A Chemically Triggered and Thermally Switched Dielectric Constant Transition in a Metal Cyanide Based Crystal†
Chao Shi
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, Jiangsu (China)
Search for more papers by this authorXi Zhang
Department of Physics & Shanghai Key Laboratory of Magnetic Resonance, East China Normal University, North Zhongshan Road 3663, Shanghai 200062 (China)
Search for more papers by this authorYing Cai
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, Jiangsu (China)
Search for more papers by this authorCorresponding Author
Prof. Ye-Feng Yao
Department of Physics & Shanghai Key Laboratory of Magnetic Resonance, East China Normal University, North Zhongshan Road 3663, Shanghai 200062 (China)
Ye-Feng Yao, Department of Physics & Shanghai Key Laboratory of Magnetic Resonance, East China Normal University, North Zhongshan Road 3663, Shanghai 200062 (China)
Wen Zhang, Ordered Matter Science Research Center, Southeast University, Nanjing 211189, Jiangsu (China)
Search for more papers by this authorCorresponding Author
Prof. Wen Zhang
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, Jiangsu (China)
Ye-Feng Yao, Department of Physics & Shanghai Key Laboratory of Magnetic Resonance, East China Normal University, North Zhongshan Road 3663, Shanghai 200062 (China)
Wen Zhang, Ordered Matter Science Research Center, Southeast University, Nanjing 211189, Jiangsu (China)
Search for more papers by this authorChao Shi
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, Jiangsu (China)
Search for more papers by this authorXi Zhang
Department of Physics & Shanghai Key Laboratory of Magnetic Resonance, East China Normal University, North Zhongshan Road 3663, Shanghai 200062 (China)
Search for more papers by this authorYing Cai
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, Jiangsu (China)
Search for more papers by this authorCorresponding Author
Prof. Ye-Feng Yao
Department of Physics & Shanghai Key Laboratory of Magnetic Resonance, East China Normal University, North Zhongshan Road 3663, Shanghai 200062 (China)
Ye-Feng Yao, Department of Physics & Shanghai Key Laboratory of Magnetic Resonance, East China Normal University, North Zhongshan Road 3663, Shanghai 200062 (China)
Wen Zhang, Ordered Matter Science Research Center, Southeast University, Nanjing 211189, Jiangsu (China)
Search for more papers by this authorCorresponding Author
Prof. Wen Zhang
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, Jiangsu (China)
Ye-Feng Yao, Department of Physics & Shanghai Key Laboratory of Magnetic Resonance, East China Normal University, North Zhongshan Road 3663, Shanghai 200062 (China)
Wen Zhang, Ordered Matter Science Research Center, Southeast University, Nanjing 211189, Jiangsu (China)
Search for more papers by this authorThis work was financially supported by the NSFC (Grant No. 21225102 and 21174039). We thank beamline BL14B (Shanghai Synchrotron Radiation Facility) for providing the beam time.
Abstract
A dielectric constant transition is chemically triggered and thermally switched in (HPy)2[Na(H2O)Co(CN)6] (2, HPy=pyridinium cation) by single-crystal-to-single-crystal transformation and structural phase transition, respectively. Upon dehydration, (HPy)2[Na(H2O)2Co(CN)6] (1) transforms to its semi-hydrated form 2, accompanying a transition from a low-dielectric state to a high-dielectric state, and vice versa. This dielectric switch is also realized by a structural phase transition in 2 that occurs between room- and low-temperature phases, and which corresponds to high- and low-dielectric states, respectively. The switching property is due to the variation in the environment surrounding the HPy cation, that is, the hydrogen-bonding interactions and the crystal packing, which exert predominant influences on the dynamics of the cations that transit between the static and motional states.
Supporting Information
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
| Filename | Description |
|---|---|
| ange_201501344_sm_miscellaneous_information.pdf1.2 MB | miscellaneous_information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1 Handbook of Stimuli-Responsive Materials (Ed.: ), Wiley-VCH, Weinheim, 2011.
