Magnetic Properties of a Single-Molecule Lanthanide–Transition-Metal Compound Containing 52 Gadolinium and 56 Nickel Atoms
Da-Peng Liu
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
These authors contributed equally to this work.
Search for more papers by this authorXin-Ping Lin
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
These authors contributed equally to this work.
Search for more papers by this authorHui Zhang
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
These authors contributed equally to this work.
Search for more papers by this authorXiu-Ying Zheng
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorCorresponding Author
Dr. Gui-Lin Zhuang
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310032 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Xiang-Jian Kong
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorCorresponding Author
Prof. Dr. La-Sheng Long
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorProf. Dr. Lan-Sun Zheng
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorDa-Peng Liu
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
These authors contributed equally to this work.
Search for more papers by this authorXin-Ping Lin
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
These authors contributed equally to this work.
Search for more papers by this authorHui Zhang
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
These authors contributed equally to this work.
Search for more papers by this authorXiu-Ying Zheng
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorCorresponding Author
Dr. Gui-Lin Zhuang
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310032 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Xiang-Jian Kong
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorCorresponding Author
Prof. Dr. La-Sheng Long
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorProf. Dr. Lan-Sun Zheng
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorAbstract
Monodisperse metal clusters provide a unique platform for investigating magnetic exchange within molecular magnets. Herein, the core–shell structure of the monodisperse molecule magnet of [Gd52Ni56(IDA)48(OH)154(H2O)38]@SiO2 (1 a@SiO2) was prepared by encapsulating one high-nuclearity lanthanide–transition-metal compound of [Gd52Ni56(IDA)48(OH)154(H2O)38]⋅(NO3)18⋅164 H2O (1) (IDA=iminodiacetate) into one silica nanosphere through a facile one-pot microemulsion method. 1 a@SiO2 was characterized using transmission electron microscopy, N2 adsorption–desorption isotherms, and inductively coupled plasma-atomic emission spectrometry. Magnetic investigation of 1 and 1 a revealed J1=0.25 cm−1, J2=−0.060 cm−1, J3=−0.22 cm−1, J4=−8.63 cm−1, g=1.95, and z J=−2.0×10−3 cm−1 for 1, and J1=0.26 cm−1, J2=−0.065 cm−1, J3=−0.23 cm−1, J4=−8.40 cm−1 g=1.99, and z J=0.000 cm−1 for 1 a@SiO2. The z J=0 in 1 a@SiO2 suggests that weak antiferromagnetic coupling between the compounds is shielded by silica nanospheres.
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