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Innenrücktitelbild: Electrical Network of Single-Crystalline Metal Oxide Nanoclusters Wired by π-Molecules (Angew. Chem. 42/2014)

Corresponding Author

Dr. Ryo Tsunashima

[email protected]

Graduate School of Science and Engineering, Yamaguchi University, Yoshida 1677-1, Yamaguchi, 753 8512 (Japan)

Graduate School of Science and Engineering, Yamaguchi University, Yoshida 1677-1, Yamaguchi, 753 8512 (Japan)Search for more papers by this author

Yoshifumi Iwamoto,

Yoshifumi Iwamoto

Department of Biology and Chemistry, Yamaguchi University, Yoshida 1677-1, Yamaguchi, 753 8512 (Japan)

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Yusuke Baba,

Yusuke Baba

Department of Biology and Chemistry, Yamaguchi University, Yoshida 1677-1, Yamaguchi, 753 8512 (Japan)

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Chisato Kato,

Chisato Kato

Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526 (Japan)

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Katsuya Ichihashi,

Katsuya Ichihashi

Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526 (Japan)

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Dr. Sadafumi Nishihara,

Dr. Sadafumi Nishihara

Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526 (Japan)

Institute for Advanced Materials Research, Hiroshima University, Higashi-Hiroshima 739-8530 (Japan)

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Prof. Katsuya Inoue,

Prof. Katsuya Inoue

Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526 (Japan)

Institute for Advanced Materials Research, Hiroshima University, Higashi-Hiroshima 739-8530 (Japan)

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Prof. Katsuya Ishiguro,

Prof. Katsuya Ishiguro

Graduate School of Science and Engineering, Yamaguchi University, Yoshida 1677-1, Yamaguchi, 753 8512 (Japan)

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Prof. Yu-Fei Song,

Prof. Yu-Fei Song

State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, 100029 Beijing (P. R. China)

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Prof. Tomoyuki Akutagawa,

Prof. Tomoyuki Akutagawa

Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, Sendai 980-8577 (Japan)

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Dr. Ryo Tsunashima,

Corresponding Author

Dr. Ryo Tsunashima

[email protected]

Graduate School of Science and Engineering, Yamaguchi University, Yoshida 1677-1, Yamaguchi, 753 8512 (Japan)

Graduate School of Science and Engineering, Yamaguchi University, Yoshida 1677-1, Yamaguchi, 753 8512 (Japan)Search for more papers by this author

Yoshifumi Iwamoto,

Yoshifumi Iwamoto

Department of Biology and Chemistry, Yamaguchi University, Yoshida 1677-1, Yamaguchi, 753 8512 (Japan)

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Yusuke Baba,

Yusuke Baba

Department of Biology and Chemistry, Yamaguchi University, Yoshida 1677-1, Yamaguchi, 753 8512 (Japan)

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Chisato Kato,

Chisato Kato

Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526 (Japan)

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Katsuya Ichihashi,

Katsuya Ichihashi

Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526 (Japan)

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Dr. Sadafumi Nishihara,

Dr. Sadafumi Nishihara

Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526 (Japan)

Institute for Advanced Materials Research, Hiroshima University, Higashi-Hiroshima 739-8530 (Japan)

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Prof. Katsuya Inoue,

Prof. Katsuya Inoue

Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526 (Japan)

Institute for Advanced Materials Research, Hiroshima University, Higashi-Hiroshima 739-8530 (Japan)

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Prof. Katsuya Ishiguro,

Prof. Katsuya Ishiguro

Graduate School of Science and Engineering, Yamaguchi University, Yoshida 1677-1, Yamaguchi, 753 8512 (Japan)

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Prof. Yu-Fei Song,

Prof. Yu-Fei Song

State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, 100029 Beijing (P. R. China)

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Prof. Tomoyuki Akutagawa,

Prof. Tomoyuki Akutagawa

Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, Sendai 980-8577 (Japan)

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First published: 14 August 2014

https://doi.org/10.1002/ange.201407931

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Graphical Abstract

Elektronen in gemischtvalenten Polyoxometallaten …︁ …︁ sind normalerweise wegen der schwachen Wechselwirkungen zwischen den Clustern über ein Clusteranion delokalisiert. In ihrer Zuschrift auf S. 11410 ff. zeigen R. Tsunashima et al., wie gemischtvalente Polyoxometallatcluster durch Tetrathiafulvalen-Derivate elektrisch verbunden werden können. Der Elektronentransport im Einkristall beruht auf einem Elektronenhüpfen infolge der starken Wechselwirkungen zwischen den Clustern und den kationischen π-Molekülen.