- 2M. A. C. Stuart, W. T. S. Huck, J. Genzer, M. Müller, C. Ober, M. Stamm, G. B. Sukhorukov, I. Szleifer, V. V. Tsukruk, M. Urban, F. Winnik, S. Zauscher, I. Luzinov, S. Minko, Nat. Mater. 2010, 9, 101.
- 3S. Horike, S. Shimomura, S. Kitagawa, Nat. Chem. 2009, 1, 695.
- 4aS. Horiuchi, Y. Tokura, Nat. Mater. 2008, 7, 357;
- 4bW. Zhang, R. G. Xiong, Chem. Rev. 2012, 112, 1163.
- 5O. Sato, J. Tao, Y.-Z. Zhang, Angew. Chem. Int. Ed. 2007, 46, 2152; Angew. Chem. 2007, 119, 2200.
- 6
- 6aO. Kahn, Molecular Magnetism, VCH, New York, 1993;
- 6bP. Gütlich, H. A. Goodwin, Top. Curr. Chem. 2004, 233.
- 7
- 7aW. Zhang, Y. Cai, R.-G. Xiong, H. Yoshikawa, K. Awaga, Angew. Chem. Int. Ed. 2010, 49, 6608; Angew. Chem. 2010, 122, 6758;
- 7bW. Zhang, H.-Y. Ye, R. Graf, H. W. Spiess, Y.-F. Yao, R.-Q. Zhu, R.-G. Xiong, J. Am. Chem. Soc. 2013, 135, 5230;
- 7cX. Zhang, X.-D. Shao, S.-C. Li, Y. Cai, Y.-F. Yao, R.-G. Xiong, W. Zhang, Chem. Commun. 2015, 51, 4568.
- 8
- 8aP. Jain, N. S. Dalal, B. H. Toby, H. W. Kroto, A. K. Cheetham, J. Am. Chem. Soc. 2008, 130, 10450;
- 8bX.-H. Zhao, X.-C. Huang, S.-L. Zhang, D. Shao, H.-Y. Wei, X.-Y. Wang, J. Am. Chem. Soc. 2013, 135, 16006;
- 8cC.-M. Ji, Z.-H. Sun, S.-Q. Zhang, T.-L. Chen, P. Zhou, J.-H. Luo, J. Mater. Chem. C 2014, 2, 567;
- 8dZ.-Y. Du, T.-T. Xu, B. Huang, Y.-J. Su, W. Xue, C.-T. He, W.-X. Zhang, X.-M. Chen, Angew. Chem. Int. Ed. 2015, 54, 914; Angew. Chem. 2015, 127, 928;
- 8eR. Shang, Z.-M. Wang, S. Gao, Angew. Chem. Int. Ed. 2015, 54, 2534; Angew. Chem. 2015, 127, 2564.
- 9H. Fröhlich, Theory of dielectrics, 2nd ed., Oxford University Press, Oxford, 1965.
- 10Y. A. Izyumov, V. N. Syromyatnikov, Phase Transitions and Crystal Symmetry, Kluwer, Dordrecht, 1990.
10.1007/978-94-009-1920-4 Google Scholar
- 11
- 11aM. A. Garcia-Garibay, Proc. Natl. Acad. Sci. USA 2005, 102, 10771;
- 11bS. D. Karlen, M. A. Garcia-Garibay, Top. Curr. Chem. 2005, 262, 179;
- 11cS. D. Karlen, H. Reyes, R. E. Taylor, S. I. Khan, M. F. Hawthorne, M. A. Garcia-Garibay, Proc. Natl. Acad. Sci. USA 2010, 107, 14973.
- 12
- 12aT. Akutagawa, H. Koshinaka, D. Sato, S. Takeda, S. Noro, H. Takahashi, R. Kumai, Y. Tokura, T. Nakamura, Nat. Mater. 2009, 8, 342;
- 12bP. Jain, V. Ramachandran, R. J. Clark, H. D. Zhou, B. H. Toby, N. S. Dalal, H. W. Kroto, A. K. Cheetham, J. Am. Chem. Soc. 2009, 131, 13625;
- 12cD.-W. Fu, W. Zhang, H.-L. Cai, Y. Zhang, J.-Z. Ge, R.-G. Xiong, S. D. Huang, T. Nakamura, Angew. Chem. Int. Ed. 2011, 50, 11947; Angew. Chem. 2011, 123, 12153;
- 12dG.-C. Xu, W. Zhang, X.-M. Ma, Y.-H. Chen, L. Zhang, H.-L. Cai, Z.-M. Wang, R.-G. Xiong, S. Gao, J. Am. Chem. Soc. 2011, 133, 14948;
- 12eY. Zhang, W. Zhang, S.-H. Li, Q. Ye, H.-L. Cai, F. Deng, R.-G. Xiong, S. D. Huang, J. Am. Chem. Soc. 2012, 134, 11044.
