Volume 127, Issue 31 p. 8976

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Innentitelbild: Coordination Assembly of Discoid Nanoparticles (Angew. Chem. 31/2015)

Dr. Kenji Hirai,

Dr. Kenji Hirai

Department of Chemical Engineering, University of Michigan, Ann Arbor, MI 48109 (USA)

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Dr. Bongjun Yeom,

Dr. Bongjun Yeom

Department of Chemical Engineering, University of Michigan, Ann Arbor, MI 48109 (USA)

Department of Chemical Engineering, Myongji University, 116 Myongji-ro, Cheoin-gu, Gyeonggi-do, 449-728 (South Korea)

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Dr. Shu-Hao Chang,

Dr. Shu-Hao Chang

Department of Chemical Engineering, University of Michigan, Ann Arbor, MI 48109 (USA)

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Dr. Hang Chi,

Dr. Hang Chi

Department of Physics, University of Michigan, Ann Arbor, MI 48109 (USA)

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Dr. John F. Mansfield,

Dr. John F. Mansfield

Electron Microbeam Analysis Laboratory, University of Michigan, Ann Arbor, MI 48109 (USA)

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Dr. Byeongdu Lee,

Dr. Byeongdu Lee

Advanced Photon Source, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439 (USA)

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Sungsik Lee,

Sungsik Lee

Advanced Photon Source, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439 (USA)

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Prof. Ctirad Uher,

Corresponding Author

Prof. Ctirad Uher

[email protected]

Department of Physics, University of Michigan, Ann Arbor, MI 48109 (USA)

Ctirad Uher, Department of Physics, University of Michigan, Ann Arbor, MI 48109 (USA)

Nicholas A. Kotov, Department of Chemical Engineering, University of Michigan, Ann Arbor, MI 48109 (USA)

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Prof. Dr. Nicholas A. Kotov,

Corresponding Author

Prof. Dr. Nicholas A. Kotov

[email protected]

Department of Chemical Engineering, University of Michigan, Ann Arbor, MI 48109 (USA)

Department of Materials Science and Engineering, Department of Biomedical Engineering, and Biointerfaces Institute, University of Michigan, Ann Arbor, MI 48109 (USA)

Ctirad Uher, Department of Physics, University of Michigan, Ann Arbor, MI 48109 (USA)

Nicholas A. Kotov, Department of Chemical Engineering, University of Michigan, Ann Arbor, MI 48109 (USA)

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Dr. Kenji Hirai,

Dr. Kenji Hirai

Department of Chemical Engineering, University of Michigan, Ann Arbor, MI 48109 (USA)

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Dr. Bongjun Yeom,

Dr. Bongjun Yeom

Department of Chemical Engineering, University of Michigan, Ann Arbor, MI 48109 (USA)

Department of Chemical Engineering, Myongji University, 116 Myongji-ro, Cheoin-gu, Gyeonggi-do, 449-728 (South Korea)

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Dr. Shu-Hao Chang,

Dr. Shu-Hao Chang

Department of Chemical Engineering, University of Michigan, Ann Arbor, MI 48109 (USA)

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Dr. Hang Chi,

Dr. Hang Chi

Department of Physics, University of Michigan, Ann Arbor, MI 48109 (USA)

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Dr. John F. Mansfield,

Dr. John F. Mansfield

Electron Microbeam Analysis Laboratory, University of Michigan, Ann Arbor, MI 48109 (USA)

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Dr. Byeongdu Lee,

Dr. Byeongdu Lee

Advanced Photon Source, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439 (USA)

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Sungsik Lee,

Sungsik Lee

Advanced Photon Source, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439 (USA)

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Prof. Ctirad Uher,

Corresponding Author

Prof. Ctirad Uher

[email protected]

Department of Physics, University of Michigan, Ann Arbor, MI 48109 (USA)

Ctirad Uher, Department of Physics, University of Michigan, Ann Arbor, MI 48109 (USA)

Nicholas A. Kotov, Department of Chemical Engineering, University of Michigan, Ann Arbor, MI 48109 (USA)

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Prof. Dr. Nicholas A. Kotov,

Corresponding Author

Prof. Dr. Nicholas A. Kotov

[email protected]

Department of Chemical Engineering, University of Michigan, Ann Arbor, MI 48109 (USA)

Department of Materials Science and Engineering, Department of Biomedical Engineering, and Biointerfaces Institute, University of Michigan, Ann Arbor, MI 48109 (USA)

Ctirad Uher, Department of Physics, University of Michigan, Ann Arbor, MI 48109 (USA)

Nicholas A. Kotov, Department of Chemical Engineering, University of Michigan, Ann Arbor, MI 48109 (USA)

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First published: 16 July 2015

https://doi.org/10.1002/ange.201505953

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Graphical Abstract

Zink(II)-Ionen und Carboxylatgruppen koordinieren an der Oberfläche von FeS₂-Nanopartikeln und lösen die Bildung von FeS₂-Multipartikelschichten mit flüssigkristallartiger Organisation aus. Die nanoskalige Porosität der Schichten in Verbindung mit ihrem schnellen Lochtransport führt zu einer hohen elektrokatalytischen Aktivität, wie C. Uher, N. Kotov et al. in ihrer Zuschrift auf S. 9094 ff. erläutern. Leitfähigkeit und Ladungsträgermobilität der p-leitenden Filme übertreffen die Werte bekannter Koordinationsverbindungen und Metall-organischer Gerüste.