPRC Lab, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorAbstract
It is challenging to prepare co-organized nanotube systems with controlled nanoscale chirality in an aqueous liquid flow field. Such systems are responsive to a bubbled external gas. A liquid vortex induced by bubbling carbon dioxide (CO2) gas was used to stimulate the formation of nanotubes with controlled chirality; two kinds of achiral cationic building blocks were co-assembled in aqueous solution. CO2-triggered nanotube formation occurs by formation of metastable intermediate structures (short helical ribbons and short tubules) and by transition from short tubules to long tubules in response to chirality matching self-assembly. Interestingly, the chirality sign of these assemblies can be selected for by the circulation direction of the CO2 bubble-induced vortex during the co-assembly process.
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