- 13M. Horie, Y. Suzaki, D. Hashizume, T. Abe, T. Wu, T. Sassa, T. Hosokai, K. Osakada, J. Am. Chem. Soc. 2012, 134, 17932.
- 14J. A. Rodríguez-Velamazán, M. A. González, J. A. Real, M. Castro, M. C. Muñoz, A. B. Gaspar, R. Ohtani, M. Ohba, K. Yoneda, Y. Hijikata, N. Yanai, M. Mizuno, H. Ando, S. Kitagawa, J. Am. Chem. Soc. 2012, 134, 5083.
- 15C. Lemouchi, K. Iliopoulos, L. Zorina, S. Simonov, P. Wzietek, T. Cauchy, A. Rodríguez-Fortea, E. Canadell, J. Kaleta, J. Michl, D. Gindre, M. Chrysos, P. Batail, J. Am. Chem. Soc. 2013, 135, 9366.
- 16W. Setaka, K. Yamaguchi, J. Am. Chem. Soc. 2013, 135, 14560.
- 17E. Coronado, M. Giménez-Marqués, G. M. Espallargas, F. Rey, I. J. Vitórica-Yrezábal, J. Am. Chem. Soc. 2013, 135, 15986.
- 18C. R. Murdock, N. W. McNutt, D. J. Keffer, D. M. Jenkins, J. Am. Chem. Soc. 2014, 136, 671.
- 19A. Comotti, S. Bracco, A. Yamamoto, M. Beretta, T. Hirukawa, N. Tohnai, M. Miyata, P. Sozzani, J. Am. Chem. Soc. 2014, 136, 618.
- 20Z.-S. Yao, M. Mito, T. Kamachi, Y. Shiota, K. Yoshizawa, N. Azuma, Y. Miyazaki, K. Takahashi, K. Zhang, T. Nakanishi, S. Kang, S. Kanegawa, O. Sato, Nat. Chem. 2014, 6, 1079.
- 21
- 21aT. K. Maji, K. Uemura, H.-C. Chang, R. Matsuda, S. Kitagawa, Angew. Chem. Int. Ed. 2004, 43, 3269; Angew. Chem. 2004, 116, 3331;
- 21bC. L. Chen, A. M. Goforth, M. D. Smith, C.-Y. Su, H. C. zur Loye, Angew. Chem. Int. Ed. 2005, 44, 6673; Angew. Chem. 2005, 117, 6831;
- 21cC. Serre, C. Mellot-Draznieks, S. Surble, N. Audebrand, Y. Filinchuk, G. Férey, Science 2007, 315, 1828;
- 21dB. Wei, R. Shang, X. Zhang, X.-D. Shao, Y.-F. Yao, Z.-M. Wang, R.-G. Xiong, W. Zhang, Chem. Eur. J. 2014, 20, 8269.
- 22aS. F. Liu, J. D. Mao, K. Schmidt-Rohr, J. Magn. Reson. 2002, 155, 15;
- 22bP. Parhami, B. M. Fung, J. Am. Chem. Soc. 1985, 107, 7304.
- 23A. K. Jonscher, Dielectric Relaxation in Solids, Chelsea Dielectrics Press, London, 1983.
- 24J. G. Kirkwood, J. Chem. Phys. 1939, 7, 911.
Citing Literature
This is the
German version
of Angewandte Chemie.
Note for articles published since 1962:
Do not cite this version alone.
Take me to the International Edition version with citable page numbers, DOI, and citation export.
We apologize for the inconvenience.
